Medium density polyethylene compositions for film applications

• US 6,824,886 B2
• Filed: 09/23/2002
• Issued: 11/30/2004
• Est. Priority Date: 12/13/1999
• Status: Expired due to Fees

• Current Assignee: Total Petrochemicals Research Feluy (Totalenergies Se)
• Original Assignee: FINA Research SA
• Inventors: Tavernier, Marc
• Primary Examiner(s): Tarazano, D. Lawrence
• Application Number:
  US10/149,576
• Publication Number:
  US 20030091849A1
• Time in Patent Office: 799 Days
• Field of Search: 428/213, 428/516, 525/240, 264/173.16
• US Class Current: 428/516
• CPC Class Codes: B32B 27/32 comprising polyolefins comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30
• CPC Class Codes: C08L 2205/02 containing two or more polymers of the same C08L -group
• CPC Class Codes: C08L 23/04 Homopolymers or copolymers of ethene
• CPC Class Codes: C08L 23/06 Polyethene
• CPC Class Codes: C08L 23/0815 Copolymers of ethene with aliphatic 1-olefins
• CPC Class Codes: C08L 23/0846 Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
• CPC Class Codes: C08L 2314/06 Metallocene or single site catalysts
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: Y10T 428/2495 Thickness [relative or absolute]
• CPC Class Codes: Y10T 428/31909 Next to second addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31913 Monoolefin polymer

Abstract

Use of a homogeneous blend of a metallocene-catalysed medium density polyethylene (mMDPE) with low density polyethylene (LDPE), to produce blown films, this composition essentially consisting of from 0.5 to 99.5 % by weight of mMDPE and from 99.5 to 0.5 % by weight of LDPE, based on the total weight of the blend. The blend is optionally coextruded between layers of LDPE. The compositions of this invention have good processability and are used to make blown films which have the good optical properties of LDPE and the good mechancial and processing properties of MDPE.

Claims

1. A coextruded film consisting of:

(i) a first layer of a composition comprising a low density polyethylene (LDPE) prepared with a non-metallocene catalyst and/or a linear low density polyethylene (LLDPE) prepared with either a non-metallocene or a metallocene catalyst;

(ii) a second layer of a homogeneous blend of a low density polyethylene (LDPE) with a metallocene catalyzed medium density polyethylene (mMDPE), this blend essentially consisting of from 0.5 to 99.5% by weight of mMDPE and from 99.5 to 0.5% by weight of LDPE, based on the total weight of the blend, and having a density of from 0.925 to 0.955 g/cm³, and the metallocene catalyst system essentially consisting of a bridged metallocene compound, alone or in combination with another metallocene catalyst which contributes less than 80% by weight of said metallocene;

(iii) a third layer of a composition comprising a low density polyethylene (LDPE) prepared with a non-metallocene catalyst and/or a linear low density polyethylene (LLDPE) prepared either with a non-metallocene or a metallocene catalyst, said third layer being the same as or different from the first layer.

2. The coextruded film of claim 1, wherein the bridged metallocene catalyst is a bis tetrahydro-indenyl compound.

3. The coextruded film of claim 1, wherein the bridged metallocene is a ethylene bis tetrahydro-indenyl zirconium compound.

4. The coextruded film of claim 1, wherein the first and third layers are external layers and the two external layers have the same composition.

5. The coextruded film of claim 1, wherein the first and third layers are external layers and each of the two external layers represent from 5 to 33 wt % of the total weight of the film.

6. The coextruded film of claim 4, wherein the two external layers have the same thickness.

11. The coextruded film of claim 4 wherein each of the two external layers represent from 5 to 33 wt % of the total weight of the film.

12. The coextruded film of claim 11, wherein the two external layers have the same thickness.

13. The coextruded film of claim 1 wherein said metallocene-catalyzed medium density polyethylene has a density within the range of 0.93 to 0.945 g/cm³.

7. A process for preparing a blow film:

a) preparing a blend of 0.5 to 99.5% by weight of a metallocene-catalyzed medium density polyethylene (mMDPE) with 99.5 to 0.5% by weight of a low density polyethylene prepared with a non-metallocene catalyst (LDPE), based on the total weight of the blend, said blend having a density of from 0.93 to 0.955 g/cm³ and a melt index MI2 of from 0.2 to 10 g/10 min, and the metallocene catalyst system essentially consisting of a bridged metallocene compound, alone or in combination with another metallocene catalyst which contributes less than 80% by weight of said metallocene;

b) preparing a second composition of a LDPE prepared with a non-metallocene catalyst, and/or a LLDPE prepared with either a non-metallocene or a metallocene catalyst;

c) preparing a third composition of a LDPE prepared with a non-metallocene catalyst, and/or a LLDPE prepared with either a non-metallocene or a metallocene catalyst, said composition being the same or different from the composition of step b);

d) coextruding the blend of step a) between a layer prepared from the composition of step b) and a layer prepared from the composition of step c), said blend of step a) representing from 33 to 100% by weight of the total weight of the film;

e) blowing the coextrudate of step d) to prepare a blown film with improved optical properties.

8. The process of claim 7, wherein the metallocene catalyst is a bis tetrahydro-indenyl compound.

9. The process of claim 7, wherein the two external layers of the coextrudate have the same composition.

10. The process of claim 9, wherein the two external layers have the same thickness.

14. The process of claim 7 wherein said metallocene-catalyzed medium density polyethylene has a density within the range of 0.93 to 0.945 g/cm³.