Transparent plastic optical components and abrasion resistant polymer substrates and methods for making the same

• US 7,018,057 B2
• Filed: 08/04/2003
• Issued: 03/28/2006
• Est. Priority Date: 08/23/2000
• Status: Expired due to Fees

• Current Assignee: Vtec Technologies, LLC
• Original Assignee: Vtec Technologies, LLC
• Inventors: Richard, David A.
• Primary Examiner(s): Cherry, Euncha P.
• Application Number:
  US10/633,972
• Publication Number:
  US 20040027704A1
• Time in Patent Office: 967 Days
• Field of Search: None
• US Class Current: 359/883
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: G02B 5/0841 comprising organic materials, e.g. polymers
• CPC Class Codes: G02B 5/0866 incorporating one or more organic, e.g. polymeric layers
• CPC Class Codes: G02B 5/0883 with a refractive index gradient rugate filters G02B5/289

Abstract

A polymer-based component formed from a synthetic thermoplastic or thermoset resin substrate, such as polymethyl methacrylate, which is resistant to warping and distortion from moisture. A composite multi-layer surface-hardening coating is formed on at least the anterior surface of the resin substrate. The component can include a composite multi-layer reflective coating to form a mirror. A protective back-coat layer is deposited on a posterior surface of the mirror. A multi-layer weather-resistant coating may optionally be applied to the anterior surface of the polymer-based mirror in order to increase the weatherability and durability of the mirror. The various layers coating the synthetic resin substrate have their moisture permeabilities selected so that substantially equal amounts of moisture permeate through to both the anterior and posterior side of the synthetic resin substrate. A sol-gel coating can be used to deposit the multi-layers in a single step by providing gradient zones of zirconia/silica while enabling a hydrophobic or a hydrophilic exterior surface.

Claims

1. A plastic component, comprising:

a transparent synthetic resin substrate having an anterior surface and a posterior surface;

a tie-bond layer formed on said anterior surface and said posterior surface of said synthetic resin substrate; and

a multi-layer surface abrasion resistant coating on the tie-bond layer, the multi-layer surface abrasion resistant coating and tie-bond layer are formed by a single wet coating that is cured to provide at least two layers of the surface abrasion resistant coating having respective different concentrations of colloid particles.

2. The plastic component of claim 1 wherein metal oxide colloid particles are in the single wet coating to form the multi-layer abrasion resistant coating and the tie-bond layer.

3. The plastic component of claim 2, wherein the multi-layer surface abrasion resistant coating has varying amounts of Z_v(iPv)₂ and SiO₂ from said anterior substrate surface to an exterior surface of the multi-layer surface abrasion resistant coating.

4. The plastic component of claim 1, wherein the two layers provided in the surface abrasion resistant coating include a first layer on an exterior surface having a colloid particle concentration of approximately 75% by weight.

5. The plastic component of claim 4, wherein a second layer adjacent the first layer has approximately 10% by weight colloid particle concentration.

6. The plastic component of claim 5, wherein the tie-bond layer has approximately 15% by weight colloid particle concentration.

7. The plastic component of claim 6, wherein the tie-bond layer is a cathodic chemabsorbed colloid particle concentration formed in the single wet coating of a sol gel.

8. The plastic component of claim 7 further has a reflective coating.

9. The plastic component of claim 2, wherein the multi-layer surface abrasion resistant coating has an exterior surface of cathodic colloid particles to provide a hydrophobic coating.

10. The plastic component of claim 2, wherein the multi-layer surface abrasion resistant coating has an exterior surface of anodic colloid particles to provide a hydrophilic coating.

11. The plastic component of claim 2, wherein the multi-layer surface abrasion resistant coating has an exterior surface that is enabled to be one of hydrophobic and hydrophilic depending on an applied pH level to the exterior surface.

12. A plastic component comprising:

a transparent synthetic resin substrate having an anterior surface and a posterior surface;

a tie-bond layer formed on one of said anterior surface and said posterior surface of said synthetic resin substrate; and

a transparent multi-layer surface abrasion resistant coating on the tie-bond layer, the multi-layer surface abrasion resistant coating and tie-bond layer are formed by a single wet coating that is cured to provide at least two layers of the surface abrasion resistant coating having respective different concentrations of colloid particles including a first layer, on an exterior surface, containing a majority of the colloid particles by weight.

13. The plastic component of claim 12 wherein metal oxide colloid particles and an organosilicon polymer are in the single wet coating to form the multi-layer abrasion resistant coating and the tie-bond layer with the metal oxide colloid particles being approximately 50% by weight of the single wet coating and the transparent synthetic resin substrate includes one of a polymethyl methacrylate resin and a polycarbonate resin.

14. The plastic component of claim 13, wherein the multi-layer surface abrasion resistant coating has varying amounts of Z_v(iPv)₂ and SiO₂ from said anterior substrate surface to the exterior surface of the multi-layer surface abrasion resistant coating.

15. The plastic component of claim 13, wherein the two layers provided in the surface abrasion resistant coating include the first layer on the exterior surface having a colloid particle concentration of approximately 75% by weight.

16. The plastic component of claim 15, wherein a second layer adjacent the first layer has approximately 10% by weight colloid particle concentration.

17. The plastic component of claim 16, wherein the tie-bond layer has approximately 15% by weight colloid particle concentration.

18. The plastic component of claim 17, wherein the tie-bond layer is a cathodic chemabsorbed colloid particle concentration formed in the single wet coating of a sol gel.

19. The plastic component of claim 18 further has a reflective coating.

20. The plastic component of claim 13, wherein the multi-layer surface abrasion resistant coating has an exterior surface of cathodic colloid particles to provide a hydrophobic coating.

21. The plastic component of claim 13, wherein the multi-layer surface abrasion resistant coating has an exterior surface of anodic colloid particles to provide a hydrophilic coating.

22. The plastic component of claim 13, wherein the multi-layer surface abrasion resistant coating has an exterior surface that is enabled to be one of hydrophobic and hydrophilic depending on an applied pH level to the exterior surface.

23. The plastic component of claim 12, wherein the two layers provided in the multi-layer surface resistant coating includes the first layer having a zirconia/silica colloid particle concentration of approximately 75% by weight, and a second layer adjacent the first layer having a zirconia/silica colloid particle concentration of approximately 10% by weight and the tie-bond layer formed on the synthetic resin substrate having a zirconia/silica colloid particle concentration of approximately 15% by weight.

24. The plastic component of claim 23, wherein a reflective coating is provided on the other of said anterior surface and said posterior surface of said synthetic resin substrate to provide a mirror.

25. The plastic component of claim 23, wherein one of a hydrophobic and hydrophilic surface is provided on the surface of the first layer.

26. The plastic component of claim 23, wherein a cathodic chemabsorbed zirconia/silica layer is formed between the tie-bond layer and surface of the synthetic resin substrate.