Wrinkle resistant infrared reflecting film and non-planar laminate articles made therefrom

• US 6,797,396 B1
• Filed: 06/09/2000
• Issued: 09/28/2004
• Est. Priority Date: 06/09/2000
• Status: Expired due to Term

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Boettcher, Jeffrey A., Koster, Brian L., Kranz, Heather K., Mortenson, David K., Liu, Yaoqi J., Ruff, Andrew T.
• Primary Examiner(s): Chen, Vivian
• Application Number:
  US09/590,924
• Time in Patent Office: 1,572 Days
• Field of Search: 428/426, 428/430, 428/441, 428/480, 428/483, 428/910, 359/359, 359/487, 359/494, 359/577, 359/580, 359/584, 359/586, 359/589, 359/601
• US Class Current: 428/483
• CPC Class Codes: B32B 17/10005 laminated safety glass or glazing
• CPC Class Codes: B32B 17/10009 characterized by the number, the constitution or treatment of glass sheets
• CPC Class Codes: B32B 17/10036 comprising two outer glass sheets
• CPC Class Codes: B32B 17/10174 Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
• CPC Class Codes: B32B 17/10761 containing vinyl acetal
• CPC Class Codes: B32B 2250/42 Alternating layers, e.g. ABAB(C), AABBAABB(C)
• CPC Class Codes: B32B 2367/00 Polyesters, e.g. PET, i.e. polyethylene terephthalate
• CPC Class Codes: Y10S 428/91 Product with molecular orientation
• CPC Class Codes: Y10T 428/31616 Next to polyester [e.g., alkyd]
• CPC Class Codes: Y10T 428/31645 Next to addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31786 Of polyester [e.g., alkyd, etc.]
• CPC Class Codes: Y10T 428/31797 Next to addition polymer from unsaturated monomers

Abstract

A birefringent dielectric multilayer film that reflects in a wavelength region of interest, and preferably reflects at least 50% of light in a band at least 100 nm wide, preferably positioned between wavelengths from about 700 nm to about 2000 nm. The film is heat set to render the film capable of shrinking to conform without substantial wrinkling to a substrate having a compound curvature. The film may be laminated to form a wide variety of non-planar articles.

Claims

1. An article comprising a birefringent dielectric multilayer film sandwiched between two substrates, the film reflecting at least 50% of light in a band at least 100 nm wide in a wavelength region of interest, wherein the film is heat set at a temperature sufficient to render the film capable of shrinking so as to conform without substantial wrinkling when positioned between the two substrates and heated.

2. The article of claim 1, wherein the wavelength region of interest is from about 700 nm to about 2000 nm.

3. The article of claim 1, wherein the film is comprised of alternating layers of a first polymer and a second polymer.

4. The article of claim 3, wherein the first polymer is selected from the group consisting of PEN and coPEN, and the second polymer is selected from the group consisting of PMMA and co-PMMA.

5. The article of claim 3, wherein the first polymer is coPET and the second polymer is selected from the group consisting of PET and co-PMMA.

6. The article of claim 1 further comprising two layers of an energy absorbing material, with the birefringent dielectric multilayer film being sandwiched therebetween, wherein the two layers, the film and the two substrates are bonded together.

7. The article of claim 6, wherein the wavelength region of interest is from about 700 nm to about 2000 nm.

8. A laminate comprising the article of claim 6, wherein the two substrates are two non-planar substrates of a glazing material.

9. The article of claim 1, further comprising two layers of an energy absorbing material, with the birefringent dielectric multilayer film.

10. The article of claim 9, further comprising a shade band layer sandwiched between the substrates.

11. The vehicle of claim 10, wherein the article further comprises a shade band layer.

12. A laminate comprising the article of claim 9, wherein each layer of energy absorbing material, the birefringent dielectric multilayer film and the two substrates are bonded together, and the two substrates are two non-planar layers of a glazing material.

13. An article comprising a birefringent dielectric multilayer film sandwiched between two substrates, the film reflecting at least 50% of light in a band at least 100 nm wide in a wavelength region of interest, wherein the film is heat set at a temperature sufficient to enable the film to shrink up to 3.887% in an in-plane direction upon heating.

14. The article of claim 13, wherein the wavelength region of interest is from about 700 nm to about 2000 nm.

15. The article of claim 13, wherein the film is heat set at a temperature sufficient to enable the film to shrink at least about 0.7% in at least one in-plane direction upon heating.

16. The article of claim 13, wherein the film is heat set at a temperature sufficient to enable the film to shrink at least about 1.0% in at least one in-plane direction upon heating.

17. The article of claim 13, wherein the film has a first shrinkage in a first in-plane direction and a second shrinkage in a second in-plane direction, and the first direction is normal to the second direction.

18. The article of claim 13 further comprising two layers of an energy absorbing material, with the birefringent dielectric multilayer film being sandwiched therebetween.

19. The article of claim 18, wherein the wavelength region of interest is from about 700 nm to about 2000 nm.

20. The article of claim 18, wherein the two layers, the film and the two substrates are bonded together to form a glazing laminate.

21. The article of claim 13, wherein the film shrinks greater than about 0.4% and less than about 3% in both in-plane directions upon heating.

22. A substantially transparent laminate article comprising the following layers:

a first non-planar layer of glass, a first layer of PVB, a film layer, a second layer of PVB and a second non-planar layer of glass, wherein the film layer comprises a birefringent dielectric multilayer film that reflects at least 50% of light in a band at least 100 nm wide positioned between wavelengths from about 700 nm to about 2000 nm, wherein the film is heat set at a temperature sufficient to render the film capable of shrinking to conform without substantial wrinkling to the non-planar glass layers.

23. The laminate article of claim 22, wherein the layers of glass have a compound curvature.

24. The laminate article of claim 22, wherein the article is a windshield for a vehicle.

25. A vehicle comprising a substantially transparent laminate glazing comprising the following layers:

a first non-planar layer of glass, a first layer of PVB, a film layer, a second layer of PVB and a second non-planar layer of glass, wherein the film layer comprises a birefringent dielectric multilayer film that reflects at least 50% of light in a band at least 100 nm wide positioned between wavelengths from about 700 nm to about 2000 nm, wherein the film is heat set at a temperature sufficient to render the film capable of shrinking to conform without substantial wrinkling to the non-planar glass layers.

26. The vehicle of claim 25, wherein at least a portion of the first and second layers of glass has a compound curvature.

27. A substantially transparent laminate article comprising in the following order;

a first non-planar substrate, a first layer of an energy absorbing material, a film layer, a second layer of an energy absorbing material, and a second non-planar substrate, wherein the film layer comprises a birefringent dielectric multilayer film that reflects at least 50% of light in a band al least 100 nm wide in a wavelength region of interest, wherein the film is heat set at a temperature sufficient to render the film capable of shrinking to conform without substantial wrinkling to the first and second non-planar substrates.

28. The laminate article of claim 27, wherein the wavelength region of interest is from about 700 nm to about 2000 nm.

29. A vehicle comprising an article of claim 27.

30. The vehicle of claim 29, wherein the wavelength region of interest is from about 700 nm to about 2000 nm.

31. A substantially transparent laminate article comprising in the following order:

a first substrate, a first layer of an energy absorbing material, a film layer, a second layer of an energy absorbing material, and a second substrate, wherein the film layer comprises a birefringent dielectric multilayer film that reflects at least 50% of light in a band at least 100 nm wide in a wavelength region of interest, wherein the film is heat set at a temperature sufficient to render the film capable of shrinking up to 3.887% in an in-plane direction upon heating.

32. The laminate article of claim 31, wherein the wavelength region of interest is from about 700 nm to about 2000 nm.

33. The laminate article of claim 31, wherein the film shrinks greater than about 0.4% and less than about 3% in both in-plane directions upon heating.

34. A vehicle comprising an article of claim 31.

35. The vehicle of claim 34, wherein the wavelength region of interest is from about 700 nm to about 2000 nm.

36. The vehicle of claim 34, wherein the film shrinks greater than about 0.4% and less than about 3% in both in-plane directions upon heating.

37. A substantially transparent laminate article comprising in the following order:

a first substrate, a film layer, and a second substrate, wherein the film layer comprises a birefringent dielectric multilayer film that reflects at least 50% of light in a band at least 100 nm wide in a wavelength region of interest, wherein the film is heat set at a temperature sufficient to render the film capable of shrinking to conform without substantial wrinkling to the first and second substrate.

38. The laminate article of claim 37, wherein the wavelength region of interest is from about 700 nm to about 2000 nm.

39. The laminate of claim 37, wherein the first substrate and the second substrate are non-planar.

40. A substantially transparent laminate article comprising the following layers:

a first substrate, a film layer, and a second substrate, wherein the film layer comprises a birefringent dielectric multilayer film that reflects at least 50% of light in a band at least 100 nm wide in a wavelength region of interest wherein the film is heat set at a temperature sufficient to render the film capable of shrinking greater than about 0.4% in both in-plane directions upon heating and less than about 3% up to 3.55% in both an in-plane directions upon heating.

41. The laminate article of claim 40, wherein the wavelength region of interest is from about 700 nm to about 2000 nm.

42. The laminate article of claim 40, wherein the film shrinks greater than about 0.4% and less than about 3% in both in-plane directions upon heating.

43. The laminate of claim 40, wherein the first substrate and the second substrate are non-planar.