Antimicrobial yarn having nanosilver particles and methods for manufacturing the same

• US 6,979,491 B2
• Filed: 03/27/2002
• Issued: 12/27/2005
• Est. Priority Date: 03/27/2002
• Status: Expired due to Term

• Current Assignee: CC Technology Investment Company Limited
• Original Assignee: CC Technology Investment Company Limited
• Inventors: Yan, Jixiong, Cheng, Jiachong
• Primary Examiner(s): SINGH-PANDEY, ARTI R
• Application Number:
  US10/106,033
• Publication Number:
  US 20030190851A1
• Time in Patent Office: 1,371 Days
• Field of Search: 106/1.13, 106/1.14, 106/1.18, 106/1.19, 106/2, 106/15.05, 442/123, 442/124, 442/1.29, 442/402, 442403-405, 428/361, 428/365, 428/907, 572/32
• US Class Current: 428/361
• CPC Class Codes: D02G 3/449 Yarns or threads with antibacterial properties filaments containing agents inhibiting growth of microorganisms D01F1/103
• CPC Class Codes: D06M 11/65 Salts of oxyacids of nitrogen
• CPC Class Codes: D06M 16/00 Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
• CPC Class Codes: D06M 23/08 Processes in which the treating agent is applied in powder or granular form adhesives for multi-layer textile fabrics D06M17/00
• CPC Class Codes: Y10S 428/907 Resistant against plant or animal attack
• CPC Class Codes: Y10T 428/2907 with coating or impregnation
• CPC Class Codes: Y10T 428/2915 including textile, cloth or fabric
• CPC Class Codes: Y10T 442/2525 Coating or impregnation functions biologically [e.g., insect repellent, antiseptic, insecticide, bactericide, etc.]
• CPC Class Codes: Y10T 442/2533 Inhibits mildew

Abstract

The present invention provides a yarn with antimicrobial effects. The antimicrobial antifungal effect of the yarn is derived from nanosilver particles (diameter between 1 and 100 nm) which are adhered to the yarn. The yarn contains fibers which are made of cotton, linen, silk, wool, leather, blending fabric, synthetic fiber, or any combination thereof. The yarn can be used to make cloth to be used particularly for treating patients with burns or wound. The cloth made from the antimicrobial yarn can be further used to make clothes such as underwears, socks, shoe cushions, shoe linings, bed sheets, pillow cases, towels, women hygiene products, laboratory coats, and medical robes. The present invention also provides a method for making the antimicrobial yarn.

Claims

1. A yarn comprising nanosilver particles attached to the fibers thereof, said nanosilver particles being 1-100 nm in diameter and made by reducing silver nitrate with a reducing agent and without using ammonia water.

3. A yarn according to claim 1, wherein said reducing agent is glucose, vitamin C, or hydrazine hydrate.

4. A yarn according to claim 1, wherein said fibers of said yarn are made of one or more types of material selected from the group consisting of cotton, linen, silk, wool, blending fabric, and synthetic fiber.

5. A yarn according to claim 1, which is dyed with a color or not dyed.

6. A yarn according to claim 1, which is used for the purpose of inhibiting growth of bacteria, fungi, or chlamydia.

7. A yarn according to claim 6, which is used for the purpose of inhibiting growth of Escherichia coli, Methicillin resistant Staphylococcus aureus, Chlamydia trachomatis, Providencia stuartil, Vibrio vulnificus, Pneumobacillus, Nitrate-negative bacillus, Staphylococcus aureus, Candida albicans, Bacillus cloacae, Bacillus allantoides, Morgan'"'"'s bacillus (Salmonella morgani), Pseudomonas maltophila, Pseudomonas aeruginosa, Neisseria gonorrhoeae, Bacillus subtilis, Bacillus foecalis alkaligenes, Streptococcus hemolyticus B, Citrobacter, and Salmonella paratyphi C.

8. An antibacterial or antifungal cloth, which is made from a yarn according to claim 1.

9. An antibacterial or antifungal cloth according to claim 8, which is used to treat patient with burn and scald-related skin infection, wound-related skin infection, dermal or mucosal bacterial or fungal infection, surgery cut infection, vaginitis, or acne-related infection.

10. An antibacterial cloth according to claim 8, which is used to fabricate underwears, socks, shoe cushions, shoe linings, bed sheets, pillow shams, towels, women hygiene products, laboratory coat, or medical robes.

11. A method of fabricating a yarn of claim 1, comprising the steps of:

(a) mixing an aqueous solution of silver nitrate with an aqueous solution of a non-ammonia reducing agent to form a nanosilver particle-containing solution;

(b) soaking a conventional yarn in said nanosilver particle-containing solution or spraying said nanosilver particle-containing solution onto a conventional yarn; and

(c) dehydrating or drying said conventional yarn that contains said nanosilver particle containing solution to form said yarn with antimicrobial activity.

12. A method according to claim 11, wherein said conventional yarn is pre-degreased before step (b).

13. A method according to claim 11, wherein said aqueous silver nitrate solution and said aqueous solution of reducing agent are mixed at 0-40°

C. in step (a).

14. A method according to claim 11, wherein step (b) is performed by spraying said nanosilver particle-containing solution onto a conventional yarn.

15. A method according to claim 11, further comprising, after step (c), a step of treating said yarn with antimicrobial activity with heat at 120-160°

C. for about 40-60 minutes.

16. A method according to claim 11, wherein said reducing agent is glucose, vitamin C, or hydrazine hydrate.

17. A method according to claim 11, wherein each liter of said nanosilver particle-containing solution comprises 2-40 g of silver nitrate and 0.5-62 g of reducing agent.

18. A method according to claim 17, wherein said reducing agent is glucose.

19. A method according to claim 17, wherein said silver nitrate and said glucose is at a ratio of about 0.03-80:

1 by weight.

2. A yarn comprising nanosilver particles attached to the fibers thereof, said nanosilver particles accounting for about 0.2 to 1.5% by weight of the total weight of said yarn.