Transparent plastic or polymer based mirror apparatus and method for making the same

• US 6,409,354 B1
• Filed: 07/27/2001
• Issued: 06/25/2002
• Est. Priority Date: 08/23/2000
• Status: Expired due to Fees

• Current Assignee: Vtec Technologies, LLC
• Original Assignee: VTEC Technologies, Inc.
• Inventors: Richard, David A.
• Primary Examiner(s): SIKDER, MOHAMMAD YUNUS
• Application Number:
  US09/916,777
• Publication Number:
  US 20020044367A1
• Time in Patent Office: 333 Days
• Field of Search: 359/883, 359/884, 359/585, 359/586, 359/587, 359/588, 359/589, 359/870, 359/359, 359/360, 359/580, 359/584, 427/160, 428/610, 428/627, 428/629
• US Class Current: 359/883
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: G02B 5/0841 comprising organic materials, e.g. polymers

Abstract

A polymer-based mirror formed from a synthetic thermoplastic or thermoset resin substrate, such as polymethyl methacrylate, which is resistant to warping and distortion from moisture. A composite multi-layer surface-hardening coating is formed on at least the anterior surface of the resin substrate. The mirror further includes a composite multi-layer reflective coating. A protective back-coat layer is deposited on a posterior surface of the mirror. A multi-layer weather-resistant coating may optionally be applied to the anterior surface of the polymer-based mirror in order to increase the weatherability and durability of the mirror. The various layers coating the synthetic resin substrate have their moisture permeabilities selected so that substantially equal amounts of moisture permeate through to both the anterior and posterior side of the synthetic resin substrate.

Claims

1. A polymer-based mirror, comprising:

a transparent synthetic resin substrate having an anterior surface and a posterior surface;

a multi-layer abrasion resistant coating formed adjacent to said anterior surface of said synthetic resin substrate, wherein at least one layer of said multi-layer abrasion resistant coating includes zirconia;

a multi-layer reflective coating formed adjacent to one of said posterior surface of said synthetic resin substrate and said abrasion resistant coating, wherein at least one layer of said multi-layer reflective coating includes zirconia; and

a protective back-coat layer formed over an outer surface of said reflective coating.

2. The polymer-based mirror of claim 1, wherein said reflective coating, said back-coat layer, and said abrasion resistant coating possess respective moisture permeability characteristics which allow substantially equal amounts of moisture to permeate through to said anterior and posterior surfaces of said synthetic resin substrate.

3. The polymer-based mirror of claim 2, wherein said abrasion resistant coating provides a surface-hardening layer for said synthetic resin substrate.

4. The polymer-based mirror of claim 3, wherein said abrasion resistant coating comprises sequential layers of SiO, SiO₂, and Z_v(iPv)₂.

5. The polymer-based mirror of claim 4, wherein said abrasion resistant coating comprises a SiO layer having a thickness between 500 to 1200 angstroms, a SiO₂ layer having a thickness between 300 to 1200 angstroms, and a Z_v(iPv)₂ layer having a thickness between 600 to 1400 angstroms.

6. The polymer-based mirror of claim 5, wherein said SiO layer has a thickness of approximately 750 angstrom, said SiO₂ layer has a thickness of approximately 550 angstrom, and said Z_v(iPv)₂ layer has a thickness of approximately 725 angstrom.

7. The polymer-based mirror of claim 1, further comprising a tie-bond layer formed on at least one of said anterior surface and said posterior surface of said synthetic resin substrate.

8. The polymer-based mirror of claim 7, wherein said tie-bond layer comprises an organosilicon polymer material.

9. The polymer-based mirror of claim 8, wherein organosilicon polymer material is triethoxymethyl silane.

10. The polymer-based mirror of claim 1, wherein said reflective coating comprises a multilayer film of sequentially deposited layers of SiO, Al, SiO, Z_v(iPv)₂, and SiO₂.

11. The polymer-based mirror of claim 10, wherein said reflective coating sequentially comprises a SiO layer having a thickness between 500 to 1200 angstroms, an Al layer having a thickness between 700 to 1500 angstroms, an SiO layer having a thickness between 500 to 1200 angstroms, a Z_v(iPv)₂ layer having a thickness between 600 to 1400 angstroms, and a SiO₂ layer having a thickness between 300 to 1200 angstroms.

12. The polymer-based mirror of claim 11, wherein said reflective coating sequentially comprises a SiO layer of approximately 750 angstroms, an Al layer of approximately 1200 angstroms, an SiO layer of approximately 750 angstroms, a Z_v(iPv)₂ layer of approximately 725 angstroms, and a SiO₂ layer of approximately 550 angstroms.

13. The polymer-based mirror of claim 1, wherein said back-coat layer comprises a resin based paint-like coating.

14. The polymer-based mirror of claim 13, wherein said resin based paint-like coating includes a powdered inorganic filler material.

15. The polymer-based mirror of claim 14, wherein said powdered inorganic filler material may comprise one of calcium carbonate, barium carbonate, and aluminum silicate.

16. The polymer-based mirror of claim 1, further comprising a posterior surface-hardening layer formed on said posterior side of said synthetic resin substrate.

17. The polymer-based mirror of claim 16, wherein said posterior surface-hardening layer comprises a multi-layer coating with at least one of its layers including zirconia.

18. The polymer-based mirror of claim 17, wherein said reflective coating, said back-coat layer, said abrasion resistant coating, and said posterior surface-hardening film possess respective moisture permeability characteristics which allow substantially equal amounts of moisture to permeate through to said anterior and posterior surfaces of said synthetic resin substrate.

19. The polymer-based mirror of claim 17, wherein said posterior surface-hardening film comprises sequential layers of SiO₂, and Z_v(iPv)₂.

20. The polymer-based mirror of claim 19, wherein said posterior surface-hardening film comprises a SiO₂ layer having a thickness between 300 to 1200 angstroms and a Z_v(iPv)₂ layer having a thickness between 600 to 1400 angstroms.

21. The polymer-based mirror of claim 20, wherein said posterior surface-hardening film comprises a SiO₂ layer having a thickness of approximately 550 angstrom and a Z_v(iPv)₂ layer having a thickness of approximately 725 angstrom.

22. The polymer-based mirror of claim 1, wherein each of said reflective coating and said protective coating are substantially impermeable to moisture.

23. The polymer-based mirror of claim 1, wherein said synthetic resin substrate comprises transparent thermoplastic or thermoset resin.

24. The polymer-based mirror of claim 23, wherein said synthetic resin substrate comprises one of a polymethyl methacrylate (PMMA) material, a transparent crystalline polymer, and a cyclic olefin copolymer.

25. The polymer-based mirror of claim 1, wherein said abrasion resistant coating has hygroscopic characteristics to reduce fogging.

26. The polymer-based mirror of claim 1, wherein said synthetic resin substrate has a planar configuration with said anterior surface and said posterior surface being substantially parallel to each other.

27. The polymer-based mirror of claim 1, wherein said synthetic resin substrate has a wedge-shaped configuration.

28. The polymer-based mirror of claim 1, wherein one of said anterior surface and said posterior surface of said synthetic resin substrate is curved.

29. The polymer-based mirror of claim 28, wherein said anterior surface of said synthetic resin substrate is spherical.

30. The polymer-based mirror of claim 29, wherein said synthetic resin substrate is bi-convex.

31. The polymer-based mirror of claim 1, wherein said synthetic resin substrate is toric.

32. The polymer-based mirror of claim 1, wherein said synthetic resin substrate is formed by a combined injection molding and compression molding process.

33. The polymer-based mirror of claim 1, wherein said synthetic resin substrate is tinted blue to provide a transmittance between 50% to 95%.

34. The polymer-based mirror of claim 1, wherein said anterior surface of said synthetic resin substrate is aspheric and can be described by the following mathematical formula:

$z<br><br>\left(x\right)=\frac{c<br><br>\text{\hspace{1em}<br><br>}<br><br>x^2}{1+\sqrt{1-c^2<br><br>\left(k+1\right)<br><br>x^2}}+a_1<br><br>x^4+a_2<br><br>x^6+a_3<br><br>x^8+a_4<br><br>x^{10}$$c<br><br>\text{\hspace{1em}<br><br>}<br><br>x^2$

wherein c is a spherical coefficient, k is a conic coefficient, a_n is an aspheric coefficient, x is the distance (radius) from the center of the synthetic resin substrate, and z is the depth.

35. The polymer-based mirror of claim 1, further comprising a weather-resistant coating formed on an outer, anterior surface of said polymer-based mirror.

36. The polymer-based mirror of claim 35, wherein said weather-resistant coating is formed over said abrasion resistant coating.

37. The polymer-based mirror of claim 35, wherein said weather-resistant coating comprises a multi-layer hydrophilic coating having a hydrophobic coating formed on its outer surface.

38. The polymer-based mirror of claim 37, wherein said multi-layer hydrophilic coating comprises alternative layers of silicon dioxide and zirconia.

39. The polymer-based mirror of claim 38, wherein said hydrophobic coating comprises perfluoroalkylsilane.

40. The polymer-based mirror of claim 39, wherein said perfluoroalkylsilane hydrophobic coating has a thickness of approximately 5-20 nm.

41. The polymer-based mirror of claim 40, wherein said multi-layer hydrophilic coating sequentially comprises from its outer surface toward its inner surface:

a silicon dioxide layer of approximately 907 angstrom, a zirconia layer of approximately 765 angstrom, a silicon dioxide layer of approximately 174 angstrom, a zirconia layer of approximately 246 angstrom, and a silicon dioxide layer of approximately 2616 angstrom.

42. The polymer-based mirror of claim 37, wherein said hydrophobic coating and said multi-layer hydrophilic coating are dry coatings which are vacuum coated onto the abrasion resistant coating.

43. The polymer-based mirror of claim 35, wherein said weather-resistant coating, said abrasion resistant coating, said reflective coating, and said protective back-coat layer are dry coatings which are vacuum coated onto said resin substrate.

44. The polymer-based mirror of claim 37, wherein said hydrophobic coating and said multi-layer hydrophilic coating have substantially equal thermal coefficients of expansion.