Method for treating an electrochemical device

• US 6,337,758 B1
• Filed: 06/06/2000
• Issued: 01/08/2002
• Est. Priority Date: 07/10/1998
• Status: Expired due to Term

• Current Assignee: Sage Electrochromics, Inc (Compagnie de Saint-Gobain SA)
• Original Assignee: Saint-Gobain Vitrage
• Inventors: Giron, Jean-Christophe, Beteille, Fabien
• Primary Examiner(s): Epps, Georgia
• Assistant Examiner(s): THOMPSON, TIMOTHY J
• Application Number:
  US09/486,718
• Time in Patent Office: 581 Days
• Field of Search: 359/265, 359/270, 359/268, 359/275
• US Class Current: 359/265
• CPC Class Codes: E06B 3/6722 with adjustable passage of light
• CPC Class Codes: G02F 1/153 Constructional details
• CPC Class Codes: G02F 1/1533 structural features not otherwise provided for
• CPC Class Codes: H01M 10/4235 Safety or regulating additives or arrangements in electrodes, separators or electrolyte H01M10/4242 takes precedence
• CPC Class Codes: H01M 6/18 with solid electrolyte
• CPC Class Codes: H01M 6/181 with polymeric electrolytes
• CPC Class Codes: H01M 6/40 Printed batteries , e.g. thin film batteries
• CPC Class Codes: H01M 6/50 Methods or arrangements for servicing or maintenance, e.g. for maintaining operating temperature constructional details of current conducting connections for detecting conditions inside cells or batteries, e.g. details of voltage sensing terminals, H01M50/569
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

The invention relates to a method of processing an electrochemical device having at least one carrier substrate (1) provided with a stack (2) of functional layers, including at least one electrochemically active layer (4) which is capable of reversibly and simultaneously inserting ions and electrons and is arranged between two electroconductive layers, in particular a device of the electrochromic type. The processing consists in locally inhibiting the functionality of at least one of the functional layers, with the exception of one of the electroconductive layers (3, 8), so as to delimit an inactive peripheral region in the stack (2).

Claims

1. A method of processing an electrochemical device having at least one carrier substrate in contact with a stack of functional layers comprising two electroconductive layers and at least one electrochemically active layer, which is capable of reversibly and simultaneously inserting ions and which is arranged between the two electroconductive layers, the method comprising

locally inhibiting a functionality of at least one of the functional layers, with the exception of one of the two electroconductive layers, by cutting through the at least one of the layers along a closed line to delimit an inactive region of the stack that is located between the closed line and an edge of the stack so as to delimit an inactive peripheral region in the stack.

2. The method according to claim 1, wherein the stack comprises at least, successively, a first electroconductive layer, an electrochemically active layer capable of reversibly inserting ions in an anodic or cathodic electrochromic material, an electrolyte layer, a second electrochemically active layer capable of reversibly inserting the ions in the cathodic or anodic electrochromic material, and a second electroconductive layer.

3. The method according to claim 1, wherein the stack of functional layers contains only layers of solid material.

4. The method according to claim 1, the inhibiting is carried out after the substrate has been provided with all the functional layers of the stack.

5. The method according to claim 1, wherein the cutting is made along a closed line which, in smaller proportions, has a profile similar or identical to that of the edge of the stack.

6. The method according to claim 1, the cutting is performed by a mechanical means or by laser irradiation.

7. The method according to claim 1, wherein the functionality of at least one of the functional layers is locally inhibited by degrading a periphery of the at least one of the functional layers by a heat treatment or by laser irradiation.

8. The method according to claim 7, wherein the degrading dehydrates or crystallizes the periphery of the at least one of the functional layers.

11. The method according to claim 1, wherein

the two electroconductive layers include a first electroconductive layer more resistant, harder and/or denser than the functional layers;

and

the inhibiting affects all of the functional layers apart from the first electroconductive layer.

12. The method according to claim 1, further comprising reducing and/or eliminating peripheral short-circuits in the stack of functional layers.

15. An electrochemical device processed using the method of claim 4, wherein the device has at least one peripheral inactive region remaining permanently in an uncolored state.

16. An electrochemical device processed using the method of claim 1, wherein during operation the device has a leakage current less than or equal to 20 μ

A/cm.

9. A method of processing an electrochemical device having at least one carrier substrate in contact with a stack of functional layers comprising two electroconductive layers and at least one electrochemically active layer, which is capable of reversibly and simultaneously inserting ions and which is arranged between the two electroconductive layers, the method comprising

locally inhibiting a functionality of at least one of the functional layers, with the exception of one of the electroconductive layers, so as to delimit an inactive contour or a non-peripheral inactive region in the stack.

10. The method according to claim 9, wherein the inactive contour or an inactive region is obtained by localized degradation of at least one of the functional layers by a heat treatment, by laser irradiation, or by localized ablation.

13. The method according to claim 10, further comprising reducing and/or eliminating non-peripheral short-circuits in the stack of functional layers.

14. The method according to claim 10, further comprising creating patterns in the device.

17. The method according to claim 9, wherein

the two electroconductive layers include a first electroconductive layer more resistant, harder and/or denser than the other functional layers;

and

the inhibiting affects all of the functional layers apart from the first electroconductive layer.

18. A method of processing an electrochemical device having at least one carrier substrate in contact with a stack of functional layers comprising two electroconductive layers and at least one electrochemically active layer, which is capable of reversibly and simultaneously inserting ions and which is arranged between the two electroconductive layers, the method comprising

locally inhibiting a functionality of at least one of the functional layers, with the exception of one of the electroconductive layers, by cutting through the at least one of the layers along a closed line to delimit an inactive region of the stack that is located between the closed line and an edge of the stack so as to delimit an inactive peripheral region in the stack;

and

locally inhibiting a functionality of the at least one of the functional layers, with the exception of the one of the electroconductive layers, so as to delimit an inactive contour or a non-peripheral inactive region in the stack.

19. The method according to claim 18, wherein

the two electroconductive layers include a first electroconductive layer more resistant, harder and/or denser than the other functional layers; and

the inhibiting affects all of the functional layers apart from the first electroconductive layer.

20. An electrochemical device processed using the method of claim 18, wherein during operation the device has a leakage current less than or equal to 20 μ

A/cm.