Integrated membrane filter

• US 6,746,513 B2
• Filed: 02/08/2003
• Issued: 06/08/2004
• Est. Priority Date: 02/19/2002
• Status: Expired due to Term

• Current Assignee: L'Air Liquide SA
• Original Assignee: L'Air Liquide SA
• Inventors: Anderson, Charles L.
• Primary Examiner(s): Spitzer, Robert H.
• Application Number:
  US10/359,758
• Publication Number:
  US 20030154856A1
• Time in Patent Office: 486 Days
• Field of Search: 95/45, 95/47--55, 951/43, 96/4, 96/8, 96/10, 961/08, 961/35, 961/53, 961/54, 210/321.8, 210/321.81, 210/321.89, 210/321.9
• US Class Current: 95/45
• CPC Class Codes: B01D 2253/102 Carbon
• CPC Class Codes: B01D 2257/702 Hydrocarbons
• CPC Class Codes: B01D 2311/04 Specific process operations in the feed stream; Feed pretreatment
• CPC Class Codes: B01D 2311/2626 Absorption or adsorption
• CPC Class Codes: B01D 2311/2649 Filtration
• CPC Class Codes: B01D 2313/40 Adsorbents within the flow path
• CPC Class Codes: B01D 53/22 by diffusion manufacturing semi-permeable membranes B01D67/00; form, structure or properties of semi-permeable membranes B01D69/00; material for semi-permeable membranes B01D71/00
• CPC Class Codes: B01D 53/229 Integrated processes (Diffusion and at least one other process, e.g. adsorption, absorption)
• CPC Class Codes: B01D 61/00 Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor separation of gases or vapours by diffusion B01D53/22
• CPC Class Codes: B01D 63/02 Hollow fibre modules
• CPC Class Codes: B01D 63/024 with a single potted end
• CPC Class Codes: B01D 63/0241 being U-shaped
• CPC Class Codes: B01D 63/032 More than two tube sheets for one bundle
• CPC Class Codes: B01J 20/20 comprising free carbon; comprising carbon obtained by carbonising processes
• CPC Class Codes: B01J 20/28033 Membrane, sheet, cloth, pad, lamellar or mat
• CPC Class Codes: B01J 20/2805 Sorbents inside a permeable or porous casing, e.g. inside a container, bag or membrane
• CPC Class Codes: B01J 20/28052 Several layers of identical or different sorbents stacked in a housing, e.g. in a column

Abstract

A gas separation module includes an adsorbent filter medium inside the case that holds the active gas separation membrane. The adsorbent filter is positioned upstream of the membrane and is operative to extract from the feed gas contaminants which adversely affect membrane separation performance and which if not removed, would cause the membrane separation performance to deteriorate. The adsorbent filter fits within vacant space in conventionally-sized hollow fiber membrane modules and thus can obviate the need to install an external adsorbent filter upstream of the module and/or to enlarge the space occupied by the module to accommodate addition of the internal adsorbent medium.

Claims

1. A method of using a membrane to separate components of a gas mixture having gaseous contaminants which can affect the separation performance of the membrane, the method comprising:

providing a module comprising

a shell;

a selectively gas permeable membrane within the shell; and

a filter medium operative to selectively remove the contaminants from the gas mixture, the filter medium being positioned between the shell and the membrane;

introducing the gas mixture into the shell;

conducting the gas mixture through the filter medium, thereby producing a filtered mixture depleted in contaminants relative to the gas mixture; and

contacting the membrane with the filtered mixture, thereby forming a permeate gas enriched in more preferentially permeable components of the gas mixture.

2. The method of gas separation of claim 1 in which the filter medium comprises activated carbon.

3. The method of claim 1 in which the filter medium is activated carbon cloth.

4. A module comprising a selectively gas permeable membrane for separating components of a gas mixture having gaseous contaminants which can affect the separation performance of the membrane, the module comprising:

a shell;

a gas separating membrane within the shell; and

a filter medium within the shell operative to prevent the contaminants from contacting the membrane.

5. The module of claim 4 in which the filter medium is operative to remove hydrocarbons from the gas mixture.

6. The module of claim 5 in which the filter medium comprises activated carbon.

7. The module of claim 5 in which the filter medium comprises adsorbent particles.

8. The module of claim 7 in which the adsorbent particles are contained within a porous pouch.

9. The module of claim 5 in which the filter medium comprises activated carbon cloth.

10. The module of claim 4 in which the gas separating membrane comprises (i) an elongated tube bundle having two ends, the bundle comprising a plurality of hollow fibers, and (ii) a first tube sheet at an end of the bundle which first tube sheet is adapted to join the hollow fibers in parallel fluid communication, and in which the shell and first tube sheet define a tube-side chamber therebetween adapted to distribute the gas mixture into the hollow fibers, the shell defines a first port in fluid communication with the tube-side chamber, and the filter medium is positioned in the tube-side chamber between the first port and the first tube sheet.

11. The module of claim 10 in which the filter medium comprises activated carbon cloth.

12. The module of claim 11 in which the filter medium comprises multiple layers of the activated carbon cloth.

13. The module of claim 10 in which the module comprises a sealing means for preventing the gas mixture from bypassing the filter medium between the first port and the hollow fibers.

14. The module of claim 10 in which the gas separating membrane further comprises a second tube sheet at an end of the bundle opposite the first tube sheet, and in which the shell defines a shell-side chamber outside the hollow fibers and between the tube sheets, in which the shell defines a second port in fluid communication with the shell-side chamber, and in which the filter medium is positioned in the shell-side chamber between the second port and the hollow fibers.

15. The module of claim 14 in which the filter medium comprises activated carbon cloth.

16. The module of claim 15 in which the activated carbon cloth is wrapped around the tube bundle.

17. The module of claim 16 in which the activated carbon cloth is wrapped in a spiral path of at least two full turns around the tube bundle.

18. The module of claim 14 in which the module comprises a sealing means for preventing the gas mixture from bypassing the filter medium between the second port and the hollow fibers.