UV curable ferromagnetic compositions

• US 6,716,893 B2
• Filed: 07/11/2002
• Issued: 04/06/2004
• Est. Priority Date: 01/13/2000
• Status: Expired due to Fees

• Current Assignee: UV Specialties, Inc.
• Original Assignee: UV Specialties, Inc.
• Inventors: Krohn, Roy C.
• Primary Examiner(s): Sergent, Rabon
• Assistant Examiner(s): MCCLENDON, SANZA L
• Application Number:
  US10/193,408
• Publication Number:
  US 20030044547A1
• Time in Patent Office: 635 Days
• Field of Search: 522/8, 522/11, 522/12, 522/21, 522/33, 522/36, 522/31, 522/64, 522/40, 522/42, 522/44, 522/46, 522/48, 522/81, 522/83, 522/90, 522/92, 522/96, 522/100, 522/102, 522/103, 522/181, 522/182, 427/508, 427/517, 427/496, 427/502, 252/62.54, 252/62.56, 252/62.64
• US Class Current: 522/92
• CPC Class Codes: C08F 220/1811 C10or C11-(Meth)acrylate, e.g. isodecyl (meth)acrylate, isobornyl (meth)acrylate or 2-naphthyl (meth)acrylate
• CPC Class Codes: C08F 220/32 containing epoxy radicals
• CPC Class Codes: C08F 222/1065 of alcohol terminated (poly)urethanes, e.g. urethane(meth)acrylates
• CPC Class Codes: C09D 4/00 Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
• CPC Class Codes: C09D 4/06 Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
• CPC Class Codes: H01F 41/16 the magnetic material being applied in the form of particles, e.g. by serigraphy , to form thick magnetic films or precursors therefor H01F41/18 -H01F41/24 take precedence
• CPC Class Codes: H01F 41/34 in patterns, e.g. by lithography
• CPC Class Codes: H05K 1/162 incorporating printed capacitors
• CPC Class Codes: H05K 1/165 incorporating printed inductors
• CPC Class Codes: H05K 2201/086 for inductive purposes, e.g. printed inductor with ferrite core
• CPC Class Codes: H05K 2203/0545 Pattern for applying drops or paste; Applying a pattern made of drops or paste using thick film techniques to apply conductive material by using a substrate with a shape pattern H05K3/1258

Abstract

The present invention discloses an ultraviolet light curable ferromagnetic composition and method for making such a composition that may be used to produce a ferromagnetic coating on a suitable substrate. These coatings may be used to produce printed capacitors and inductors. The disclosed composition does not contain any significant amount of volatile organic solvents that do not become incorporated in the active layer after curing.

Claims

1. A photocurable ferromagnetic composition comprising:

an acrylated epoxy oligomer present in an amount from 2% to 6% of the weight of the ferromagnetic composition;

an isobornyl acrylate monomer present in an amount from 15% to 25% of the weight of the ferromagnetic composition;

a photoinitiator present in an amount from 1% to 10% of the weight of the ferromagnetic composition; and

a magnetic powder present in an amount from 20% to 60% of the weight of the ferromagnetic composition.

2. The photocurable ferromagnetic composition of claim 1 wherein the magnetic powder is ferrite.

3. The photocurable ferromagnetic composition of claim 1 further comprising an acrylated aliphatic oligomer mixture.

4. The photocurable ferromagnetic composition of claim 3 wherein the acrylated aliphatic oligomer mixture is present in an amount from 15% to 45% of the weight of the ferromagnetic composition.

5. The photocurable ferromagnetic composition of claim 3 further comprising a flow promoting agent.

6. The photocurable ferromagnetic composition of claim 5 wherein the flow promoting agent is present in an amount from 0.1% to 6% of the weight of the ferromagnetic composition.

7. The photocurable ferromagnetic composition of claim 5 wherein:

the acrylated epoxy oligomer is present in an amount from 3% to 5% of the weight of the ferromagnetic composition;

the isobornyl acrylate monomer is present in an amount from 18% to 22% of the weight of the ferromagnetic composition;

the photoinitiator is present in an amount from 2% to 6% of the weight of the ferromagnetic composition;

the acrylated aliphatic oligomer mixture is present in an amount from 25% to 35% of the weight of the ferromagnetic composition;

the flow promoting agent is present in an amount from 0.1% to 6% of the weight of the ferromagnetic composition; and

the magnetic powder is present in an amount from 30% to 50% of the weight of the ferromagnetic composition.

8. The photocurable ferromagnetic composition of claim 5 wherein:

the acrylated epoxy oligomer is present in an amount of 4% of the weight of the ferromagnetic composition;

the isobornyl acrylate monomer is present in an amount of 20% of the weight of the ferromagnetic composition;

the photoinitiator is present in an amount of 4.5% of the weight of the ferromagnetic composition;

the acrylated aliphatic oligomer mixture is present in an amount of 30% of the weight of the ferromagnetic composition;

the flow promoting agent is present in an amount of 3% of the weight of the ferromagnetic composition; and

the magnetic powder is present in an amount of 40% of the weight of the ferromagnetic composition.

9. The ferromagnetic composition of claim 1 wherein the isobornyl acrylate monomer is selected from the group consisting of isobornyl acrylate, isobornyl methacrylate, and mixtures thereof.

10. The ferromagnetic composition of claim 1 wherein the photoinitiator is selected from the group consisting of:

1-hydroxycyclohexyl phenyl ketone;

2-methyl-1-[4-(methylthio)phenyl]-2-morpholino propan-1-;

the combination of 50% 1-hydroxy cyclohexyl phenyl ketone and 50% benzophenone;

2,2-dimethoxy-1,2-diphenylethan-1-one;

the combination of 25% bis(2,6-dimethoxybenzoyl-2,4-, 4-trimethyl pentyl phosphine oxide and 75% 2-hydroxy-2-methyl-1-phenyl-propan-1-one;

2-hydroxy-2-methyl-1-phenyl-1-propane;

the combination of 50% 2,4,6-trimethylbenzoyldiphenyl-phosphine oxide and 50% 2-hydroxy 2-methyl-1-phenyl-propan-1-one;

mixed triaryl sulfonium hexafluoroantimonate salts, mixed triaryl sulfonium hexafluorophosphate salts; and

mixtures thereof.

11. The ferromagnetic composition of claim 1 wherein the acrylated epoxy oligomer is selected from the group consisting of:

novolac epoxy acrylate diluted 20% by weight with tripropylene glycol diacrylate;

difunctional bisphenol based epoxy acrylate; and

mixtures thereof.

12. A method for coating a substrate with a photocurable ferromagnetic composition, the method comprising:

applying the ferromagnetic composition to the substrate, wherein the ferromagnetic composition includes;

an acrylated epoxy oligomer present in an amount from 2% to 6% of the weight of the ferromagnetic composition;

an isobornyl acrylate monomer present in an amount from 15% to 25% of the weight of the ferromagnetic composition;

a photoinitiator present in an amount from 1% to 10% of the weight of the ferromagnetic composition;

an acrylated aliphatic oligomer mixture present in an amount from 15% to 45% of the weight of the ferromagnetic composition;

a flow promoting agent present in an amount from 0.1% to 6% of the weight of the ferromagnetic composition; and

a magnetic powder present in an amount from 20% to 60% of the weight of the ferromagnetic composition.

13. The method of claim 12, wherein UV light used in illuminating impinges upon the ferromagnetic composition so that the ferromagnetic composition is caused to form a coating as it cures.

14. The method of claim 12, wherein the method of applying the ferromagnetic composition is spraying.

15. The method of claim 12, wherein the method of applying the ferromagnetic composition is screen printing.

16. The method of claim 12, wherein the method of applying the ferromagnetic composition is dipping the substrate into the composition sufficiently to cause the composition to uniformly coat the substrate.

17. The method of claim 12, wherein the method of applying the ferromagnetic composition is brushing.

18. The method of claim 12, wherein the method of applying the ferromagnetic composition is selectively depositing to the, substrate at predetermined locations.

19. A method for coating a substrate with a photocurable ferromagnetic composition, the method comprising:

applying the ferromagnetic composition to the substrate, wherein the ferromagnetic composition includes;

an acrylated epoxy oligomer present in an amount from 3% to 5% of the weight of the ferromagnetic composition;

an isobornyl acrylate monomer present in an amount from 18% to 22% of the weight of the ferromagnetic composition;

a photoinitiator present in an amount from 2% to 6% of the weight of the ferromagnetic composition;

an acrylated aliphatic oligomer mixture present in an amount from 25% to 35% of the weight of the ferromagnetic composition;

a flow promoting agent present in an amount from 0.1% to 6% of the weight of the ferromagnetic composition; and

a magnetic powder present in an amount from 30% to 50% of the weight of the ferromagnetic composition;

illuminating the ferromagnetic composition with a UV light sufficient to cause the ferromagnetic composition to be incorporated into the ferromagnetic coating by the time the composition is cured.

20. The method of claim 19, wherein:

the acrylated epoxy oligomer is present in an amount of 4% of the weight of the ferromagnetic composition;

the isobornyl acrylate monomer is present in an amount of 20% of the weight of the ferromagnetic composition;

the photoinitiator is present in an amount of 4.5% of the weight of the ferromagnetic composition;

the acrylated aliphatic oligomer mixture is present in an amount of 30% of the weight of the ferromagnetic composition;

the flow promoting agent is present in an amount of 3% of the weight of the ferromagnetic composition; and

the magnetic powder is present in an amount of 40% of the weight of the ferromagnetic composition.

21. A method of making a photocurable ferromagnetic composition comprising:

mixing from 15% to 25% by weight of isobornyl acrylate monomer and from 1% to 10% by weight of a photoinitiator in a pan;

introducing from 0.1% to 6% by weight of a flow-promoting agent and from 2% to 6% by weight of an acrylated epoxy oligomer into the pen;

mixing said flow-promoting agent and said epoxy acrylate oligomer in the pan;

introducing from 20% to 60% by weight of a magnetic powder into the pan;

and mixing the magnetic powder in the pan, wherein all weight percents are based on the weight of the ferromagnetic composition.