Polyolefin fiber compositions

• US 6,388,013 B1
• Filed: 01/04/2001
• Issued: 05/14/2002
• Est. Priority Date: 01/04/2001
• Status: Expired due to Fees

• Current Assignee: Equistar Chemicals LP (Lyondellbasell Industries NV)
• Original Assignee: Equistar Chemicals LP (Lyondellbasell Industries NV)
• Inventors: Bridges, Michael, Saraf, Anil W.
• Primary Examiner(s): Nutter, Nathan M.
• Application Number:
  US09/754,732
• Time in Patent Office: 495 Days
• Field of Search: 525/191, 525/222, 525/232, 525/240, 525/241
• US Class Current: 525/191
• CPC Class Codes: C08L 2203/12 used for fibers
• CPC Class Codes: C08L 2205/03 containing three or more polymers in a blend
• CPC Class Codes: C08L 23/0869 Acids or derivatives thereof
• CPC Class Codes: C08L 23/12 Polypropene
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 45/00 Compositions of homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic ring system; Compositions of derivatives of such polymers of cyclic anhydrides or imides C08L35/00; of cyclic esters of polyfunctional acids C08L31/00
• CPC Class Codes: C08L 57/02 Copolymers of mineral oil hydrocarbons
• CPC Class Codes: D01F 6/46 of polyolefins

Abstract

Polyolefin fibers, primarily polypropylene fibers, having improved properties are provided. The ability to produce fibers having an improved balance of properties including increased tenacity, modulus and elongation, is accomplished by incorporating from 1 to 10 weight percent aromatic hydrocarbon resin in the polypropylene fiber-forming composition which can be based on a propylene homopolymer or copolymer or blend of these propylene polymer resins with a non-propylene-containing resin.

Claims

1. A polyolefin fiber having an improved balance of properties comprising 90 to 99 weight percent polyolefin and 1 to 10 weight percent aromatic hydrocarbon resin.

2. The fiber of claim 1 wherein the polyolefin is a polypropylene resin selected from the group consisting of propylene copolymers or blend of propylene homopolymer or copolymer with a nonpropylene-containing polymer.

3. The fiber of claim 2 wherein the aromatic hydrocarbon resin has a weight average molecular weight from about 300 to 8000 and molecular weight distribution from about 1.2 to 5.0.

4. The fiber of claim 3 wherein the aromatic hydrocarbon resin is selected from the group consisting of selectively hydrogenated resins of polymerized styrenic-based polymers, resins obtained from polymerized mixed aromatic monomer feed streams, and resins obtained by polymerizing pure monomer feed streams and constitutes from 2.5 to 7.5 weight percent of the total weight of the fiber-forming composition.

5. The fiber of claim 4 wherein the aromatic hydrocarbon resin has a weight average molecular weight from about 500 to 4000 and molecular weight distribution from about 1.4 to 2.5.

6. The fiber of claim 5 wherein the aromatic hydrocarbon resin has a ring and ball softening point from about 75°

C. to about 140°

C.

7. The fiber of claim 3 wherein the polypropylene resin is a propylene homopolymer having an isotacticity of 92 percent or higher.

8. The fiber of claim 3 wherein the polypropylene is a blend of 70 percent or greater polypropylene homopolymer and 30 percent of less ethylene-alkyl acrylate copolymer.

9. The fiber of claim 8 wherein the ethylene-alkyl acrylate copolymer is a copolymer of ethylene and methyl acrylate.

10. The fiber of claim 1 which is obtained by melt-spinning.

11. The fiber of claim 1 having a denier per filament of 6 or less and melt flow rate of 15 to 50 g/10 min.

12. The fiber of claim 1 having a denier per filament between 6 and 30 and melt flow rate of 9 to 25 g/10 min.

13. A polypropylene fiber having an improved balance of properties comprising 90 to 99 weight percent propylene homopolymer having an isotacticity of 92 percent or higher and 1 to 10 weight percent of an aromatic hydrocarbon resin having a weight average molecular weight from about 300 to 8000, molecular weight distribution from about 1.2 to 5.0 and selected from the group consisting of selectively hydrogenated resins of polymerized styrenic-based polymers, resins obtained from polymerized mixed aromatic monomer/feed streams, and resins obtained by polymerizing pure monomer feed streams.

14. The fiber of claim 13 wherein the aromatic hydrocarbon resin has a ring and ball softening point from about 75°

C. to about 140°

C., an acid number less than 1 and saponification number less than 2.