In-situ short circuit protection system and method for high-energy electrochemical cells

• US 6,099,986 A
• Filed: 07/25/1997
• Issued: 08/08/2000
• Est. Priority Date: 07/25/1997
• Status: Expired due to Term

• Current Assignee: 3M Innovative Properties Company (3M Company), Avestor (Bolloré SE), Bathium Canada Inc. (Bolloré SE)
• Original Assignee: 3M Innovative Properties Company (3M Company), Hydro-Quebec (Province of Québec)
• Inventors: Gauthier, Michel, Domroese, Michael K., Hoffman, Joseph A., Trice, Jennifer L., Rouillard, Roger, Radewald, Vern E., Lindeman, David D., Rouillard, Jean, Shiota, Toshimi, Noel, Joseph-Robert-Gaetan
• Primary Examiner(s): Nuzzolillo, Maria
• Assistant Examiner(s): Ruthkosky, Mark
• Application Number:
  US08/900,929
• Time in Patent Office: 1,110 Days
• Field of Search: 429/7, 429/62, 429/120
• US Class Current: 429/120
• CPC Class Codes: H01M 10/613 Cooling or keeping cold
• CPC Class Codes: H01M 10/647 Prismatic or flat cells, e.g. pouch cells
• CPC Class Codes: H01M 10/6554 Rods or plates
• CPC Class Codes: H01M 50/574 Devices or arrangements for the interruption of current
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

An in-situ thermal management system for an energy storage device. The energy storage device includes a plurality of energy storage cells each being coupled in parallel to common positive and negative connections. Each of the energy storage cells, in accordance with the cell'"'"'s technology, dimensions, and thermal/electrical properties, is configured to have a ratio of energy content-to-contact surface area such that thermal energy produced by a short-circuit in a particular cell is conducted to a cell adjacent the particular cell so as to prevent the temperature of the particular cell from exceeding a breakdown temperature. In one embodiment, a fuse is coupled in series with each of a number of energy storage cells. The fuses are activated by a current spike capacitively produced by a cell upon occurrence of a short-circuit in the cell, thereby electrically isolating the short-circuited cell from the common positive and negative connections.

Claims

1. An in-situ thermal management system for an energy storing unit, comprising:

a plurality of thin-film electrochemical cells each being coupled in parallel to common positive and negative connections, each of the electrochemical cells having a ratio of energy content-to-contact surface area such that thermal energy produced by a short-circuit in a particular cell of the plurality of cells is conducted to a thermal conductor connected to each of the cells and to a cell adjacent the particular cell so as to prevent a temperature of the particular cell from exceeding a breakdown temperature; and

a plurality of fuses each coupled in series with one of the electrochemical cells, a fuse coupled to the particular cell being activated by a current spike capacitively produced by the particular cell upon occurrence of the short-circuit in the particular cell, thereby electrically isolating the particular cell from the common positive and negative connections.

2. The system of claim 1, wherein the fuses are activated by a current spike having an amperage ranging between approximately 300 A and 600 A.

3. The system of claim 1, wherein the fuses have a current rating of approximately 50 A.

4. The system of claim 1, wherein the fuses are fabricated as an integrated package.

5. The system of claim 1, wherein the breakdown temperature represents a melting temperature of the particular cell.

6. The system of claim 1, wherein the ratio of energy content-to-contact surface area is less than approximately 0.006 Wh/cm².

7. The system of claim 1, wherein each of the plurality of electrochemical cells has a prismatic configuration.

8. The system of claim 1, wherein each of the plurality of electrochemical cells has a surface area ranging between approximately 100 cm² and 400 cm² and an energy content ranging between approximately 10 Wh and 40 Wh.

20. The system of claim 1, wherein each of the plurality of fuses comprises a thermal fuse.

9. An in-situ thermal management system for an energy storing unit, comprising:

a plurality of energy storing cells connected in parallel to common positive and negative connections and maintained in a state of compression, a thermal conductor connected to each of the cells; and

a plurality of short-circuit protection devices each being coupled in series to one of the plurality of energy storing cells, a particular short-circuit protection device of the plurality of short-circuit protection devices coupled to a particular cell of the plurality of cells being activated by a current spike capacitively produced upon occurrence of a short-circuit in the particular cell, the particular cell being electrically isolated from the common positive and negative connections upon activation of the particular short-circuit device.

10. An in-situ thermal management system for an energy storing unit, comprising:

a plurality of substantially planar thin-film electrochemical cells each having a breakdown temperature;

the plurality of electrochemical cells being arranged such that a planar surface of a particular cell of the plurality of cells is in thermal contact with a planar surface of a cell disposed adjacent the particular cell; and

the planar surfaces of the particular cell and the adjacent cell each having a ratio of energy content-to-contact surface area such that thermal energy produced by a short-circuit condition arising in the particular cell is conducted to a thermal conductor connected thereto and to the adjacent cell so as to prevent a temperature of the particular cell from exceeding the breakdown temperature.

11. The system of claim 10, wherein each of the plurality of electrochemical cells comprises lithium, and the breakdown temperature represents a melting temperature of lithium.

12. The system of claim 10, wherein the planar surfaces of the particular and adjacent cell each have a ratio of energy content-to-contact surface area such that thermal energy produced by the short-circuit condition occurring in the particular cell is conducted to the adjacent cell so as to prevent a temperature of the particular cell from exceeding a safety temperature, the safety temperature being lower than the breakdown temperature.

13. The system of claim 12, wherein the safety temperature is 130°

Celsius.

14. The system of claim 10, wherein the ratio of energy content-to-surface area is less than approximately 0.006 Wh/cm².

15. The system of claim 10, wherein the ratio of energy content-to-surface area ranges between approximately 0.0034 Wh/cm² and 0.0038 Wh/cm².

16. The system of claim 10, wherein each of the plurality of electrochemical cells has a prismatic configuration.

17. The system of claim 10, wherein each of the plurality of electrochemical cells has a surface area ranging between approximately 100 cm² and 400 cm².

18. The system of claim 10, wherein each of the plurality of electrochemical cells has an energy content ranging between approximately 10 Wh and 40 Wh.

19. The system of claim 10, wherein each of the plurality of electrochemical cells has a thickness that varies between approximately 3 mm to 10 mm and the ratio of energy content-to-contact surface area is less than approximately 0.006 Wh/cm².