Miniature milliwatt electric power generator

• US 6,207,887 B1
• Filed: 07/07/1999
• Issued: 03/27/2001
• Est. Priority Date: 07/07/1999
• Status: Expired due to Term

• Current Assignee: HI-Z Technology, Inc.
• Original Assignee: HI-Z Technology, Inc.
• Inventors: Elsner, Norbert B., Bass, John C.
• Primary Examiner(s): Gorgos, Kathryn
• Assistant Examiner(s): Parsons, Thomas H.
• Application Number:
  US09/349,428
• Time in Patent Office: 629 Days
• Field of Search: 136/201, 136/203, 136/205, 136/237, 136/239, 136/240, 204/192.15, 204/192.17
• US Class Current: 136/201
• CPC Class Codes: H10N 10/01 Manufacture or treatment
• CPC Class Codes: H10N 10/17 characterised by the structure or configuration of the cell or thermocouple forming the device

Abstract

A miniature thermoelectric module for generating electric power from low power heat sources in the range of a fraction of a Watt to a few Watts. The module comprises an array of thermoelectric elements, each element having a cross section of less than 0.001 square inch and a length of at least 0.25 inch. The elements are separated from each other with a polyimide insulator sheet in a checkerboard array. In a preferred embodiment, the modules are fabricated by hot pressing a stack of alternating plates of p and n doped thin plates all separated by thin sheets of a polyimide insulator material to produce a pressed stack of p and n doped layers. The stack is then sliced to produce layered plates which are then stacked with insulating polyimide layers positioned between the layered plates to produce the checkerboard array of p and n thermoelectric elements. Contacts are applied to electrically connect all of the elements. In a preferred embodiment, the contacts are applied by first sputtering a thin layer of gold, then welding gold tabs, and then blasting away the excess sputtered gold. In one preferred embodiment, the contacts connect all of the elements in series. In another preferred embodiment, the elements are connected in a series-parallel circuit. In a preferred embodiment, the module is utilized in a generation unit with a 1-Watt radioactive heat source to produce about 40 mW of electric power at 5.5 Volts which is converted to 12 Volts with a DC to DC converter.

Claims

1. A thermoelectric module defining a hot side and a cold side, said module comprising:

A) a plurality of P-type thermoelectric elements,

B) a plurality of N-type thermoelectric elements, said P-type elements and said N-type elements being arranged in an array and insulated from each other with self adhering polyimide film,

C) a plurality of contacts on said cold side and said hot side connecting said elements in an electric circuit.

2. A module as in claim 1 wherein each of said contacts comprise a thin sputtered layer of gold and a gold tab welded over said sputtered layer.

3. A module as in claim 1 wherein each of said contacts comprise a thin sputtered layer of gold and a layer of gold electroplated over said sputtered layer.

4. A module as in claim 1 wherein each of said contacts comprise a thin sputtered layer of electrically conductive material and a layer of electrically conductive material electroplated over said sputtered layer.

5. A module as in claim 1 wherein each of said contacts comprise a thin sputtered layer of electrically conductive material and an electrically conductive tab welded over said sputtered layer.

6. A module as in claim 5 wherein both said electrically conductive material and said electrically conductive tab is a Ni—

Al alloy.

7. A module as in claim 5 wherein both said electrically conductive material and said electrically conductive tab is chosen from a group consisting of:

Au, Pd, Pt, Ni, Al, Fe and Co.

8. A module as in claim 1 wherein said N-type elements comprise bismuth telluride doped with iodoform and said P-type elements comprise bismuth telluride doped with lead.

9. A module as in claim 1 wherein each of said P-type element and each of said N-type element has a cross section of less than 0.01 square inch.

10. A module as in claim 1 wherein each of said P-type element and each of said N-type element has a cross section of less than about 0.0003 square inch.

11. A module as in claim 1 wherein each of said P-type element and each of said N-type element has a cross section of less than about 0.0003 square inch and a length of more than 0.5 inch and said plurality of elements number at least 100.

12. A module as in claim 11 wherein said elements number at least 324.

13. A module as in claim 1 wherein all elements are connected in series.

14. A module as in claim 1 wherein said elements are connected in a series-parallel circuit.

15. A method of making a small thermoelectric module comprising the steps of:

A) preparing a puck of N-type thermoelectric material,

B) preparing a puck of P-type thermoelectric material,

C) cutting thin plates from said N and P type pucks, to produce a plurality of N-type plates and a plurality of P-type plates,

D) stacking the plates to produce alternating layers of N and P type plates with a thin layer of self adhering polyimide insulator film between each layer of plates, to produce a stack of alternating insulated layers,

E) pressing the stack of alternating insulated layers in a hot press to produce a pressed stack of alternating insulated layers,

F) cutting thin plates from said pressed stack of alternating insulated layers to produce a plurality of insulated layered plates,

G) stacking the insulated layered plates to produce layers of insulated layered plates with a thin layer of self adhering polyimide insulator between each layer of insulated layered plates, to produce a stack of insulated layered plates in which each P-type layer is adjacent to a N-type layer but separated from it by said film of self adhering polyimide insulator film,

H) pressing the stack of insulated layers of layered plates in a hot press to produce a pressed stack of insulated layers of insulated layered plates, said pressed stack of insulated layers of insulated layered plates comprising an array of P-type and N-type thermoelectric elements arranged in a checkerboard pattern and defining a hot side and a cold side,

I) applying electrical contacts between P-type elements and N-type elements at said hot side and cold side to connect a plurality of said elements in an electric circuit, and

J) attaching at least two electrical leads at appropriate positions on said array of thermoelectric elements to produce a thermoelectric module.

16. A method as in claim 15 wherein said steps of preparing said N-type and P-type pucks comprise the following steps:

A) preparing a N-type alloy of a solid solution of Bi₂Te₃ and Bi₂Se₃ where the amount of Bi₂Se₃ is from 7 to 20 molecular percent, with a doping of about 0.1 percent iodoform by melting said Bi₂Te₃ and Bi₂Se₃ and iodoform in a quartz ampoule,

B) removing said alloy and grinding it in an inert gas glove box to produce a powder,

C) pressing said powder in a vacuum hot press to form an N-type puck,

D) preparing a P-type alloy of a solid solution of Bi₂Te₃ and Sb₂Te₃ and the amount of Sb₂Te₃ can vary from 70 to 90 molecular percent, with a doping of about 0.1 percent lead by melting said Bi₂Te₃ and Sb₂Te₃ and lead in a quartz ampoule,

E) removing said alloy and grinding it in an inert gas glove box to produce a powder,

F) pressing said powder in a vacuum hot press to form an P-type puck.

17. A method as in claim 15 wherein said contacts comprise gold tabs and said step of applying said contacts comprises the sub-steps of:

A) sputtering a thin layer that is a few microns thick of gold on said cold side and said hot side,

B) welding said gold tabs on top of said thin layer to make said contacts, and

C) blasting away said thin layer except where covered by said gold tabs.

18. A method as in claim 17 wherein said sub-step of welding said gold tabs is parallel gap welding said gold tabs.

19. A method as in claim 17 wherein said sub-step of welding said gold tabs is laser welding said gold tabs.

20. A method as in claim 19 wherein said sub-step of laser welding said gold tabs further includes a sub-step of covering said gold tabs with a transparent tool prior to said laser welding.

21. A method as in claim 15 wherein said contacts comprise gold tabs and said step of applying said contacts comprises the sub-steps of:

A) covering said cold side and said hot side with a mask,

B) sputtering a thin layer that is a few microns thick of gold through said mask onto said cold side and said hot side to form gold contact pads,

C) removing said mask from said cold side and said hot side, and

D) welding said gold tabs on top of said contact pads.

22. A method as in claim 15 wherein said step of applying said contacts comprises the sub-steps of:

A) covering said cold side and said hot side with a mask,

B) sputtering a thin layer that is a few microns thick of gold through said mask onto said cold side and said hot side to form an electric circuit, and

C) removing said mask from said cold side and said hot side.

23. A method as in claim 22 further comprising the sub-step of electroplating the module after said mask is removed from said cold side and said hot side.

24. A method as in claim 15 wherein said contacts comprise gold tabs and said step of applying said contacts comprises the sub-steps of:

A) covering a first side of said cold side and said hot side with photoresist,

B) placing a pattern over said photoresist, wherein said pattern represents locations of gold contact pads,

C) exposing said pattern covered photoresist to ultraviolet light to form a soluble photoresist portion and a hardened photeresist portion,

D) removing said pattern,

E) dissolving said soluble photoresist portion,

F) sputtering a thin layer that is a few microns thick of gold through said hardened photoresist portion onto said first side to form said gold contact pads,

G) dissolving said hardened photoresist portion,

H) welding said gold tabs on top of said gold contact pads, and

I) repeating steps A) through H) for a second side of cold side and said hot side.

25. A method as in claim 15 wherein said step of applying said contacts comprises the sub-steps of:

A) covering a first side of said cold side and said hot side with photoresist,

B) placing a pattern over said photoresist, wherein said pattern represents locations of an electric circuit connecting said elements,

C) exposing said pattern covered photoresist to ultraviolet light to form a soluble photoresist portion and a hardened photeresist portion,

D) removing said pattern,

E) dissolving said soluble photoresist portion,

F) sputtering a thin layer that is a few microns thick of gold through said hardened photoresist portion onto first side to form said electric circuit,

G) dissolving said hardened photoresist portion, and

H) repeating steps A) through G) for a second of said cold side and said hot side.

26. A method as in claim 25 further comprising the sub-step of electroplating the module after dissolving said hardened photoresist portion.

27. An electric generation unit comprising:

A) a thermoelectric module defining a hot side and a cold side, said module comprising;

1) a plurality of P-type thermoelectric elements,

2) a plurality of N-type thermoelectric elements,

said P-type elements and said N-type elements being arranged in an array and insulated from each other with self adhering polyimide film,

3) a plurality of contacts on said cold side and said hot side connecting said elements in an electric circuit, and

4) at least two electrical leads attached to said array;

B) a heat source positioned adjacent to said hot side.

28. An electric generator as in claim 27 wherein each of said P-type element and each of said N-type element has a cross section of less than 0.01 square inch.

29. An electric generator as in claim 28 wherein said elements number at least 324.

30. An electric generator as in claim 27 wherein each of said P-type element and each of said N type element has a cross section of less than about 0.0003 square inch.

31. An electric generator as in claim 27 wherein each of said P-type element and each of said N type element has a cross section of less than about 0.0003 square inch and a length of more than 0.5 inch and said plurality of elements number at least 100.