Process for preparing multilayer plastic composites of incompatible plastics

• US 6,280,671 B1
• Filed: 03/01/1995
• Issued: 08/28/2001
• Est. Priority Date: 08/05/1993
• Status: Expired due to Fees

• Current Assignee: Roehm GmbH Chemische Fabrik
• Original Assignee: Roehm GmbH Chemische Fabrik
• Inventors: Poehlmann, Klaus-Ernst, Mueller, Michael, Meier-Kaiser, Michael, Benz, Volker, Lorenz, Hans
• Primary Examiner(s): DIXON, MERRICK L
• Application Number:
  US08/396,645
• Time in Patent Office: 2,372 Days
• Field of Search: 264/167, 264/171, 264/555, 264/171.11, 264/172.14, 264/172.15, 264/177.1, 264/211.22, 425/132, 425/461, 425/463, 425/DIG.243
• US Class Current: 264/172.14
• CPC Class Codes: B29C 48/07 Flat, e.g. panels
• CPC Class Codes: B29C 48/08 flexible, e.g. films
• CPC Class Codes: B29C 48/19 the layers being joined at their edges
• CPC Class Codes: B29C 48/20 one of the layers being a strip, e.g. a partially embedded strip
• CPC Class Codes: B29C 48/21 the layers being joined at their surfaces
• CPC Class Codes: B29C 48/22 with means connecting the layers, e.g. tie layers or undercuts
• CPC Class Codes: B29C 70/20 oriented in a single direction, e.g. roofing or other parallel fibres B29C70/083, B29C70/226 take precedence
• CPC Class Codes: B29K 2995/0039 Amorphous
• CPC Class Codes: B29K 2995/0041 Crystalline
• CPC Class Codes: E01F 8/0017 Plate-like elements E01F8/0035 takes precedence
• CPC Class Codes: Y10T 428/24942 including components having same physical characteristic in differing degree

Abstract

Multilayer plastic composites containing at least two incompatible plastics, A and B, in which the layering sequence alternates between A and B, the layers of plastic B are discontinued at regular intervals, and the resulting gaps in the layers are filled in with plastic A, exhibit good adhesion between the layers. In preferred embodiments of the invention, the amorphous, crystalline, or semi-crystalline plastic B has a higher coefficient of thermal expansion than the amorphous plastic A. The plastic composite is preferably produced via coextrusion.

Claims

1. A method for producing a multilayer plastic composite,

said composite comprising a sequence of layers of at least two incompatible thermoplastic plastics, A and B, wherein said sequence of layers alternates between A and B, a layer of plastic B is discontinuous at regular intervals to form gaps in said layer of plastic B, and said gaps in said layer of B are filled in with plastic A;

said method comprising coextruding plastic A and plastic B through a die comprising a pair of parallel exit slits and a plurality of exit ports, with a gap between each port, located between said pair of parallel exit slits, said plurality of exit ports being evenly spaced along a line parallel to said pair of exit slits,

wherein said coextruding plastic A and plastic B comprises forming a pair of fluid streams of said plastic A by passing a fluid stream of plastic A through said pair of parallel exit slits and forming a plurality of fluid streams of plastic B with gaps between each stream of said plastic B by passing a fluid stream of plastic B through said plurality of exit ports, so that said fluid streams of said plastic A exit said pair of exit slits and said fluid streams of plastic B exit said plurality of exit ports in such a manner to result in a portion of said fluid streams of said plastic A passing through said gaps between each stream of said plastic B to effect fusion of said pair of fluid streams of said plastic A, to obtain said composite.

2. The method of claim 1, wherein said plastic B has a greater coefficient of thermal expansion than said plastic A.

3. The method of claim 1, wherein said plastic A is amorphous, and said plastic B is semi-crystalline.

4. The method of claim 1, wherein said plastic A is amorphous, and said plastic B is crystalline.

5. The method of claim 1, wherein said plastic A is amorphous, and said plastic B is amorphous.