Thick film conductor composition for use in biosensors

• US 6,042,751 A
• Filed: 09/17/1998
• Issued: 03/28/2000
• Est. Priority Date: 09/17/1998
• Status: Expired due to Term

• Current Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Chan, Man-Sheung, Kuty, Donald W.
• Primary Examiner(s): KOPEC, MARK T
• Application Number:
  US09/156,309
• Time in Patent Office: 558 Days
• Field of Search: 252/511, 252/514, 430/209, 430/212, 430/218, 204/280, 204/292, 204/294
• US Class Current: 252/511
• CPC Class Codes: G01N 27/3271 Amperometric enzyme electrodes for analytes in body fluids, e.g. glucose in blood amperometry per se G01N27/49; aspects concerning the enzyme reagent C12Q1/001
• CPC Class Codes: H05K 1/095 for polymer thick films, i.e. having a permanent organic polymeric binder

Abstract

The invention is directed to polymer thick film conductor compositions comprising conductive metal particles selected from the group consisting of finely divided powders of platinum group metals and mixtures thereof; modified graphite; and a thermoplastic polymer and optionally, graphite and/or a metallized graphite in combination with a surfactant may replace the modified graphite.

Claims

1. A conductor composition for use in electrochemical sensor applications, comprising, based on solids:

(a) 0.1-5% wt. conductive metal particles selected from the group consisting of finely divided powders of platinum group metals and mixtures thereof,

(b) 62-85% wt. of modified graphite; and

(c) 14-35% wt. of a thermoplastic polymer.

2. The conductor composition of claim 1 further comprising surfactant.

3. The composition of claim 2 wherein the surfactant is a nonionic surfactant selected from the group consisting of fatty acid, fatty alcohol, long-chain alkylphenol, poly(ethylene oxide)-modified fatty acid, fatty alcohol and alkylphenol.

4. The composition of claim 1 or 2 further comprising organic solvent.

5. The composition of claim 1 wherein the thermoplastic binder is selected from the group consisting of poly(styrene), styrene-containing acrylic copolymer, poly(acrylonitrile-butadiene-styrene), poly(hydroxyether), copolyester, poly(carbonate), and polyimide.

6. The composition of claim 1 or 3 wherein the organic solvent is selected from the group consisting of glycol ether acetate, glycol diacetate, alkyl ketone, aryl ketone, aromatic hydrocarbon and mixtures thereof.

7. A working electrode for use in electrochemical biosensor comprising the conductor composition of claim 1 or 2 on a substrate.