Corrosion-protected coaxial cable, method of making same and corrosion-inhibiting composition

• US 6,596,393 B1
• Filed: 04/20/2000
• Issued: 07/22/2003
• Est. Priority Date: 04/20/2000
• Status: Expired due to Term

• Current Assignee: CommScope Inc. (CommScope Holding Company, Inc.)
• Original Assignee: Commscope Solutions Properties LLC (CommScope Holding Company, Inc.)
• Inventors: Houston, Eddy, Maresca, Benedict
• Primary Examiner(s): Kelly, Cynthia H.
• Assistant Examiner(s): GRAY, JILL M
• Application Number:
  US09/552,903
• Time in Patent Office: 1,188 Days
• Field of Search: 428/375, 428/379, 428/383, 428/389, 174/102.R, 174/102.C, 174/102.SP, 174/102.A, 174/107, 174/109, 174/23.R, 174/23.C, 174/28
• US Class Current: 428/389
• CPC Class Codes: C23F 11/149 Heterocyclic compounds containing nitrogen as hetero atom
• CPC Class Codes: C23F 11/161 Mercaptans
• CPC Class Codes: C23F 11/163 Sulfonic acids
• CPC Class Codes: H01B 7/28 Protection against damage caused by moisture, corrosion, chemical attack or weather
• CPC Class Codes: H01B 7/2806 Protection against damage caused by corrosion
• CPC Class Codes: Y10T 428/2933 Coated or with bond, impregnation or core
• CPC Class Codes: Y10T 428/294 including metal or compound thereof [excluding glass, ceramic and asbestos]
• CPC Class Codes: Y10T 428/2958 Metal or metal compound in coating

Abstract

The present invention is a corrosion-protected cable, a method of making a corrosion-inhibiting cable, and a corrosion-inhibiting composition. The corrosion-inhibiting composition includes a water-insoluble corrosion-inhibiting compound dispersed in an oil, and a stabilizer selected from the group consisting of propylene based glycol ethers, propylene based glycol ether acetates, ethylene based glycol ethers and ethylene based glycol ether acetates. The corrosion-inhibiting composition is preferably applied to the outer conductor of the coaxial cable, e.g., by wiping or by immersion, and heated to provide a corrosion-inhibiting coating that is not tacky or greasy.

Claims

1. A coaxial cable, comprising:

an elongate center conductor;

a dielectric layer surrounding said center conductor;

an outer conductor comprising aluminum or an aluminum alloy surrounding said dielectric layer; and

a corrosion-inhibiting coating on at least an outer portion of said outer conductor and comprising a water-insoluble corrosion-inhibiting compound selected from the group consisting of petroleum sulfonates and salts thereof, said corrosion inhibiting coating further including residual amounts of an oil dispersant, and residual amounts of a stabilizer selected from the group consisting of propylene glycol ethers, propylene glycol ether acetates, ethylene glycol ethers and ethylene glycol ether acetates.

2. The coaxial cable according to claim 1, wherein the corrosion-inhibiting compound is a petroleum sulfonate salt.

3. The coaxial cable according to claim 2, wherein the petroleum sulfonate salt is selected from the group consisting of calcium, barium, magnesium, sodium, potassium and ammonium salts, and mixtures thereof.

4. The coaxial cable according to claim 2, wherein the petroleum sulfonate salt comprises a calcium salt.

5. The coaxial cable according to claim 4, wherein the petroleum sulfonate salt has an activity of greater than 0 to about 25% based on the calcium salt.

6. The coaxial cable according to claim 4, wherein the petroleum sulfonate salt further comprises a salt selected from the group consisting of barium and sodium salts.

7. The coaxial cable according to claim 1, wherein said dielectric layer comprises a foamed polymeric material.

8. The coaxial cable according to claim 1, wherein said center conductor is formed of a material selected from the group consisting of copper,a copper alloy, a copper-clad metal, and a copper alloy-clad metal.

9. The coaxial cable according to claim 1, further comprising a corrosion-inhibiting layer between the center conductor and the dielectric layer comprising a benzotriazole compound and a polymeric compound.

10. The coaxial cable according to claim 9, wherein said benzotriazole compound is benzotriazole.

11. The coaxial cable according to claim 9, wherein said polymeric compound is a foamed, low-density polyethylene.

12. The coaxial cable according to claim 1, wherein said outer conductor includes a bonded aluminum-polymer-aluminum laminate tape extending longitudinally of the cable.

13. The coaxial cable according to claim 12, wherein said laminate tape has overlapping longitudinal edges.

14. The coaxial cable according to claim 12, wherein said corrosion-inhibiting coating is on an outer surface of said laminate tape.

15. The coaxial cable according to claim 12, wherein said outer conductor further comprises a braid surrounding said laminate tape and formed of wires coated with said corrosion-inhibiting coating.

16. The coaxial cable according to claim 12, further comprising a plurality of wires helically arranged around said laminate tape and coated with said corrosion-inhibiting coating.

17. The coaxial cable according to claim 1, wherein said outer conductor includes a longitudinally-welded sheath, and said corrosion-inhibiting coating is on an outer surface of said sheath.

18. The coaxial cable according to claim 1, further comprising a polymer jacket surrounding said outer conductor.

19. The coaxial cable according to claim 1, wherein said water-insoluble corrosion-inhibiting compound is present in an amount of from about 15% to about 30% by weight.

20. A coaxial cable, comprising:

an elongate center conductor;

a dielectric layer surrounding said center conductor;

an outer conductor comprising aluminum or an aluminum alloy surrounding said dielectric layer; and

a corrosion-inhibiting coating on at least an outer portion of said outer conductor, said corrosion-inhibiting coating formed by beating a composition comprising a water-insoluble petroleum sulfonate corrosion-inhibiting compound dispersed in an oil, and a stabilizer selected from the group consisting of propylene glycol ethers, propylene glycol ether acetates, ethylene glycol ethers and ethylene glycol ether acetates such that a substantial portion of the oil and the stabilizer evaporate to leave a non-tacky, non-greasy corrosion-inhibiting coating comprising said corrosion-inhibiting compound on said outer conductor.

21. The coaxial cable according to claim 20, wherein said water-insoluble corrosion-inhibiting compound is present in an amount of from about 15% to about 30% by weight.

22. A coaxial cable, comprising;

an elongate center conductor;

a dielectric layer surrounding said center conductor;

an outer conductor comprising aluminum or an aluminum alloy surrounding said dielectric layer; and

a corrosion-inhabiting composition comprising a water-insoluble corrosion-inhibiting compound consisting essentially of a petroleum sulfonate dispersed in an oil, and a stabilizer selected from the group consisting of propylene glycol ethers, propylene glycol ether acetates, ethylene glycol ethers and ethylene glycol ether acetates.

23. The coaxial cable according to claim 22 wherein said water-insoluble corrosion-inhibiting compound is present in an amount of from about 15% to about 30% by weight.