Staged reductant injection for improved NO.sub.x reduction

• US 6,125,629 A
• Filed: 11/13/1998
• Issued: 10/03/2000
• Est. Priority Date: 11/13/1998
• Status: Expired due to Fees

• Current Assignee: Engelhard Corporation (BASF SE)
• Original Assignee: Engelhard Corporation (BASF SE)
• Inventors: Patchett, Joseph A.
• Primary Examiner(s): Denion, Thomas
• Assistant Examiner(s): TRAN, BINH Q
• Application Number:
  US09/191,779
• Time in Patent Office: 690 Days
• Field of Search: 60/286, 60/274, 60/284, 60/295, 60/302, 60/303, 422/172, 422/182, 422/183, 422/148
• US Class Current: 60/286
• CPC Class Codes: B01D 53/9431 Processes characterised by a specific device
• CPC Class Codes: B01D 53/9495 Controlling the catalytic process
• CPC Class Codes: F01N 13/0093 the purifying devices are of the same type
• CPC Class Codes: F01N 13/0097 the purifying devices are arranged in a single housing
• CPC Class Codes: F01N 2560/026 for measuring or detecting NOx
• CPC Class Codes: F01N 2560/06 the means being a temperature sensor
• CPC Class Codes: F01N 2560/07 the means being an exhaust gas flow rate or velocity meter or sensor, intake flow meters only when exclusively used to determine exhaust gas parameters
• CPC Class Codes: F01N 2570/18 Ammonia
• CPC Class Codes: F01N 2610/02 the substance being ammonia or urea
• CPC Class Codes: F01N 2610/03 the substance being hydrocarbons, e.g. engine fuel
• CPC Class Codes: F01N 2610/14 Arrangements for the supply of substances, e.g. conduits
• CPC Class Codes: F01N 2610/146 Control thereof, e.g. control of injectors or injection valves
• CPC Class Codes: F01N 2900/08 said parameters being related to the engine
• CPC Class Codes: F01N 2900/14 said parameters being related to the exhaust gas
• CPC Class Codes: F01N 3/2066 Selective catalytic reduction [SCR]
• CPC Class Codes: F01N 3/208 Control of selective catalytic reduction [SCR], e.g. dosing of reducing agent
• CPC Class Codes: Y02A 50/20 Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
• CPC Class Codes: Y02T 10/12 Improving ICE efficiencies

Abstract

An external reductant for an SCR vehicular NO_x emission control system is selectively injected to SCR catalysts which are only at catalytically active temperatures thereby avoiding reductant absorption in catalytically unactive catalysts and improving conversion response time.

Claims

1. A method for converting NOx emissions in the exhaust gases of a vehicle powered by a diesel engine comprising the steps of:

a) providing a first SCR catalyst catalytically active when its catalyst bed temperature is within a temperature range of a first low temperature to a first high temperature;

b) providing a second SCR catalyst chemically different from the first SCR catalyst and catalytically active when its catalyst bed temperature is within a temperature range of a second low temperature to a second high temperature, the second low temperature being less than the first low temperature;

c) sequentially passing the exhaust gas in any order from one of the SCR catalysts to the other SCR catalysts;

d) metering a reductant selected from the group consisting of ammonia and an ammonia precursor(s) during warm-up of the engine to the second SCR catalyst until the first SCR catalyst bed is heated from ambient temperature to a temperature whereat it ceases to function as a heat sink; and

,

e) thereafter and during warm-up, metering the reductant to any one of the SCR catalysts having a catalytically active bed whereby oxidation of reductant and substantial retention of reductant on the catalyst bed is avoided.

2. The method of claim 1 further including the step of simultaneously metering the reductant to the first and second catalysts if both catalyst'"'"'s beds are catalytically active.

3. The method of claim 2 wherein the first and second catalysts are combined into a single catalyst bed and the metering step directs reductant against that portion of the catalyst bed which has ceased to function after cold start as a heat sink and is at a catalytically active temperature.

4. The method of claim 2 wherein the metering reductant rate to any SCR catalyst is a variable rate determined as a function of the catalyst bed temperature, space velocity of the exhaust gas through the catalyst and quantity of NOx present in the exhaust gas.

5. The method of claim 2 further including an oxidation catalyst downstream of the second SCR catalyst for preventing ammonia slip.

6. The method of claim 2 wherein the first SCR catalyst is a noble metal catalyst deposited on a metal oxide support and the second catalyst comprises an oxide.