Methods for fabricating metal nanowires

• US 6,843,902 B1
• Filed: 10/12/2001
• Issued: 01/18/2005
• Est. Priority Date: 07/20/2001
• Status: Expired due to Fees

• Current Assignee: Regents of the University of California (University of California)
• Original Assignee: Regents of the University of California (University of California)
• Inventors: Penner, Reginald Mark, Zach, Michael Paul, Favier, Fred
• Primary Examiner(s): Phasge, Arun S.
• Application Number:
  US09/976,990
• Time in Patent Office: 1,194 Days
• Field of Search: 205/76, 205/109, 205/122, 205/104
• US Class Current: 205/76
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: C25D 1/006 Nanostructures, e.g. using aluminium anodic oxidation templates [AAO]
• CPC Class Codes: C25D 1/04 Wires; Strips; Foils
• CPC Class Codes: C25D 5/02 Electroplating of selected surface areas
• CPC Class Codes: C25D 5/48 After-treatment of electroplated surfaces
• CPC Class Codes: C25D 5/605 Surface topography of the layers, e.g. rough, dendritic or nodular layers
• CPC Class Codes: C25D 5/611 Smooth layers
• CPC Class Codes: C25D 5/617 Crystalline layers
• CPC Class Codes: C25D 9/08 by cathodic processes
• CPC Class Codes: G01N 27/127 comprising nanoparticles
• CPC Class Codes: G01N 33/005 for H2
• CPC Class Codes: Y10S 977/762 Nanowire or quantum wire, i.e. axially elongated structure having two dimensions of 100 nm or less

Abstract

Methods for the preparation of long, dimensionally uniform, metallic nanowires that are removable from the surface on which they are synthesized. The methods include the selective electrodeposition of metal nanowires at step edges present on a stepped surface, such as graphite, from an aqueous solution containing a metal or metal oxide. Where a metal oxide is first deposited, the metal oxide nanowires are reduced via a gas phase reduction at elevated temperatures to metal nanowires. Alternatively, beaded or hybrid nanowires comprising a metal A into which nanoparticles of a metal B have been inserted may be prepared by first electrodepositing nanoparticles of metal B selectively along step edges of a stepped surface, capping these nanoparticles with a molecular layer of an organic ligand, selectivley electrodepositing nanowire segments of metal A between nanoparticles of metal B and then heating the surface of the hybrid nanowire under reducing conditions to remove the ligand layer. In all three methods, the nanowires may be removed from the stepped surface by embedding the wires in a polymer film, and then peeling this film containing the embedded wires off of the stepped surface.

Claims

1. A method for preparing metallic nanometer scale wires comprising the steps of

electrodepositing a plurality of wires from an aqueous solution including a metal at step edges present on a stepped surface,

embedding the plurality of wires in a polymer film, and

lifting the plurality of wires off of the stepped surface.

2. The method of claim 1 wherein the electrodepositing step includes applying a nucleation pulse to the aqueous solution.

3. The method of claim 2 wherein the electrodepositing step further includes applying a deposition potential to the aqueous solution.

4. The method of claim 3 wherein the over potential corresponding to the deposition potential is less than about −

400 millivolts.

5. A method for preparing metallic nanowires comprising the steps of

electrodepositing metal oxide particles at step edges present on a stepped surface from an aqueous solution including a metal oxide forming a plurality of metal oxide wires,

reducing the plurality of metal oxide wires via gas phase reduction to a plurality of metal wires,

embedding the plurality of metal wires in a polymer film, and

lifting the plurality of metal wires from the stepped surface.

6. The method of claim 5 wherein the electrodepositing step includes applying a deposition potential to the solution.

7. The method of claim 6 wherein the over potential corresponding to the deposition potential is less than −

900 millivolts.

8. The method of claim 5 wherein the reducing step includes reducing the plurality of metal oxide wires in hydrogen gas.

9. The method of claim 8 wherein the reducing step further includes reducing the plurality of metal oxide wires at about 500°

C.

10. A method for preparing beaded nanowires comprising the steps of

electrodepositing nanoparticles of a first metal from a first aqueous solution at step edges present on a stepped surface, and

electrodepositing wire segments of a second metal from a second aqueous solution at the stepped edges between the nanoparticles forming a plurality of beaded nanowires.

11. The method of claim 10 wherein the first metal is a noble metal.

12. The method of claim 10 further comprising the step of capping the nanoparticles with a ligand.

13. The method of claim 12 further comprising the step of heating the nanoparticles and wire segments of the plurality of beaded nanowires at reduction conditions.

14. The method of claim 13 further comprising the step of embedding the plurality of beaded nanowires in a polymer film.

15. The method of claim 13 further comprising the step of removing the plurality of beaded nanowires from the stepped surface.

16. A method for preparing nanometer scale metallic wires comprising the steps of

applying a deposition potential to an aqueous solution comprising a metal or metal oxide wherein the deposition potential corresponds to an over potential of less than −

900 millivolts, and

selectively depositing metal or metal oxide nanowires at step edges present on a stepped surface.

17. The method of claim 16 further comprising the step of reducing the metal oxide nanowires in hydrogen gas.

18. The method of claim 17 wherein the reducing step includes reducing the metal oxide nanowires in hydrogen gas at about 500°

C.

19. The method of claim 16 further comprising the step of embedding the metal nanowires in a polymer film and removing the metal nanowires from the stepped surface.