Method for detecting a concentration of a solution

• US 6,706,533 B2
• Filed: 03/15/2001
• Issued: 03/16/2004
• Est. Priority Date: 03/15/2000
• Status: Expired due to Fees

• Current Assignee: Kanto Kagaku Kabushiki Kaisha
• Original Assignee: Kanto Kagaku Kabushiki Kaisha
• Inventors: Nomura, Akio, Iwao, Tomoaki
• Primary Examiner(s): Warden, Jill
• Assistant Examiner(s): Gordon, Brian R
• Application Number:
  US09/810,149
• Publication Number:
  US 20010031501A1
• Time in Patent Office: 1,097 Days
• Field of Search: 436/52, 436/150, 436/179, 422/62, 422/82.05, 422/105
• US Class Current: 436/150
• CPC Class Codes: G01N 27/06 of a liquid involving electrolysis G01N27/26
• CPC Class Codes: Y10T 436/117497 with a continuously flowing sample or carrier stream
• CPC Class Codes: Y10T 436/25625 Dilution

Abstract

A concentration detection method and a concentration detection apparatus, and an agent diluting preparation apparatus capable of accurately estimating the concentration of a solution without the need of strict temperature control, and of estimating the concentration of the solution in real time, and further of cost reduction of diluting and preparing an agent and of simplification of diluting and preparing work are provided herein.

Claims

1. A method for detecting a concentration of a solution comprising:

measuring an electrical conductivity and a temperature of a solution; and

calculating a concentration of a desired substance in the solution, wherein the calculation of the concentration is achieved on the basis of the following formula;

2. The method for detecting a concentration of claim 1, wherein the constants A, B, a, and b in the formula are values which are obtained by measuring the electrical conductivities at a plurality of temperatures for each of the solutions containing the same desired substances with a plurality of concentrations and estimating the values with the least squares method.

3. The method for detecting a concentration of claim 1, wherein the constants A, B, a, and b are values estimated by a method including:

a first step for measuring an electrical conductivity at a plurality of temperatures for each of the solutions containing the same agents with a plurality of concentrations;

a second step for deriving a linear equation using the least squares method for a relationship between the temperature and the electrical conductivity at each concentration;

a third step for calculating the electrical conductivity at each temperature by substituting the plurality of the temperatures for each of said linear equation;

a fourth step for deriving a second linear equation with the least squares method with respect to the electrical conductivity and the concentration at each temperature in the third step; and

a fifth step for deriving linear equations, w=AT+B and z=aT+b, depending upon temperature with respect to each of the inclination w and the intercept z of each second linear equation obtained in the fourth step.

4. The method for detecting a concentration of claim 1, wherein the plurality of the temperatures is included in a temperature range of ±

5 degrees of a predetermined temperature.

5. The method for detecting a concentration of claim 1, wherein the plurality of the temperatures are included in the temperature range of ±

10 degree of a predetermined temperature.

6. The method for detecting a concentration of claim 1, wherein the solution is an aqueous solution.

7. The method for detecting a concentration of claim 1, wherein the solution contains only one kind of a solute.

8. A method for preparing an agent to a desired concentration utilizing the following steps:

measuring an electrical conductivity and a temperature of a solution;

calculating a concentration of a desired substance in the solution, wherein the calculation of the concentration is achieved on the basis of the following formula;

9. The method for preparing an agent of claim 8, further comprising:

a first step for mixing the agent with water into an aqueous solution thereof;

a second step for detecting a concentration of the agent in the aqueous solution; and

a third step for adding an agent or water into the aqueous solution to adjust the concentration of the agent to a predetermined concentration based upon the detected concentration of the agent.

10. The method for preparing an agent of claim 9, wherein at least the second step and the third step are controlled with a computer program.