Use of an amphoteric polymer to treat a hard surface

• US 6,593,288 B2
• Filed: 07/29/2002
• Issued: 07/15/2003
• Est. Priority Date: 07/15/1999
• Status: Expired due to Term

• Current Assignee: Rhodia Chimie (Solvac SA)
• Original Assignee: Rhodia Chimie (Solvac SA)
• Inventors: Aubay, Eric, Yeung, Dominic
• Primary Examiner(s): DELCOTTO, GREGORY R
• Application Number:
  US10/207,303
• Publication Number:
  US 20030083223A1
• Time in Patent Office: 351 Days
• Field of Search: 510/237, 510/180, 510/181, 510/426, 510/427, 510/499, 510/503, 510/504, 510/433, 510/476, 134/42
• US Class Current: 510/504
• CPC Class Codes: C11D 1/02 Anionic compounds C11D1/002, C11D1/004, C11D1/008 take precedence
• CPC Class Codes: C11D 1/66 Non-ionic compounds C11D1/002, C11D1/004, C11D1/008 take precedence
• CPC Class Codes: C11D 2111/20 Industrial or commercial equipment, e.g. reactors, tubes or engines
• CPC Class Codes: C11D 2111/24 Mineral surfaces, e.g. stones, frescoes, plasters, walls or concretes
• CPC Class Codes: C11D 3/3769 (Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
• CPC Class Codes: C11D 3/3796 Amphoteric polymers or zwitterionic polymers
• CPC Class Codes: C11D 3/39 Organic or inorganic per-compounds

Abstract

This invention relates to the use of a water-soluble or water-dispersible copolymer comprising, in the form of polymerized units:

(a) at least one monomer compound of general formula I:

(b) at least one hydrophilic monomer bearing a function of acidic nature which is copolymerizable with (a) and capable of ionizing in the application medium,

(c) optionally, at least one hydrophilic monomer compound containing ethylenic unsaturation and of neutral charge, bearing one or more hydrophilic groups, which is copolymerizable with (a) and (b),

the a/b molar ratio being between 60/40 and 5/95,

to give a hard surface hydrophilic properties.

Claims

1. A method for reducing the drying speed of a liquid cleaning composition which is applied onto a motor vehicle surface, comprising the step of adding to the composition applied to the motor vehicle surface an efficient amount of a water-soluble or water-dispersible copolymer comprising, in the form of polymerized units:

(a) at least one monomer compound of general formula I;

 

wherein;

R₁ and R₄, independently of each other, represent a hydrogen atom or a linear or branched C₁-C₆ alkyl group;

R₂ and R₃, independently of each other, represent an alkyl, hydroxyalkyl or aminoalkyl group wherein the alkyl group is a linear or branched C₁-C₆ chain;

n and m are integers between 1 and 3; and

X, which are identical or different, represent counterions which are compatible with the water-soluble or water-dispersible nature of the polymer;

(b) at least one hydrophilic monomer bearing a function of acidic nature which is copolymerizable with (a) and capable of ionizing in the application medium, and

(c) optionally, at least one hydrophilic monomer compound containing ethylenic unsaturation and of neutral charge, bearing one or more hydrophilic groups, which is copolymerizable with (a) and (b); and

wherein the a/b molar ratio is between 60/40 and 5/95, the composition comprising;

from 0% to 5% by weight relative to the total weight of said composition of the water-soluble or water-dispersible copolymer,

from 0% to 30% relative to the weight of the formulation, of at least one nonionic surfactant;

from 0% to 30% relative to the weight of the formulation, of at least one anionic surfactant;

from 0% to 30% by weight of an amphoteric or zwitterionic surfactant;

from 0% to 30% by weight of a cationic surfactant;

the minimum amount of surfactant being at least 1%;

from 0% to 50 relative to the weight of the formulation, of an inorganic or organic detergent adjuvant; and

optionally, a hydrotropic agent, fillers and pH regulators.

2. A method according to claim 1, wherein R₂ and R₃ represent a methyl group.

3. A method according to claim 1, wherein the monomer (a) is represented by the following formula:

X⁻

represent a counterion which is compatible with the water-soluble or water-dispersible nature of the polymer.

4. A method according to claim 1, wherein X⁻

represents a chloride.

5. A method according to claim 1, wherein (b) are C₃-C₈ carboxylic, sulfonic, sulfuric, phosphonic or phosphoric acids containing monoethylenic unsaturation.

6. A method according to claim 1, wherein the monomer (b) is acrylic acid, methacrylic acid, α

-ethacrylic acid, β

,β

-dimethylacrylic acid, methylenemalonic acid, vinylacetic acid, allylacetic acid, ethylideneacetic acid, propylideneacetic acid, crotonic acid, maleic acid, fumaric acid, itaconic acid, citraconic acid, mesaconic acid, N-methacryloylalanine, N-acryloylhydroxyglycine, sulfopropyl acrylate, sulfoethyl acrylate, sulfoethyl methacrylate, sulfoethyl methacrylate, styrenesulfonic acid, vinylsulfonic acid, vinylphosphonic acid, phosphoethyl acrylate, phosphonoethyl acrylate, phosphopropyl acrylate, phosphonopropyl acrylate, phosphoethyl methacrylate, phosphonoethyl methacrylate, phosphopropyl methacrylate or phosphonopropyl methacrylate.

7. A method according to claim 1, wherein the monomer (c) is chosen from acrylamide, vinyl alcohol, C₁-C₄ alkyl esters of acrylic acid and of methacrylic acid, C₁-C₄ hydroxyalkyl esters of acrylic acid and of methacrylic acid, in particular ethylene glycol and propylene glycol acrylate and methacrylate, polyalkoxylated esters of acrylic acid and of methacrylic acid.

8. A method according to claim 1, wherein X is chloride, sulfate, hydrogen sulfate, phosphate, citrate, formate or acetate anion.

9. A method according to claim 1, wherein the water-soluble or water-dispersible copolymer is obtained by copolymerization:

of 5 mol % to 60 mol %, of the monomer (a);

of 10 mol % to 95 mol %, of the monomer (b); and

of 0 mol % to 50 mol %, of the monomer (c), provided that the a/b molar ratio is between 60/40 and 5/95.

10. A method according to claim 1, wherein the water-soluble or water-dispersible copolymer is obtained by copolymerization:

of 20 mol % to 50 mol %, of the monomer (a);

of 20 mol % to 80 mol % of the monomer (b); and

of 5 mol % to 30 mol %, of the monomer (c).

11. A method according to claim 1, wherein the a/b molar ratio is between 50/50 and 10/90.

12. A method according to claim 1, wherein the molecular mass of the copolymer is at least 1000, and not more than 20,000,000.

13. A method according to claim 1, wherein the molecular mass of the copolymer is at least 10,000 and not more than 10,000,000.

14. A method according to claim 1, wherein the copolymer/surfactant weight ratio is between 1/2 and 1/100.