Large area electrochromic window

• US 6,045,724 A
• Filed: 03/05/1998
• Issued: 04/04/2000
• Est. Priority Date: 11/29/1989
• Status: Expired due to Fees

• Current Assignee: Donnelly Corporation (Magna International Incorporated)
• Original Assignee: Donnelly Corporation (Magna International Incorporated)
• Inventors: Varaprasad, Desaraju V., Lynam, Niall R., Habibi, Hamid R., Desaraju, Padma
• Primary Examiner(s): Tucker, Philip
• Application Number:
  US09/035,623
• Time in Patent Office: 761 Days
• Field of Search: 252/583, 252/586, 359/265, 359/272, 359/275
• US Class Current: 252/583
• CPC Class Codes: C09K 9/02 Organic tenebrescent materials
• CPC Class Codes: G02F 1/1503 caused by oxidation-reduction reactions in organic liquid solutions, e.g. viologen solutions
• CPC Class Codes: G02F 1/161 Gaskets; Spacers; Sealing of cells; Filling or closing of cells
• CPC Class Codes: G02F 2001/1502 complementary cell
• CPC Class Codes: G02F 2001/15145 the electrochromic layer comprises a mixture of anodic and cathodic compounds

Abstract

The specification discloses electrochemichromic solutions and devices based on the use of solvents comprising at least about 25% 3-hydroxypropionitrile, 3,3'"'"'-oxydipropionitrile, 2-acetylbutyrolactone, 2-methylglutaronitrile, 3-methylsulfolane and mixtures thereof. The specification also discloses vacuum backfilling techniques for filling electrochemichromic cells and enhanced UV stability through solvent self-screening.

Claims

1. A large area variable transmission electrochromic window suitable for use as at least one of an architectural window, an automotive window, and an office partition panel comprising:

first and second spaced optically transparent elements, said elements each having front and rear surfaces and defining a space between the rear surface of said first element and the front surface of said second element;

an electrochromic medium confined in said space whose light transmission is variable upon the application of an electric field thereto;

means for applying an electric field to said electrochromic medium to cause variation in the light transmittance of said medium wherein said means for applying an electric field include a substantially transparent conductive coating on at least one of said rear surface of said first element and said front surface of said second element, said substantially transparent conductive coating having a sheet resistance of 25 ohms/square or lower and selected from the group consisting of indium tin oxide, doped tin oxide, and doped zinc oxide;

said electrochromic medium including a redox chemical pair which colors under the application of voltage;

said electrochromic medium further including an ultraviolet stabilizer whereby said redox chemical pair is provided with enhanced ultraviolet stability;

said electrochromic window having an electrochromically active large area of length dimension at least about 14 cm and of width dimension at least about 14 cm;

said electrochromic window exhibiting a steady state leakage current of less than about 2.68 amperes per square meter when a potential of one volt is applied to said electrochromic window whereby coloration uniformity of said electrochromic window is enhanced.

2. The window of claim 1 wherein said ultraviolet stabilizer is selected from the group consisting of benzophenones and cyanoacrylates.

3. The window of claim 2 wherein said ultraviolet stabilizer is selected from the group consisting of 2, 4-dihydroxy-benzophenone, 2,2'"'"'-dihydroxy-4-methoxybenzophenone, and 2-ethylhexyl-2-cyano-3, 3-diphenyacrylate.

4. The window of claim 1 wherein said ultraviolet stabilizer has a concentration in said electrochromic medium of at least approximately 5% weight/volume.

5. The window of claim 4 wherein said ultraviolet stabilizer is a benzophenone.

6. The window of claim 4 wherein said ultraviolet stabilizer is a cyanoacrylate.

7. The window of claim 1 wherein said redox chemical pair includes a viologen species.

8. The window of claim 1 wherein said redox chemical pair comprises a viologen species and at least one compound selected from the group consisting of phenazines, phenylenediamines, benzidenes and fulvalenes.

9. The window of claim 8 wherein said phenazine compound is selected from the group consisting of 5, 10-dihydro-5, 10-dimethylphenazine, 5, 10-dihydro-5, 10-diethylphenazine and 5, 10-dihydro-5, 10-dioctylphenazine.

10. The window of claim 8 wherein said phenylenediamine compound is N, N, N'"'"', N'"'"'-tetramethyl-phenylenediamine.

11. The window of claim 8 wherein said benzidene compound is N, N, N'"'"', N'"'"'-tetramethylbenzidene.

12. The window of claim 8 wherein said fulvalene compound is tetrathiafulvalene.

13. The window of claim 1 wherein said redox chemical pair includes a phenazine compound.

14. The window of claim 13 wherein said phenazine compound is selected from the group consisting of 5, 10-dihydro-5, 10-dimethylphenazine, 5, 10-dihydro-5, 10-diethylphenazine and 5, 10-dihydro-5, 10-dioctylphenazine.

15. The window of claim 1 wherein said sheet resistance is 15 ohms/square or lower.

16. The window of claim 15 wherein said substantially transparent conductive coating is indium tin oxide.

17. The window of claim 15 wherein said substantially transparent conductive coating is doped tin oxide.

18. The window of claim 15 wherein said substantially transparent conductive coating is doped zinc oxide.

19. The window of claim 1 wherein said substantially transparent conductive coating is indium tin oxide.

20. The window of claim 1 wherein said substantially transparent conductive coating is doped tin oxide.

21. The window of claim 1 wherein said substantially transparent conductive coating is doped zinc oxide.