Electrochromic transparency incorporating security system

• US 6,535,126 B2
• Filed: 12/15/2000
• Issued: 03/18/2003
• Est. Priority Date: 12/15/2000
• Status: Expired due to Fees

• Current Assignee: PPG Industries Ohio Incorporated (Nouryon BV)
• Original Assignee: PPG Industries Ohio Incorporated (Nouryon BV)
• Inventors: Jiao, Yu, Rukavina, Thomas G., Lin, Chia Cheng
• Primary Examiner(s): PHAM, TOAN NGOC
• Application Number:
  US09/738,306
• Publication Number:
  US 20020021481A1
• Time in Patent Office: 823 Days
• Field of Search: 340/550, 340/540, 340/545.1, 340/545.4, 359/601-610, 359/267-273
• US Class Current: 340/550
• CPC Class Codes: B60R 25/1004 Alarm systems characterised by the type of sensor, e.g. current sensing means using door lock sensors B60R25/1001
• CPC Class Codes: B60R 25/102 a signal being sent to a remote location, e.g. a radio signal being transmitted to a police station, a security company or the owner
• CPC Class Codes: B60R 25/33 of global position, e.g. by providing GPS coordinates
• CPC Class Codes: G02F 1/163 Operation of electrochromic cells, e.g. electrodeposition cells; Circuit arrangements therefor
• CPC Class Codes: G08B 13/04 by breaking of glass

Abstract

An electrochromic window assembly includes a security system for monitoring breakage of the electrochromic window assembly. Control circuitry is connected to the electrochromic window assembly for monitoring an electrical characteristic of one or more conductive coatings within the electrochromic window assembly, such as electrical resistance. Upon detecting a change in the electrical resistance, such as that caused by a break in one or more conductive coating, an alarm signal is generated and is sent to an alarm trigger circuit for activating an alarm. A method for monitoring penetration or breakage of an electrochromic window assembly is also provided, which method involves applying electrical activation to an electrochromic assembly and monitoring for a change in an electrical characteristic based on the applied electrical potential. Electrochromic window assemblies incorporating security alarm features in accordance with the present invention are particularly useful in automobile applications.

Claims

1. An electrochromic security window assembly comprising:

first and second spaced transparent substrates defining a chamber therebetween, the first and the second substrates including first and second conductive coatings on respective facing surfaces thereof;

an electrochromic medium contained in the chamber comprising at least one anodic electrochromic compound and at least one cathodic electrochromic compound and having reduced light transmittance upon application of electrical activation between the first and second conductive coatings above a reduction potential capable of simultaneously oxidizing the anodic electrochromic compound and reducing the cathodic compound;

means for applying an electrical potential across the electrochromic medium comprising a voltage source connected in series with the first conductive coating, the second conductive coating and the electrochromic medium; and

means for detecting a change in an electrical characteristic of at least one of the first and second conductive coatings and for generating an output signal in response to a change in the electrical characteristic corresponding to a break in the at least one conductive coating comprising a first sensing element connected in series with the first conductive coating and the voltage source, and circuitry for detecting an electrical condition of the first sensing element corresponding to a flow of current through the first conductive coating, for producing the output signal as a function of the detected electrical condition of the first sensing element, for comparing the output signal to a predetermined electrical condition, and for activating an alarm when the output signal is greater than or less than the predetermined electrical condition.

2. An electrochromic security window assembly as in claim 1, wherein:

the means for detecting further includes a second sensing element connected in series with the second conductive coating and the voltage source; and

the circuitry for detecting detects an electrical condition of the second sensing element corresponding to a flow of current through the second conductive coating and produces the output signal as a function of the detected electrical condition of the second sensing element.

3. An electrochromic security window assembly as in claim 1, further including a means for switching which alternately connects the voltage source in series with (i) the first conductive coating, the second conductive coating and the electrochromic medium, and (ii) the first sensing element and the first conductive coating.

4. An electrochromic security window assembly as in claim 3, wherein the means for switching includes at least one switch.

5. An electrochromic security window assembly comprising:

first and second spaced transparent substrates defining a chamber therebetween, the first and the second substrates including first and second conductive coatings on respective facing surfaces thereof;

an electrochromic medium contained in the chamber comprising at least one anodic electrochromic compound and at least one cathodic electrochromic compound and having reduced light transmittance upon application of electrical activation between the first and second conductive coatings above a reduction potential capable of simultaneously oxidizing the anodic electrochromic compound and reducing the cathodic compound;

means for applying an electrical potential across the electrochromic medium comprising a current source configured to be connected in series with (i) the first conductive coating, the second conductive coating and the electrochromic medium, and (ii) the first conductive coating; and

means for detecting a change in an electrical characteristic of at least one of the first and second conductive coatings and for generating an output signal in response to a change in the electrical characteristic corresponding to a break in the at least one conductive coating comprising circuitry for detecting an electrical condition of the first conductive coating corresponding to a flow of current from the current source therethrough, for producing the output signal as a function of the detected electrical condition of the first conductive coating, for comparing the output signal to a predetermined electrical condition, and for activating an alarm when the output signal is greater than or less than the predetermined electrical condition.

6. An electrochromic security window assembly as in claim 5, wherein the circuitry for detecting detects an electrical condition of the second conductive coating corresponding to a flow of current from the current source therethrough and produces the output signal as a function of the detected electrical condition of the second conductive coating.

7. An electrochromic security window assembly as in claim 5, further including a means for switching which alternately connects the current source in series with (i) the first conductive coating, the second conductive coating and the electrochromic medium, and (ii) the first conductive coating.

8. An electrochromic security window assembly as in claim 7, wherein the means for switching includes at least one switch.

9. An electrochromic security window assembly comprising:

first and second spaced transparent substrates defining a chamber therebetween, the first and the second substrates including first and second conductive coatings on respective facing surfaces thereof;

an electrochromic medium contained in the chamber comprising at least one anodic electrochromic compound and at least one cathodic electrochromic compound and having reduced light transmittance upon application of electrical activation between the first and second conductive coatings above a reduction potential capable of simultaneously oxidizing the anodic electrochromic compound and reducing the cathodic compound;

a power supply configured to produce an electrical potential across the electrochromic medium; and

means for detecting a change in an electrical characteristic of at least one of the first and second conductive coatings and for generating an output signal in response to a change in the electrical characteristic corresponding to a break in the at least one conductive coating.

10. An electrochromic security window assembly as in claim 9, wherein the power supply is a voltage source or a current source.

11. An electrochromic security window assembly as in claim 9, wherein the means for detecting detects a change in an electric current through the at least one conductive coating.

12. An electrochromic security window assembly as in claim 11, wherein the means for detecting is a resistor connected in series with the at least one conductive coating.

13. An electrochromic security window assembly as in claim 9, wherein the first and second transparent substrates are selected from the group consisting of glass and polymeric materials.

14. An electrochromic security window assembly as in claim 13, wherein the glass is float glass.

15. An electrochromic security window assembly as in claim 9, wherein the first and the second substrates are glass, and further comprising a transparent polymeric layer.

16. An electrochromic security window assembly as in claim 15, wherein the transparent polymeric layer is laminated to an outer surface of the first transparent substrate.

17. An electrochromic security window assembly as in claim 15, further comprising a glass outer substrate, the transparent polymeric layer laminated between the glass outer substrate and the outer surface of the first transparent substrate.

18. An electrochromic security window assembly as in claim 9, wherein the cathodic electrochromic compound is a viologen compound and the anodic electrochromic compound is a phenazine compound.

19. An electrochromic security window assembly as in claim 9, wherein the electrochromic window assembly is selected from the group consisting of automotive windshields, automotive side windows, automotive rear windows, automotive sunroofs, architectural glazings, architectural windows, and architectural skylights.

20. An electrochromic security window assembly comprising:

first and second spaced transparent substrates defining a chamber therebetween, the first and the second substrates including first and second conductive coatings on respective facing surfaces thereof;

an electrochromic medium contained in the chamber comprising at least one anodic electrochromic compound and at least one cathodic electrochromic compound and having reduced light transmittance upon application of electrical activation between the first and second conductive coatings above a reduction potential capable of simultaneously oxidizing the anodic electrochromic compound and reducing the cathodic compound;

means for applying an electrical potential across the electrochromic medium; and

means for detecting a change in an electrical characteristic of at least one of the first and second conductive coatings and for generating an output signal in response to a change in the electrical characteristic corresponding to a break in the at least one conductive coating, comprising a sensing element connected for detecting a flow of current through the electrochromic medium, and circuitry for detecting an electrical condition of the sensing element corresponding to the flow of current through the electrochromic medium, for producing the output signal indicative of the electrical condition, for comparing the output signal to a predetermined electrical condition, and for activating an alarm when the output signal is greater than or less than the predetermined electrical condition.

21. An electrochromic security window assembly as in claim 20, wherein the sensing element is a resistor.

22. An electrochromic security window assembly comprising:

first and second spaced transparent substrates defining a chamber therebetween, the first and the second substrates including first and second conductive coatings on respective facing surfaces thereof;

an electrochromic medium contained in the chamber comprising at least one anodic electrochromic compound and at least one cathodic electrochromic compound and having reduced light transmittance upon application of electrical activation between the first and second conductive coatings above a reduction potential capable of simultaneously oxidizing the anodic electrochromic compound and reducing the cathodic compound;

means for applying an electrical potential across the electrochromic medium; and

means for detecting a change in an electrical characteristic of at least one of the first and second conductive coatings and for generating an output signal in response to a change in the electrical characteristic corresponding to a break in the at least one conductive coating comprising circuitry for detecting an electrical condition corresponding to a flow of current through the electrochromic medium, for producing the output signal indicative of the electrical condition, for comparing the output signal to a predetermined electrical condition, and for activating an alarm when the output signal is greater than or less than the predetermined electrical condition.

23. An electrochromic security window assembly comprising:

first and second spaced transparent substrates defining a chamber therebetween, the first and the second substrates including first and second conductive coatings on respective facing surfaces thereof;

an electrochromic medium contained in the chamber comprising at least one anodic electrochromic compound and at least one cathodic electrochromic compound and having reduced light transmittance upon application of electrical activation between the first and second conductive coatings above a reduction potential capable of simultaneously oxidizing the anodic electrochromic compound and reducing the cathodic compound;

means for applying an electrical potential across the electrochromic medium, wherein the electrical potential applied to the at least one conductive coating is adjustable between a voltage below the reduction potential capable of simultaneously oxidizing the anodic electrochromic compound and reducing the cathodic electrochromic compound when the window assembly is in a state of increased light transmittance and a voltage above the reduction potential capable of simultaneously oxidizing the anodic electrochromic compound and reducing the cathodic electrochromic compound when the window assembly is in a state of reduced light transmittance and vice versa; and

means for detecting a change in an electrical characteristic of at least one of the first and second conductive coatings and for generating an output signal in response to a change in the electrical characteristic corresponding to a break in the at least one conductive coating.

24. An electrochromic security window assembly comprising:

first and second spaced transparent substrates defining a chamber therebetween, the first and the second substrates including first and second conductive coatings on respective facing surfaces thereof;

an electrochromic medium contained in the chamber comprising at least one anodic electrochromic compound and at least one cathodic electrochromic compound and having reduced light transmittance upon application of electrical activation between the first and second conductive coatings above a reduction potential capable of simultaneously oxidizing the anodic electrochromic compound and reducing the cathodic compound;

means for alternately applying the electrical potential across the electrochromic medium;

(i) across the first and second conductive coatings at a voltage above the reduction potential capable of simultaneously oxidizing the anodic electrochromic compound and reducing the cathodic electrochromic compound when the window assembly is in a state of reduced light transmittance; and

(ii) to the at least one conductive coating at a voltage capable of detecting a change in the electrical characteristic; and

means for detecting a change in an electrical characteristic of at least one of the first and second conductive coatings and for generating an output signal in response to a change in the electrical characteristic corresponding to a break in the at least one conductive coating.

25. A method for monitoring penetration of a window assembly capable of variable light transmittance comprising:

a) providing an electrochromic security window assembly comprising;

(i) first and second spaced transparent substrates defining a chamber therebetween, the first and the second substrates including first and second conductive coatings on respective facing surfaces thereof; and

(ii) an electrochromic medium contained within the chamber comprising at least one anodic electrochromic compound and at least one cathodic electrochromic compound and having reduced light transmittance upon application of electrical potential between the first and second conductive coatings above a reduction potential capable of simultaneously oxidizing the anodic electrochromic compound and reducing the cathodic compound;

b) alternately applying the electrical potential to (i) the first conductive coating, the electrochromic medium and the second conductive coating connected in series and (ii) the at least one of the first and second conductive coating;

c) monitoring for a change in an electrical characteristic of the at least one of the first and second conductive coatings having the electrical potential applied thereto; and

d) generating an output signal upon the change in the electrical characteristic.

26. A method as in claim 25, wherein the first and second conductive coatings are connected in parallel.

27. A method as in claim 25, wherein:

step (b) includes applying the electrical potential to the first conductive coating, the electrochromic medium and the second conductive coating connected in series; and

step (c) includes monitoring for a change in the current through the electrochromic medium.

28. A method for monitoring penetration of a window assembly capable of variable light transmittance comprising:

a) providing an electrochromic security window assembly comprising;

(i) first and second spaced transparent substrates defining a chamber therebetween, the first and the second substrates including first and second conductive coatings on respective facing surfaces thereof; and

(ii) an electrochromic medium contained within the chamber comprising at least one anodic electrochromic compound and at least one cathodic electrochromic compound and having reduced light transmittance upon application of electrical potential between the first and second conductive coatings above a reduction potential capable of simultaneously oxidizing the anodic electrochromic compound and reducing the cathodic compound;

b) applying an electrical potential to at least one of the first and second conductive coatings, wherein the electrical potential applied to the first and second conductive coatings is adjustable between a voltage above the reduction potential capable of simultaneously oxidizing the anodic electrochromic compound and reducing the cathodic electrochromic compound when the window assembly is in a state of reduced light transmittance and a voltage below the reduction potential capable of simultaneously oxidizing the anodic electrochromic compound and reducing the cathodic electrochromic compound to intermittently monitor for a change in the electrical characteristic of the at least one of the first and second conductive coatings and vice versa;

c) monitoring for a change in an electrical characteristic of the at least one of the first and second conductive coatings having the electrical potential applied thereto; and

d) generating an output signal upon the change in the electrical characteristic.

29. A method as in claim 28, wherein step (c) includes monitoring for a change in current through the first conductive coating and/or the second conductive coating.

30. A method as in claim 28, wherein the output signal activates an alarm.

31. A method as in claim 28, wherein the first and second transparent substrates are selected from the group consisting of glass and polymeric materials.

32. A method as in claim 28, wherein the electrochromic window assembly is selected from the group consisting of automotive windshields, automotive side windows, automotive rear windows, automotive sunroofs, architectural glazings, architectural windows, and architectural skylights.