Method and composition for rejuvenating weathered polymeric materials

• US 6,669,991 B2
• Filed: 03/22/2002
• Issued: 12/30/2003
• Est. Priority Date: 03/22/2002
• Status: Expired due to Term

• Current Assignee: Donna M. Stuart
• Original Assignee: Donna M. Stuart
• Inventors: Stuart, Alan
• Primary Examiner(s): CAMERON, ERMA C
• Application Number:
  US10/102,714
• Publication Number:
  US 20030180452A1
• Time in Patent Office: 648 Days
• Field of Search: 427/384, 427/429
• US Class Current: 427/384
• CPC Class Codes: C08J 2327/06 Homopolymers or copolymers of vinyl chloride
• CPC Class Codes: C08J 7/02 with solvents, e.g. swelling agents
• CPC Class Codes: C08J 7/065 Low-molecular-weight organic substances, e.g. absorption of additives in the surface of the article

Abstract

A method for rejuvenating a vinyl resin surface, the method comprising applying a composition to the surface, where the composition includes at least one organic solvent compound that has a solubility parameter (δ) of from about 8.0 to about 10.6 (cal/cm³)^½.

Claims

1. A method for rejuvenating the surface of vinyl siding, the method comprising:

applying a composition to the surface of the vinyl siding, where the composition consists essentially of one or more organic solvent compounds that have a solubility parameter (δ

) of from about 8.0 to about 10.6 (cal/cm³)^½

, optionally one or more diluents selected from the group consisting of aliphatic distillates, aromatic distillates, naphtha, pine oil, tricresyl phosphate, and mixtures thereof, and optionally one or more antioxidants, thermal stabilizers, bacteriostats, ultraviolet absorbers, and a mixture thereof.

2. The method of claim 1, where the organic solvent compound is a polar compound.

3. The method of claim 1, where the organic solvent compound is selected from the group consisting of an ether, a heterocyclic ether, an aldehyde, a ketone, an ester, a chlorinated hydrocarbon, an amide, a cyclic amide, a compound that is both an ether and an ester, and a mixture thereof.

4. The method of claim 1, where the organic solvent compound is selected from the group consisting of dimethoxyethane, tetrahydrofuran, ethyl acetate, methyl ethyl ketone, acetone, acetophenone, methylene chloride, chloroform, ethyl 3-ethoxypropionate, ethylene glycol monobutyl ether acetate, and a mixture thereof.

5. The method of claim 1, where the organic solvent compound has a solubility parameter (δ

) of from about 8.3 to about 10.4 (cal/cm³)^½

.

6. The method of claim 1, where the organic solvent compound has a solubility parameter (δ

) of from about 8.7 to about 10.2 (cal/cm³)^½

.

7. The method of claim 1, where the organic solvent compound has a solubility parameter (δ

) of from about 8.9 to about 10.0 (cal/cm³)^½

.

8. The method of claim 1, where the composition includes from about 50 to about 100 percent by weight of the one or more organic solvent compounds that have a solubility parameter (δ

) of from about 8.0 to about 10.6 (cal/cm³)^½

.

9. The method of claim 3, where the composition includes from about 50 to about 100 percent by weight of one or more organic solvent compounds that have a solubility parameter (δ

) of from about 8.0 to about 10.6 (cal/cm³)^½

.

10. The method of claim 4, where the composition includes from about 50 to about 100 percent by weight of one or more organic solvent compounds that have a solubility parameter (δ

) of from about 8.0 to about 10.6 (cal/cm³)^½

.

11. The method of claim 1, where said step of applying includes wiping the surface with a cloth or sponge.

12. The method of claim 1, where the diluent is a mixture consisting essentially of from about 40 to about 80 percent by weight of an aliphatic compounds and from about 20 to about 60 percent by weight of an aromatic compounds, based on the total weight of the diluent.

13. The method of claim 1, where the organic solvent compound is selected from the group consisting of ethyl 3-ethoxypropionate, ethylene glycol monobutyl ether acetate, and acetone.

14. The method of claim 1, wherein the vinyl surface comprises poly(vinylchloride) or a vinyl chloride copolymer having a solubility parameter of from about 9.4 to about 9.8 (cal/cm³)^½

.

15. A method for rejuvenating the surface of vinyl siding, the method comprising;

applying a composition to the surface of the vinyl siding, where the composition comprises from about 28 to about 32 percent by weight ethyl 3-ethoxypropionate, from about 11 to about 15 percent by weight butyl acetate, from about 11 to about 13 percent by weight toluene, from about 8 to about 12 percent by weight ethylene glycol monobutyl ether acetate, from about 5 to about 9 percent by weight acetone, from about 3 to about 4 percent by weight 1,2,4-trimethylbenzene, from about 1 to about 3 percent by weight 1,3,5-trimethylbenzene, from about 16 to about 20 percent by weight aliphatic petroleum distillates, and from about 8 to about 12 percent by weight aromatic petroleum distillates.

16. The method of claim 15, where the composition further includes antioxidants, thermal stabilizers, bacteriostats, ultraviolet absorbers, or a mixture thereof.

17. The method of claim 15, where said step of applying includes wiping the surface with a cloth or sponge.

18. The method of claim 15, where the composition consists essentially of from about 28 to about 32 percent by weight ethyl 3-ethoxypropionate, from about 11 to about 15 percent by weight butyl acetate, from about 11 to about 13 percent by weight toluene, from about 8 to about 12 percent by weight ethylene glycol monobutyl ether acetate, from about 5 to about 9 percent by weight acetone, from about 3 to about 4 percent by weight 1,2,4-trimethylbenzene, from about 1 to about 3 percent by weight 1,3,5-trimethylbenzene, from about 16 to about 20 percent by weight aliphatic petroleum distillates, and from about 8 to about 12 percent by weight aromatic petroleum distillates.

19. The method of claim 15, wherein the vinyl surface comprises poly(vinylchloride) or a vinyl chloride copolymer having a solubility parameter of from about 9.4 to about 9.8 (cal/cm³)^½

.

20. A method for rejuvenating and cleaning the surface of weathered vinyl siding, the composition comprising:

applying a composition to the surface of the vinyl siding, where the composition comprises from about 50 to about 100 percent by weight of an organic solvent component that is an ether, a heterocyclic ether, an aldehyde, a ketone, an ester, a chlorinated hydrocarbon, an amide, a cyclic amide, a compound that is both an ether and an ester, or a mixture thereof, where the organic solvent component has a solubility parameter (δ

) of from about 8.0 to about 10.6 (cal/cm³)^½

.

21. The method of claim 20 wherein the vinyl surface comprises poly(vinylchloride) or a vinyl chloride copolymer having a solubility parameter of from about 9.4 to about 9.8(cal/cm³){fraction (1/2)}.

22. A method for rejuvenating the surface of vinyl siding, the method comprising;

applying a composition to the surface of vinyl siding, where the vinyl siding includes poly(vinylchoride) or other vinyl copolymers that are characterized by having a solubility parameter of from about 9.4 to about 9.8 (cal/cm³)^½

, where the composition includes at least 50 percent by weight of one or more organic solvent compounds that have a solubility parameter of from about 8.0 to about 10.6 (cal/cm³)^½

.

23. The method of claim 22, where the one or more organic solvent compounds include ethyl 3-ethoxypropionate, ethylene glycol monobutyl ether acetate, and acetone.

24. The method of claim 22, wherein the vinyl surface comprises poly(vinylchloride) or a vinyl chloride copolymer having a solubility parameter of from about 9.4 to about 9.8 (cal/cm³)^½

.