Method molding a glass composition into an optical element with reduced pull-out

• US 6,588,231 B1
• Filed: 11/12/1999
• Issued: 07/08/2003
• Est. Priority Date: 09/18/1995
• Status: Expired due to Fees

• Current Assignee: Hoya Corporation
• Original Assignee: Hoya Corporation
• Inventors: Hashimoto, Kazuaki, Oogami, Yu, Hirota, Shin-Ichiro
• Primary Examiner(s): VINCENT, SEAN E
• Application Number:
  US09/437,947
• Time in Patent Office: 1,334 Days
• Field of Search: 65/251, 65/325, 65/66, 651/27, 651/345, 651/822
• US Class Current: 65/25.1
• CPC Class Codes: C03B 11/08 for making solid articles, e.g. lenses
• CPC Class Codes: C03B 11/086 of coated dies use of materials as release or lubricating compositions C03B40/02
• CPC Class Codes: C03B 2215/12 Ceramics or cermets, e.g. cemented WC, Al2O3 or TiC
• CPC Class Codes: C03B 2215/24 Carbon, e.g. diamond, graphite, amorphous carbon
• CPC Class Codes: C03B 2215/34 of ceramic or cermet material, e.g. diamond-like carbon
• CPC Class Codes: C03B 40/02 by lubrication; Use of materials as release or lubricating compositions
• CPC Class Codes: C03C 3/068 containing rare earths
• CPC Class Codes: C03C 3/091 containing aluminium
• CPC Class Codes: C03C 3/095 containing rare earths
• CPC Class Codes: Y02P 40/57 Improving the yield, e-g- reduction of reject rates
• CPC Class Codes: Y10S 501/903 having refractive index less than 1.8 and ABBE number less than 70

Abstract

A mold has a moling surface of a material containing silicon carbide and/or silicon nitride as a main component and a carbon thin film formed on the molding surface to prevent fusion sticking. A glass substance which has a sag point not higher than 565° C. and a predetermined composition free from arsenic oxide is introduced into the mold. The glass substance is press-formed in a heated and softened condition into a glass optical element of high precision.

Claims

1. A method of manufacturing a glass optical element with high precision by press molding a glass substance, comprising the steps of:

preparing a mold that has a molding surface which comprises silicon and which is polished into a mirror surface,

preparing a dehydrated glass substance as the glass substance, heating and softening the dehydrated glass substance, and press molding the dehydrated glass substance with the molding surface to form the glass optical element.

2. The method of claim 1 the molding surface is covered with a releasing film.

3. The method of claim 2 wherein the molding surface comprises silicon carbide or silicon nitride.

4. The method of claim 3 wherein the dehydrated glass substance comprises substantially no arsenic oxide.

5. The method of claim 4 wherein the dehydrated glass substance comprises an amount of an antimony oxide.

6. The method of claim 3 wherein preparing the glass substance comprises forming glass perform by dripping a glass melt over a reception plate and by shaping the glass melt over a gas spouted from the reception plate.

7. The method of claim 3 wherein the dehydrated glass substance contains a total content of hydroxyl groups and water molecules not greater than 50 ppm in terms of water molecules.

8. The method of claim 7 wherein the press molding is carried out within a non-oxidizing atmosphere.

10. The method of claim 3 wherein the releasing film comprises a layer comprising carbon.

9. The method of 7 wherein the dehydrated glass substance has a total content of hydroxyl groups and water molecules not greater than 25 ppm in terms of water molecule.

11. The method of 3 wherein the dehydrated glass substance has a sag point of not higher than 565°

C.

12. A method of manufacturing a glass optical element with high precision by press molding a glass substance, comprising the steps of:

preparing a mold that has a molding surface which comprises silicon and which is polished into a mirror surface,

preparing the glass substance having a total content of hydroxyl groups and water molecules not greater than 50 ppm in terms of water molecules,

heating and softening the glass substance, and press molding the glass substance with the molding surface to form the glass optical element.

13. The method of claim 12 wherein the molding surface is covered with a layer comprising carbon.

14. A method of manufacturing a glass optical element with high precision by press molding a glass substance, using a mold with surface defects reduced on a molding surface, comprising the steps of:

preparing a mold wherein the molding surface comprising silicon,

preparing a dehydrated glass substance;

heating and softening the dehydrated glass substance, and

press molding the dehydrated glass substance in the mold to form the glass optical element.

15. The method of claim 14 wherein the molding surface is covered with a releasing film.

16. The method of claim 15 wherein the molding surface comprises silicon carbide or silicon nitride.

17. The method of claim 16 wherein the releasing film comprises a layer comprising carbon.