Method for reducing the quantity of residual monomers in aqueous polymeric dispersions

• US 6,433,132 B1
• Filed: 08/17/2001
• Issued: 08/13/2002
• Est. Priority Date: 08/28/1998
• Status: Expired due to Fees

• Current Assignee: BASF AG (BASF SE)
• Original Assignee: BASF AG (BASF SE)
• Inventors: Wood, Claudia, Baumstark, Roland, Dobbelaar, Johannes
• Primary Examiner(s): Boykin, Terressa M.
• Application Number:
  US09/784,452
• Time in Patent Office: 361 Days
• Field of Search: 524/800, 524/832, 528/480
• US Class Current: 528/480
• CPC Class Codes: C08F 6/006 Removal of residual monomers by chemical reaction, e.g. scavenging

Abstract

A process for reducing the amount of residual monomer in aqueous polymer dispersions operates by aftertreatment with an initiator system essentially comprising

a) from 0.001 to 5% by weight, based on the total monomer amount used to prepare the polymer dispersion,

a₁) of an oxidizing agent

R¹OOH,

 where R¹ is hydrogen or a C₁-C₈-alkyl or a C₆-C₁₂-aryl group, and/or

a₂) of a compound which in aqueous medium releases hydrogen peroxide, and

b) from 0.005 to 5% by weight, based on the total monomer amount used to prepare the polymer dispersion, of a reducing agent prepared from

b₁) an aldehyde

R²CH═O,

 where R² is a C₁-C₁₂-alkyl group which may contain functional groups and/or may be olefinically unsaturated, and

b₂) an inorganic dithionite, and

c) catalytic amounts of a polyvalent metal ion which is able to exist in a plurality of valence states.

Claims

1. A process for reducing the amount of residual monomer in aqueous polymer dispersions by aftertreatment with an initiator system, which comprises said aftertreatment in the aqueous polymer dispersion being accompanied by the addition of an initiator system essentially comprising

a) from 0.001 to 5% by weight, based on the total monomer amount used to prepare the polymer dispersion,

a₁) of an oxidizing agent

2. A process as claimed in claim 1, wherein the oxidizing agent is inorganic compound.

3. A process as claimed in claim 1, wherein the oxidizing agent is hydrogen peroxide.

4. A process as claimed in claim 1, wherein R² is a methyl group.

5. A process as claimed in claim 1, wherein, in the reducing agent, aldehyde and dithionite are employed in a molar ratio of from 0.1:

1 to 1;

0.1.

6. A process as claimed in claim 1, wherein sodium dithionite is used to prepare the reducing agent.

7. A process as claimed in claim 1, wherein the oxidizing agent and the reducing agent are supplied simultaneously in separate feed streams to the polymer dispersion during the aftertreatment.

8. A process as claimed in claim 1, wherein the metal ions are added to the polymer dispersion in the aftertreatment prior to the oxidizing and reducing agent.

9. A process as claimed in claim 1, wherein iron ions are employed as polyvalent metal ion.

10. A process as claimed in claim 1, wherein the iron ions are added in complexed form.

11. A process as claimed in claim 1, wherein the temperature of the polymer dispersion during the aftertreatment is from 50 to 130°

C.

12. A process as claimed in claim 1, wherein the aftertreatment is conducted at superatmospheric pressure, at atmospheric pressure (1 bar absolute) or at subatmospheric pressure.

13. A process as claimed in claim 1, wherein the pH of the polymer dispersion during the aftertreatment is ≧

2 and ≦

8.