Plastic composites made from incompatible plastics

• US 6,773,255 B2
• Filed: 05/15/2001
• Issued: 08/10/2004
• Est. Priority Date: 08/05/1993
• Status: Expired due to Fees

• Current Assignee: Roehm GmbH Chemische Fabrik
• Original Assignee: Roehm GmbH Chemische Fabrik
• Inventors: Pöhlmann, Klaus-Ernst, Müller, Michael, Meier-Kaiser, Michael, Benz, Volker, Lorenz, Hans
• Primary Examiner(s): Kelly, Cynthia H.
• Assistant Examiner(s): FERGUSON, LAWRENCE D
• Application Number:
  US09/854,604
• Publication Number:
  US 20010026026A1
• Time in Patent Office: 1,183 Days
• Field of Search: 425/463, 425/464, 425/466, 425/467, 425/380, 425/382, 425/461, 425/132, 428/212, 427/436
• US Class Current: 425/463
• CPC Class Codes: B29C 48/07 Flat, e.g. panels
• CPC Class Codes: B29C 48/08 flexible, e.g. films
• CPC Class Codes: B29C 48/19 the layers being joined at their edges
• CPC Class Codes: B29C 48/20 one of the layers being a strip, e.g. a partially embedded strip
• CPC Class Codes: B29C 48/21 the layers being joined at their surfaces
• CPC Class Codes: B29C 48/22 with means connecting the layers, e.g. tie layers or undercuts
• CPC Class Codes: B29C 70/20 oriented in a single direction, e.g. roofing or other parallel fibres B29C70/083, B29C70/226 take precedence
• CPC Class Codes: B29K 2995/0039 Amorphous
• CPC Class Codes: B29K 2995/0041 Crystalline
• CPC Class Codes: E01F 8/0017 Plate-like elements E01F8/0035 takes precedence
• CPC Class Codes: Y10T 428/24942 including components having same physical characteristic in differing degree

Abstract

Multilayer plastic composites containing at least two incompatible plastics, A and B, in which the layering sequence alternates between A and B, the layers of plastic B are discontinued at regular intervals, and the resulting gaps in the layers are filled in with plastic A, exhibit good adhesion between the layers. In preferred embodiments of the invention, the amorphous, crystalline, or semi-crystalline plastic B has a higher coefficient of thermal expansion than the amorphous plastic A. The plastic composite is preferably produced via coextrusion.

Claims

1. An extrusion die, comprising a pair of parallel exit slits and a plurality of exit ports located between said pair of parallel exit slits and evenly spaced along a line parallel to said pair of parallel exit slits.

2. The extrusion die of claim 1, which is adapted for producing a multilayer plastic composite by a method, said composite comprising a sequence of layers of at least two incompatible thermoplastic plastics, A and B, wherein said sequence of layers alternates between A and B, a layer of plastic B is discontinuous at regular intervals to form gaps in said layer of plastic B, and said gaps in said layer of B are filled in with plastic A;

said method comprising coextruding plastic A and plastic B through said die,

wherein said coextruding plastic A and plastic B comprises forming a pair of fluid streams of said plastic A by passing a fluid stream of plastic A through said pair of parallel exit slits and forming a plurality of fluid streams of plastic B with gaps between each stream of said plastic B by passing a fluid stream of plastic B through said plurality of exit ports, so that said fluid streams of said plastic A exit said pair of exit slits and said fluid streams of plastic B exit said plurality of exit ports in such a manner to result in a portion of said fluid streams of said plastic A passing through said gaps between each stream of said plastic B to effect fusion of said pair of fluid streams of said plastic A, to obtain said composite.

3. The extrusion die of claim 1, which is adapted for producing a multilayer plastic composite comprising a sequence of layers of at least two incompatible thermoplastic plastics, A and B, wherein said sequence of layers alternates between A and B, a layer of plastic B is discontinuous at regular intervals to form gaps in said layer of plastic B, and said gaps in said layer of B are filled in with plastic A.

4. The extrusion die of claim 3, wherein the number of layers of plastic B is less than 3.

5. The extrusion die of claim 4, wherein the number of layers of plastic B is 1.

6. The extrusion die of claim 3, wherein the multilayer plastic composite has a thickness of 0.5 to 25 mm.

7. The extrusion die of claim 6, wherein the multilayer plastic composite has a thickness of 1 to 20 mm.

8. The extrusion die of claim 3, wherein the layers of plastic B each independently has a thickness of 0.1 to 22 mm.

9. The extrusion die of claim 8, wherein the layers of plastic B each independently has a thickness of 0.2 to 20 mm.

10. The extrusion die of claim 3, wherein the gaps in the layers of plastic B are 1 to 100 mm.

11. The extrusion die of claim 10, wherein the gaps in the layers of plastic B are 5 to 50 mm.

12. The extrusion die of claim 3, wherein the distance between nearest neighbor gaps in the layers of plastic B are 1 to 50 mm.

13. The extrusion die of claim 12, wherein the distance between nearest neighbor gaps in the layers of plastic B are 2 to 30 mm.