Heat-treatable dichroic mirrors

• US 6,262,850 B1
• Filed: 11/03/1998
• Issued: 07/17/2001
• Est. Priority Date: 11/03/1998
• Status: Expired due to Term

• Current Assignee: Cardinal CG Company (Cardinal Glass Industries Incorporated)
• Original Assignee: Cardinal Glass Industries Incorporated
• Inventors: Krisko, Annette J., Maxwell, Scott A.
• Primary Examiner(s): Epps, Georgia
• Assistant Examiner(s): SEYRAFI, SAEED HMT
• Application Number:
  US09/185,305
• Time in Patent Office: 987 Days
• Field of Search: 359/634, 359/631, 359/580, 359/584, 359/585, 359/588, 359/589, 359/883, 359/884, 430/48
• US Class Current: 359/634
• CPC Class Codes: B60R 1/088 using a cell of electrically changeable optical characteristic, e.g. liquid-crystal or electrochromic mirrors
• CPC Class Codes: B60R 1/1207 with lamps; with turn indicators
• CPC Class Codes: C03C 17/36 at least one coating being a metal
• CPC Class Codes: C03C 17/3618 Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
• CPC Class Codes: C03C 17/3649 made of metals other than silver
• CPC Class Codes: C03C 17/3663 specially adapted for use as mirrors
• CPC Class Codes: C03C 2217/734 comprising an alternation of high and low refractive indexes
• CPC Class Codes: C03C 2217/78 Coatings specially designed to be durable, e.g. scratch-resistant
• CPC Class Codes: G02B 5/10 with curved faces

Abstract

A heat-treatable dichroic mirror, comprising a transparent substrate having a glass transition temperature in the range of 650-800° C., and a plurality of sputtered films carried on said substrate and forming at least two pairs of contiguous films in which the films of each pair have disparate refractive indices differing by at least about 0.2 so as to provide between them a reflective interface. The films include an oxide of a metal such as titanium, a second film comprising an oxidizable metal or semi-metal such as silicon, and a protective overcoat of a thickness and composition sufficient to substantially prevent permeation of oxygen therethrough when heat treated at said glass transition temperature. The mirror, after said heat treatment, exhibits a transmittance of at least 24% in the wavelength range of 550-650 nm, a reflectance of at least 45%, and a haze of not greater than about 1%.

Claims

1. A heat-treatable dichroic mirror, comprising a transparent substrate having a glass transition temperature in the range of 650-800°

C., and a plurality of sputtered films carried on said substrate and forming at least two pairs of contiguous films, the films of each pair having disparate refractive indices differing by at least about 0.2 so as to provide between them a reflective interface, the films including a first film that is a member of a said contiguous film pair and comprising an oxide of a metal, a second film positioned further from the substrate than the first film and that is a member of a said contiguous film pair, the second film comprising an oxidizable metal or semi-metal, and a protective overcoat of a thickness and composition sufficient to substantially prevent permeation of oxygen therethrough when heat treated at said glass transition temperature, said mirror, after said heat treatment, exhibiting a transmittance of at least 24% in the wavelength range of 550-650 nm, a reflectance of at least 45%.

2. The mirror of claim 1 wherein said first film comprises an oxide of a metal selected from the group consisting of titanium, zinc, niobium, tin, bismuth, and alloys thereof.

3. The mirror of claim 1 wherein said second film is selected from the group consisting of silicon, niobium, aluminum, nickel, chromium, and alloys thereof.

4. The mirror of claim 1 wherein said first and second films are members of the same film pair having disparate refractive indices.

5. The mirror of claim 1 including a third film deposited between the first and second films and forming with at least one of the first and second films a film pair having disparate refractive indices, said third film being of a thickness and composition sufficient to substantially prevent permeation of oxygen therethrough when the mirror is heat treated at said glass transition temperature.

6. The mirror of claim 5 wherein said third film forms with each of the first and second films a film pair having disparate refractive indices.

7. The mirror of claim 5 or claim 6 wherein said second film forms with each of said second film and said protective overcoat a film pair having disparate refractive indices.

8. The mirror of claim 1 wherein said first film includes an impurity in an amount sufficient to retard haze formation in said first film upon said heat treatment, the mole ratio of said impurity to said metal oxide not exceeding 0.1.

9. The mirror of claim 8 wherein said impurity comprises nitrogen.

11. The mirror of any one of claims 1-10 wherein said overcoat film is silicon nitride.

20. The mirror of claim 1 wherein the substrate has a first side and a second side and said plurality of sputtered films are carried on the first side of the substrate.

21. The mirror of claim 20 wherein said transmittance is measured from said second side of the substrate.

22. The mirror of claim 20 wherein said reflectance is measured from said first side of the substrate.

10. A heat-treatable dichroic mirror, comprising a transparent substrate having a glass transition temperature in the range of 650-800°

C., and a plurality of sputtered films carried on said substrate and forming at least two pairs of contiguous films, the films of each pair having disparate refractive indices differing by at least about 0.2 so as to provide between them a reflective interface, the films including a first film that is a member of a said contiguous film pair and comprising an oxide of titanium, a second film positioned further from the substrate than the first film and that is a member of a said contiguous film pair, the second film comprising silicon, and a protective overcoat of a thickness and composition sufficient to substantially prevent permeation of oxygen therethrough when heat treated at said glass transition temperature, said titanium oxide first film including an impurity deposited therein during formation of said first film and in an amount sufficient to retard haze formation in said first contiguous film upon said heat treatment, the mole ratio of said impurity to said titanium oxide not exceeding 0.1.

12. A heat-treatable dichroic mirror, comprising a transparent substrate having a first side and a second side and a glass transition temperature in the range of 650-800°

C., a visibly reflective film carried on the first side of the substrate, the visibly reflective film comprising at least two pairs of contiguous films, the films of each pair having disparate refractive indices differing by at least about 0.2 so as to provide between them a visibly reflective interface, the films including a first film that is a member of a said contiguous film pair and comprising an oxide of a metal selected from the group consisting of titanium, zinc, niobium, tin, bismuth and alloys thereof, a second film positioned further from the substrate than the first film and that is a member of a said contiguous film pair, the second film comprising an oxidizable element selected from the group consisting of silicon, niobium, aluminum, nickel, chromium, and alloys thereof, and a protective overcoat of silicon nitride of a thickness and composition sufficient to substantially prevent permeation of oxygen therethrough when said mirror is heat treated at said glass transition temperature, said mirror, after said heat treatment, exhibiting a transmittance from said second side of the substrate of at least 24%, and a reflectance from said first side of the substrate of at least 45%.

13. The mirror of claim 12 wherein said first film includes an impurity deposited therein during formation of said first film and in an amount sufficient to retard haze formation in said first contiguous film upon said heat treatment, the mole ratio of said impurity to said metal oxide not exceeding 0.1.

14. The mirror of claim 13 wherein said impurity is nitrogen.

18. The method of claim 13 wherein said metal oxide is titanium oxide.

19. The method of any one of claims 14-18 wherein said metal oxide film is sputtered from a target comprising titanium oxide having a substoichiometric amount of oxygen.

15. Method of making a dichroic mirror comprising magnetron sputter coating upon a transparent substrate having a glass transition temperature in the range of 650-800°

C. a plurality of sequential films forming at least two pairs of contiguous films, the films of each pair having disparate refractive indices differing by at least about 0.2 so as to provide between them a reflective interface, the films including a first film, the coating further including a protective overcoat of a thickness and composition sufficient to substantially prevent permeation of oxygen therethrough when said mirror is heat treated at said glass transition temperature, the method including the step of incorporating in said first metal oxide film an impurity at a mole ratio of said impurity to said metal oxide in the range of 0.001 and 0.1.

16. The method of claim 15 including the step of sputter-coating said metal oxide film in an atmosphere containing said impurity.

17. The method of claim 16 including the step of sputter-coating said metal oxide film in an atmosphere containing oxygen and nitrogen.

23. A heat-treatable dichroic mirror, comprising a transparent substrate having a glass transition temperature in the range of 650-800°

C., a visibly reflective film carried on a first side of the substrate, the visibly reflective film comprising at least two pairs of contiguous films, the films of each pair having disparate refractive indices differing by at least about 0.2 so as to provide between them a visibly reflective interface, the films including a first film that is a member of a said contiguous film pair and comprising an oxide of a metal selected from the group consisting of titanium, zinc, niobium, tin, bismuth and alloys thereof, a second film positioned further from the substrate than the first film and that is a member of a said contiguous film pair, the second film comprising an oxidizable element selected from the group consisting of silicon, niobium, aluminum, nickel, chromium, and alloys thereof, and a protective overcoat of silicon nitride of a thickness and composition sufficient to substantially prevent permeation of oxygen therethrough when said mirror is heat treated at said glass transition temperature, said mirror, after said heat treatment, exhibiting a transmittance of at least 24% at a predetermined visible wavelength, and a reflectance that is at least 30% throughout the wavelength range of 400-700 nm.

24. A heat-treatable dichroic mirror, comprising a transparent substrate having a glass transition temperature in the range of 650-800°

C., a visibly reflective film carried on a first side of the substrate and a visible light source positioned behind a second side of the substrate, the visibly reflective film comprising at least two pairs of contiguous films, the films of each pair having disparate refractive indices differing by at least about 0.2 so as to provide between them a visibly reflective interface, the films including a first film that is a member of a said contiguous film pair and comprising an oxide of a metal, a second film positioned further from the substrate than the first film and that is a member of a said contiguous film pair, the second film comprising an oxidizable metal or semi-metal, and a protective overcoat of a thickness and composition sufficient to substantially prevent permeation of oxygen therethrough when heat treated at said glass transition temperature, said mirror, after said heat treatment, exhibiting a transmittance from said second side of the substrate of at least 24% at a peak output wavelength of the light source, and a reflectance from said first side of the substrate of at least 45%.