Organic light active devices and methods for fabricating the same

• US 6,876,143 B2
• Filed: 12/17/2002
• Issued: 04/05/2005
• Est. Priority Date: 11/19/2002
• Status: Expired due to Fees

• Current Assignee: John James Daniels
• Original Assignee: John James Daniels
• Inventors: Daniels, John James
• Primary Examiner(s): Guharay, Karabi
• Application Number:
  US10/321,161
• Publication Number:
  US 20040113543A1
• Time in Patent Office: 840 Days
• Field of Search: 313500-512, 315/169.3, 315/169.1, 428/690, 428/917, 345/45, 345/76, 257/40
• US Class Current: 313/504
• CPC Class Codes: H01J 1/62 Luminescent screens; Selection of materials for luminescent coatings on vessels
• CPC Class Codes: H01J 1/63 characterised by the luminescent material
• CPC Class Codes: H01J 63/04 Vessels provided with luminescent coatings; Selection of materials for the coatings
• CPC Class Codes: H01L 27/14627 Microlenses
• CPC Class Codes: H01L 27/148 Charge coupled imagers individual charge coupled devices H01L29/765
• CPC Class Codes: H05B 33/00 Electroluminescent light sources
• CPC Class Codes: H10K 50/00 Organic light-emitting devices integrated devices or assemblies of multiple devices H10K59/00, H10K65/00; organic semiconductor lasers H01S5/36
• CPC Class Codes: H10K 50/11 characterised by the electroluminescent [EL] layers
• CPC Class Codes: H10K 50/182 OLED comprising a fiber structure
• CPC Class Codes: H10K 50/80 Constructional details
• CPC Class Codes: H10K 59/00 Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
• CPC Class Codes: H10K 59/13 comprising photosensors that control luminance
• CPC Class Codes: H10K 59/32 Stacked devices having two or more layers, each emitting at different wavelengths
• CPC Class Codes: H10K 71/12 using liquid deposition, e.g. spin coating
• CPC Class Codes: H10K 71/13 using printing techniques, e.g. ink-jet printing or screen printing
• CPC Class Codes: Y02E 10/549 Organic PV cells
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product
• CPC Class Codes: Y10S 428/917 Electroluminescent

Abstract

A method for fabricating organic light active devices using field-attractive Organic Light Active Material (“OLAM™”) microcapsules. The OLAM microcapsules are randomly dispersed within a monomer carrier fluid that is injected or otherwise disposed between two electrodes. The OLAM microcapsules may include additives that impart rheological properties, and other electrical, mechanical, optical and magnetic properties. The OLAM microcapsules form chains between the electrodes when an aligning field is applied. Holding the aligning field to keep the chains formed, the carrier fluid is cured and the OLAM microcapsule chains are locked into alignment between the electrodes. The problem of contamination of the OLAM material is the major factor limiting the display life span, and thus is a bar to commercial success. This fabrication method results in the corrosion sensitive OLAM material being protected by the microcapsule shell and the cured carrier, and the pixel alignment is automatic, since the OLAM microcapsule chains are formed only between the electrodes.

Claims

1. An OLED device comprising;

a first electrode, a second electrode disposed adjacent to the first electrode and defining a gap there between, an OLED particulate, wherein the OLED particulate comprises organic-layered particles, each organic-layered particle including a hole transport layer and an electron transport layer having a hetero-junction there between, and a carrier material disposed within said gap and containing said OLED particulate.

2. An OLED device according to claim 1;

wherein each organic-layered particle further includes at least one of a blocking layer and an emissive layer.

3. An OLED device according to claim 1;

wherein the OLED particulate comprises microcapsules, each microcapsule including an internal phase and a shell, at least one of the internal phase and the shell including an OLED material and at least one of the internal phase and the shell including a field reactive material comprising at least one of an electrostatic material and a magnetically reactive material.

4. An OLED device according to claim 1;

wherein the OLED particulate comprises microcapsules, each microcapsule including an internal phase and a shell, at least one of the internal phase and the shell including an OLED material, and at least one of the internal phase and the shell including a composition that causes the microcapsule to rupture if electrical energy above a threshold is applied to the microcapsule.

5. An OLED device according to claim 1;

wherein the OLED particulate comprises microcapsules, each microcapsule including an internal phase and a shell, at least one of the internal phase and the shell including an OLED material, and at least one of the internal phase and the shell including a composition effective to provide a barrier against degradation of the OLED material.

6. An OLED device according to claim 1;

wherein the OLED particulate comprises microcapsules having constituent parts including at least one of hole transport material, electron transport material, field reactive material, solvent material, color material, shell forming material, barrier material, desiccant material, and heat meltable material, the constituent parts forming at least one internal phase and at least one shell, the constituent parts having electrical characteristics that result in a preferred path of electrical conduction through the hole transport material and the electron transport material so that the microcapsule behaves as a pn junction upon application of an electrical potential to the first electrode and the second electrode.

7. An OLED device according to claim 1;

wherein the carrier material is relatively less electrically conductive than the OLED particulate so that the OLED particulate offers a path of less electrical resistance than the carrier material.

8. An OLED device according to claim 1;

wherein the OLED particulate comprises microcapsules, each microcapsule including an internal phase and shell, the internal phase including an OLED material, and wherein the shell is relatively less electrically conductive than the OLED material so that the OLED particulate offers a path of less electrical resistance than the shell.

9. An OLED device according to claim 1;

wherein the OLED particulate comprises microcapsules, each microcapsule including an internal phase and shell, the shell including an OLED component material being one of a hole transport material and an electron transport material, and the internal phase comprising an OLED component material being the other of a hole transport material and an electron transport material.

10. An OLED device according to claim 1;

wherein the carrier material has optical properties so that during the use of the OLED device the carrier material is one of transparent, diffusive, absorptive, and reflective to light energy.

11. An OLED device according to claim 1;

wherein material characteristics of the OLED particulate includes at least one of a magneto-rheological characteristic and an electro-rheological characteristic for causing the OLED particulate to orient in an applied electrical field.

12. An OLED device according to claim 1;

wherein the OLED particulate comprises microcapsules, each microcapsule including an internal phase comprised of OLED material and magnetically reactive material disposed within a first shell;

an electrolyte and curable material; and

a second shell encapsulating the first shell, the electrolyte and the curable material, wherein in response to an applied magnetic field, the position of the first shell is changeable relative to the second shell, and upon curing of the curable material, the position of the first shell relative to the second shell is locked in place.

13. An OLED device comprising, a first OLED pixel layer comprised of a first layer electrode, a second layer electrode disposed adjacent to the first electrode and defining a first layer gap there between, an OLED particulate wherein the OLED particulate comprises organic-layered particles, each organic-layered particle including a hole transport layer and an electron transport layer having a hetero-junction there between, and a carrier material disposed within said first layer gap and containing said OLED particulate, and at least one subsequent OLED pixel layer comprised of a first subsequent layer electrode, a second subsequent layer electrode disposed adjacent to the first subsequent layer electrode and defining a second layer gap there between, said OLED particulate, and the carrier material disposed within said second layer gap and containing said OLED particulate.

14. An OLED device according to claim 13;

wherein said OLED particulate of the first OLED pixel layer emits light of a first wavelength range in response to a driving voltage being applied to the first layer electrode and the second layer electrode; and

each said OLED particulate of each said subsequent OLED pixel layer emits light of a different wavelength range in response to the driving voltage being applied to each first subsequent layer electrode and each second subsequent layer electrode.

15. An OLED device according to claim 14;

wherein said OLED particulate of the first OLED pixel layer emits light in a red color range;

said OLED particulate of a first subsequent OLED pixel layer emits light in a green color range; and

said OLED particulate of a second subsequent OLED pixel layer emits light in a blue color range.

16. An OLED device according to claim 14;

further comprising a dichromatic pixel layer disposed adjacent to a last said subsequent OLED pixel layer, the dichromatic pixel layer comprising a first dichromatic electrode, a second dichromatic electrode disposed adjacent to the first dichromatic electrode and defining a dichromatic pixel gap there between, and a dichromatic element disposed in said dichromatic pixel gap.

17. An OLED device according to claim 14;

wherein said OLED particulate of the first OLED pixel layer emits light in a red color range;

said OLED particulate of a first subsequent OLED pixel layer emits light in a green color range;

said OLED particulate of a second subsequent OLED pixel layer emits light in a blue color range; and

said OLED particulate of at least one additional subsequent OLED pixel layer emit light in at least one of an additional color range or having a color and/or light intensity different from the color and/or light intensity of other OLED particulate.

18. An OLED device according to claim 13;

wherein the second layer electrode comprises the same electrode as the first subsequent layer electrode.

19. An OLED device according to claim 13;

wherein said OLED particulate of the first OLED pixel layer emits electrical energy in response to reception of photons of a first wavelength range and applies the electrical energy as a detectable signal to the first layer electrode and the second layer electrode; and

each said OLED particulate of each said subsequent OLED pixel layer emits electrical energy in response to reception of photons of a different wavelength range and applies the electrical energy as a detectable signal to each first subsequent layer electrode and each second subsequent layer electrode.

20. An OLED device according to claim 13;

wherein said OLED particulate of at least one said subsequent OLED pixel layer emits electrical energy in response to reception of photons and applies the electrical energy as a detectable signal to said first subsequent layer electrode and said second subsequent layer electrode of said at least one said subsequent OLED pixel layer.

21. An OLED device, comprising:

a first electrode layer;

a second electrode layer disposed adjacent to the first electrode layer and defining a gap therebetween;

a carrier material disposed within the gap; and

OLED particulate disposed within the carrier material, the OLED particulate comprising multi-layered organic particles having at least an electron transport layer and a hole transport layer having a hetero-junction therebetween.

22. An OLED device according to claim 21;

wherein the multi-layered organic particles of the OLED particulate are effective receiving through the carrier material electrical charges from the first electrode layer and the second electrode layer and generating photon emissions in response to receiving said electrical charges.

23. An OLED device according to claim 22;

wherein the multi-layered organic particles are selectively positioned and oriented in the carrier material to increase the conversion efficiency of said electrical charges to said photon emissions.

24. An OLED device according to claim 23;

wherein the first electrode layer comprises an x-electrode layer having x-electrode lines;

the second electrode layer comprises a y-electrode layer having y-electrode line disposed adjacent to the x electrode layer and defining a gap therebetween so that pixel volumes are defined at intersections of respective x-electrode lines and y-electrode lines; and

wherein the OLED particles are selectively positioned and oriented in the carrier material so that there is a greater distribution of OLED particles in the pixel volumes than between the pixel volumes.

25. An OLED device according to claim 21;

wherein each multi-layered organic particle further includes at least one of a blocking layer and an emissive layer.

26. An OLED device according to claim 21;

wherein the carrier material is relatively less electrically conductive than the OLED particulate so that the OLED particulate offers a path of less electrical resistance than the carrier material.

27. An OLED device according to claim 21;

wherein the multi-layered organic particles of the OLED particulate are effective for forming a light detecting particle by receiving a photon and separating electrical charges in response to the received photon, the separated electrical charges being transfer through the carrier material to the first electrode layer and the second electrode.

28. An OLED device according to claim 21;

wherein the multi-layered organic particles are selectively positioned and oriented in the carrier material to increase the conversion efficiency of said received photons to said separated electrical charges.

29. An OLED device according to claim 27;

wherein each multi-layered organic particle further includes at least one of a blocking layer and an emissive layer.