Adhesive articles which contain at least one hydrophilic or hydrophobic layer, method for making and uses for same

• US 7,175,897 B2
• Filed: 11/12/2003
• Issued: 02/13/2007
• Est. Priority Date: 12/17/2002
• Status: Active Grant

• Current Assignee: Avery Dennison Corporation
• Original Assignee: Avery Dennison Corporation
• Inventors: Shih, Frank Y., Nguyen, Thanh V., Baron, Richard, Rizzo, Frank, Boulier, Paul, Gilbert, Michael
• Primary Examiner(s): TARAZANO, DONALD LAWRENCE
• Application Number:
  US10/712,978
• Publication Number:
  US 20040115412A1
• Time in Patent Office: 1,189 Days
• Field of Search: 214/403, 428/411.1, 428/483, 428/520, 428/522, 428/36.91, 428/343, 728/36, 436/52
• US Class Current: 428/36.91
• CPC Class Codes: A61B 5/14532 for measuring glucose, e.g. by tissue impedance measurement
• CPC Class Codes: B01L 2300/0825 Test strips
• CPC Class Codes: B01L 2300/0887 Laminated structure
• CPC Class Codes: B01L 2300/165 Specific details about hydrophobic, oleophobic surfaces
• CPC Class Codes: B01L 3/502707 characterised by the manufacture of the container or its components by shaping or joining plastic parts B29C59/00, B29C65/00; by laminating B32B37/00; manufacture of microstructural devices in general B81C
• CPC Class Codes: C09J 2423/006 in the substrate
• CPC Class Codes: C09J 2425/006 in the substrate
• CPC Class Codes: C09J 2431/00 Presence of polyvinyl acetate
• CPC Class Codes: C09J 2433/006 in the substrate
• CPC Class Codes: C09J 2467/006 in the substrate
• CPC Class Codes: C09J 7/22 Plastics; Metallised plastics
• CPC Class Codes: C09J 7/38 Pressure-sensitive adhesives [PSA]
• CPC Class Codes: Y10T 428/1393 Multilayer [continuous layer]
• CPC Class Codes: Y10T 428/24959 of adhesive layers
• CPC Class Codes: Y10T 428/28 Web or sheet containing structurally defined element or component and having an adhesive outermost layer
• CPC Class Codes: Y10T 428/31547 Of polyisocyanurate
• CPC Class Codes: Y10T 428/31797 Next to addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 436/117497 with a continuously flowing sample or carrier stream

Abstract

The present invention relates to an adhesive article which can be used as a layer in or a cover for various articles in which a hydrophilic or hydrophobic surface is desired. The adhesive article includes a base layer having a first surface and a second surface and a coating layer formed on the first surface of the base layer, where the coating layer contains at least one adhesive resin and at least one hydrophilic polymer; at least one adhesive resin (which can be a hydrophobic polymer) and at least one surfactant; or at least one adhesive resin, at least one hydrophilic polymer and at least one surfactant. Given the application, the coating layer can be formulated to provide either a hydrophilic or hydrophobic surface. The polymer portion of the coating provides the coating layer with sufficient hydrophilic properties to increase the rate fluid transport across (or in the area near) the coating layer.

Claims

1. An article for fluid transport comprising:

a substrate having at least one fluid transport structure;

at least one adhesive article, the adhesive article comprising;

a base layer having a first and second surface; and

at least one coating layer on at least one surface of a base layer, the coating layer comprising;

(A) at least one adhesive resin and (B) at least one hydrophilic polymer, at least one surfactant or a combination of at least one hydrophilic polymer and at least one surfactant, with the proviso that when (B) is only a surfactant, then the coating layer contains less than about 40% by weight polyurethane; and

wherein the hydrophilic polymer is selected from cellulosic polymers, polyvinyl alcohol, polyvinyl pyrrolidone, dextran, nylons, polyamides, hydroxyethyl methacrylate, starches and gelatins; and

wherein the at least one adhesive article is heat sealed to the substrate and covers the at least one fluid transport structure and the coating layer is positioned to contact fluid of the fluid transport structure.

2. The article of claim 1, wherein the coating layer comprises at least one adhesive resin and at least one hydrophilic polymer.

3. The article of claim 2, wherein the coating layer comprises from about 30% to about 99% by weight adhesive resin and from about 1% to about 70% by weight hydrophilic polymer.

4. The article of claim 1, wherein the coating layer comprises at least one adhesive resin and at least one surfactant.

5. The article of claim 4, wherein the coating layer comprises from about 70% to about 99.9% by weight adhesive resin and from about 0.1% to about 30% by weight surfactant.

6. The article of claim 1, wherein the coating layer comprises at least one adhesive resin, at least one hydrophilic polymer and at least one surfactant.

7. The article of claim 1, wherein the coating layer comprises from about 10% to about 90% by weight adhesive resin, from about 10% to about 90% by weight hydrophilic polymer, and from about 0.1% to about 10% by weight surfactant.

19. The article of claim 1 wherein the adhesive article is positioned to form a space within the fluid transport structure.

20. The article of claim 1 wherein the adhesive article is positioned on at least one spacer to form a space within the fluid transport structure.

21. The article of claim 20 wherein the space is formed by the adhesive article and the at least one spacer between the adhesive article and the substrate.

22. The article of claim 20 wherein the at least one spacer comprises two or more individual pieces.

8. A biosensor comprising:

a base plate having an electrode system;

a sample space formed on the base plate, the sample space being formed in such a manner as to enable the input of a sample;

a reaction layer located in the sample space; and

a cover for covering the top portion of the sample space, the cover being formed from an adhesive article, wherein the adhesive article comprises;

a base layer having a first and second surface; and

at least one coating layer on at least one surface of a base layer, the coating layer comprising;

(A) at least one adhesive resin and (B) at least one hydrophilic polymer, at least one surfactant or a combination of at least one hydrophilic polymer and at least one surfactant, with the proviso that when (B) is only a surfactant, then the coating layer contains less than about 40% by weight polyurethane.

9. The biosensor of claim 8, wherein the coating layer comprises at least one adhesive resin and at least one hydrophilic polymer.

10. The biosensor of claim 9, wherein the coating layer comprises from about 30% to about 99% by weight adhesive resin and from about 1% to about 70% by weight hydrophilic polymer.

11. The biosensor of claim 8, wherein the coating layer comprises at least one adhesive resin and at least one surfactant.

12. The biosensor of claim 11, wherein the coating layer comprises from about 70% to about 99.9% by weight adhesive resin and from about 0.1% to about 30% by weight surfactant.

13. The biosensor of claim 8, wherein the coating layer comprises at least one adhesive resin, at least one hydrophilic polymer and at least one surfactant.

14. The biosensor of claim 13, wherein the coating layer comprises from about 10% to about 90% by weight adhesive resin, from about 10% to about 90% by weight hydrophilic polymer, and from about 0.1% to about 10% by weight surfactant.

15. The biosensor of claim 8 further comprising an insulating layer formed over at least a portion of the base plate.

16. The biosensor of claim 8 further comprising an insulating layer formed over at least a portion of the base plate and a portion of the electrode system.

17. The biosensor of claim 8 wherein the sample space is formed by the cover and at least one spacer between the cover and the substrate.

18. The biosensor of claim 17 wherein the at least one spacer comprises two or more individual pieces.