Rheology modification of settled solids in mineral processing

• US 6,365,116 B1
• Filed: 04/19/2000
• Issued: 04/02/2002
• Est. Priority Date: 01/19/1999
• Status: Expired due to Fees

• Current Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Original Assignee: Nalco Chemical Company (Ecolab, Inc.)
• Inventors: Henderson, Raymond Leslie, Barham, Scott Lewis
• Primary Examiner(s): Hruskoci, Peter A.
• Application Number:
  US09/552,535
• Time in Patent Office: 713 Days
• Field of Search: 210/698-701, 210/725, 210/727, 210/728, 210/729, 210/730, 210/733, 210/734, 210/738, 210/803, 210/209, 210/519, 210/520, 210/528, 209/5, 423/121, 423/122
• US Class Current: 423/121
• CPC Class Codes: B01F 27/82 Pan-type mixers, i.e. mixers in which the stirring elements move along the bottom of a pan-shaped receptacle with stirring elements moving along the wall or bottom of the receptacle B01F27/091
• CPC Class Codes: B01F 35/712 for feeding fluids
• CPC Class Codes: C01F 7/0653 characterised by the flocculant added to the slurry final clarification of the aluminate solution C01F7/47
• CPC Class Codes: C01F 7/066 Treatment of the separated residue

Abstract

The present invention comprises a method for reducing the viscosity of the settled mud or underflow of a raked thickener thereby reducing the torque necessary to move the rake blade through the settled mud. The method includes the step of delivering a viscosity modifier to the settled mud and in front of the rake blade by pumping the viscosity modifier down the rake arm to an area in front of the rake blade. The method also includes an improved rake mechanism that includes a means for delivering viscosity modifier to the settled mud and in front of the rake blade. The present invention also includes a method for increasing the rate of consolidation of flocculated solids in a slurry.

Claims

1. A method for fluidifying flocculated aqueous suspensions of red mud in the production of alumina from bauxite in a Bayer process wherein a raking mechanism, having a rake arm including a rake blade at one end of the rake arm, is used to remove flocculated red mud, the method comprising the steps of:

dissolving bauxite using sodium hydroxide to form red mud;

decanting and washing the red mud, wherein one or more waters derived from the washing step are recycled to a location upstream of the washing step;

separating the red mud from alumina in successive thickener vats;

adding a flocculant comprising a polyacrylamide having a molecular weight greater than ten million into a suspension of red mud in one of the successive vats;

pumping a dispersing agent into the red mud, simultaneously with the

addition of the flocculant to the suspension in the thickener vat;

wherein the dispersing agent is selected from a group consisting of lignosulfonate, a polyacrylate, a copolymer of (meth)acrylic acid and acrylamide, (meth)acrylic acid, 2-acrylamide-2-methylpropane sulfonic acid, taurine modified polymers, napthalein sulfonates, napthalein sulphonated derivatives, and hydroxymethyl diphosphonic acid polymers, and the rake arm comprises a hollow conduit connected to a reservoir containing the dispersing agent, the rake arm further comprises at least one opening for delivering dispersing agent to the vicinity of the rake blade, and

eliminating the red mud thus treated.

2. The method of claim 1 wherein the dispersing agent is an anionic acrylic acid polymer.

3. The method of claim 1 wherein the hollow conduit comprises a central opening connected to the reservoir containing the dispersing agent and an outlet for delivering the dispersing agent therethrough.

4. The method of claim 1 wherein the hollow conduit comprises two opposing ends, including an outlet for delivering the dispersing agent therethrough and the raking mechanism further comprises a first conduit extending between the reservoir of dispersing agent and the rake arm.

5. The method of claim 1 wherein the dispersing agent is composed of lignosulfonate.

6. The method of claim 1 wherein the raking mechanism includes a rake drive connected to a rake shaft, the rake shaft connecting the rake drive to a rake arm, the rake arm comprising a plurality of rake blades, and at least one conduit comprising a first end connected to the reservoir containing a dispersing agent, a second end disposed in front of the rake blades and an outlet for delivering the dispersing agent therethrough.

7. The method of claim 6 wherein a pump is used for pumping the dispersing agent from the reservoir to the second end of the conduit.

8. The method of claim 1 wherein a first conduit is connected to the rake arm, the first conduit and the rake arm forming a T-connection.

9. The method of claim 1 including the step of pumping the dispersing agent down to the rake arm of the raking mechanism in front of the rake blade.