Enhanced heat mirror films

• US 7,215,473 B2
• Filed: 08/17/2002
• Issued: 05/08/2007
• Est. Priority Date: 08/17/2002
• Status: Active Grant

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Fleming, Robert James
• Primary Examiner(s): CHANG, AUDREY Y
• Application Number:
  US10/222,473
• Publication Number:
  US 20040032658A1
• Time in Patent Office: 1,725 Days
• Field of Search: 359/494, 359/584, 359/585, 359/497, 359/498, 428/483, 428/457
• US Class Current: 359/585
• CPC Class Codes: B32B 17/10005 laminated safety glass or glazing
• CPC Class Codes: B32B 17/10009 characterized by the number, the constitution or treatment of glass sheets
• CPC Class Codes: B32B 17/10036 comprising two outer glass sheets
• CPC Class Codes: B32B 17/10174 Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
• CPC Class Codes: B32B 17/10761 containing vinyl acetal
• CPC Class Codes: B32B 2367/00 Polyesters, e.g. PET, i.e. polyethylene terephthalate
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: G02B 5/282 reflecting for infrared and transparent for visible light, e.g. heat reflectors, laser protection

Abstract

A heat mirror film containing visible light-transmissive and infrared reflective film comprising a birefringent dielectric multilayer support that reflects at least 50% of light in a band at least 100 nm wide in a wavelength region of interest, a metal or metal alloy layer whose thickness is such that the film is visible light-transmissive and its reflection band is broadened, and a crosslinked polymeric layer has improved infrared reflecting properties. The film can be joined or laminated into glazing (especially non-planar vehicular safety glazing) with reduced likelihood that the metal or metal alloy layer will be damaged or distorted.

Claims

1. A process for making a film comprising:

a) providing a visible light-transmissive birefringent dielectric multilayer support that reflects at least 50% of light in a band at least 100 nm wide in a wavelength region of interest, and

b) forming in either order atop the support;

i) a visible light-transmissive metal or metal alloy layer, and

ii) a crosslinked polymeric layer,

whereby the thickness of the metal or metal alloy layer is such that the film is at least about 20% visible light-transmissive and its reflection band is broadened with respect to that of the support.

2. A process according to claim 1 wherein the wavelength region of interest is the infrared region.

3. A process according to claim 1 wherein the metal or metal alloy layer is formed between the support and the crosslinked polymeric layer.

4. A process according to claim 1 wherein the crosslinked polymeric layer is formed between the support and the metal or metal alloy layer.

5. A process according to claim 1 wherein the crosslinked polymeric layer is formed by flash evaporation, vapor deposition and crosslinking of a radiation-crosslinkable monomer.

6. A process according to claim 1 wherein the film is extensible.

7. A process according to claim 1 wherein the metal or metal alloy layer comprises silver and the crosslinked polymeric layer comprises an acrylate polymer.

8. A process according to claim 1 further comprising modifying an interface between the metal or metal alloy layer and at least one adjacent layer within the film to enhance interlayer adhesion.

9. A process according to claim 8 wherein plasma treatment is employed between the metal or metal alloy layer and an adjacent layer within the film.

10. A process according to claim 8 wherein plasma treatment is employed between the metal or metal alloy layer and two adjacent layers within the film.

11. A process according to claim 1 further comprising stretching the film without substantial cracking or creasing of the metal or metal alloy layer.

12. A process according to claim 11 wherein the film, if heated, exhibits different shrinkage in two in-plane directions.

13. A process according to claim 1 further comprising heating and joining together the film and at least one layer of a mechanical energy-absorbing material to provide a safety glazing pre-laminate.

14. A process for making a glazing article comprising:

a) assembling a layer of glazing material and a film comprising a birefringent dielectric multilayer support that reflects at least 50% of light in a band at least 100 nm wide in a wavelength region of interest and which has atop the support in either order a crosslinked polymeric layer and a metal or metal alloy layer whose thickness is such that the film is at least about 20% visible light-transmissive and its reflection band is broadened, and

b) bonding the glazing material and film together into a unitary article.

15. A process according to claim 14 wherein the glazing material comprises glass and the article comprises an adhesive layer between the film and the glass.

16. A process for making a laminate article comprising:

a) assembling;

i) a first layer of a glazing material,

ii) a first mechanical energy-absorbing layer,

iii) a visible light-transmissive and infrared-reflective film comprising a birefringent dielectric multilayer support that reflects at least 50% of light in a band at least 100 nm wide in a wavelength region of interest and which has atop the support in either order a crosslinked polymeric layer and a metal or metal alloy layer whose thickness is such that the film is at least about 20% visible light-transmissive and its reflection band is broadened,

iv) a second mechanical energy-absorbing layer and

v) a second layer of gazing material,

 

so that the film is between the first and second mechanical energy-absorbing layers and the first and second mechanical energy-absorbing layers are between the first and second layers of glazing material,

b) removing residual air from between the layers, and

c) beating and applying pressure to bond the layers together into a unitary article.

17. A process according to claim 16 wherein the removal of residual air or the application of pressure to the layers is performed using at least one nip roll.

18. A process according to claim 16 wherein the glazing material layers are non-planar.

19. A process according to claim 18 wherein the layers are bonded together without substantial cracking, creasing or wrinkling of the film.

20. A process according to claim 16 wherein the crosslinked polymeric layer is formed by flash evaporation, vapor deposition and crosslinking of a radiation-crosslinkable monomer.

21. A process according to claim 16 wherein the crosslinked polymeric layer comprises an acrylate polymer.

22. A film comprising a birefringent dielectric multilayer support that reflects at least 50% of light in a band at least 100 nm wide in a wavelength region of interest and which has atop the support in either order a crosslinked polymeric layer and a metal or metal alloy layer whose thickness is such that the film is at least about 20% visible light-transmissive and its reflection band is broadened with respect to that of the support.

23. A film according to claim 22 wherein the wavelength region of interest is the infrared region.

24. A film according to claim 22 wherein the metal or metal alloy layer is between the support and the crosslinked polymeric layer.

25. A film according to claim 22 wherein the crosslinked polymeric layer is between the support and the metal or metal alloy layer.

26. A film according to claim 22 wherein an interface between the metal or metal alloy layer and an adjacent layer within the film has been subjected to an adhesion-enhancing treatment, or one or more adjacent layers comprises an adhesion-enhancing adjuvant, whereby the interlayer adhesion is increased.

27. A film according to claim 26 wherein the metal or metal alloy layer or an adjacent layer has been subjected to plasma treatment.

28. A film according to claim 22 wherein the film is stretched.

29. A film according to claim 22 wherein the metal or metal alloy layer has a crosslinked polymeric layer adjacent to each of its faces.

30. A film according to claim 22 further comprising one or more pairs of an additional crosslinked polymeric layer and an additional metal or metal alloy layer.

31. A film according to claim 22 wherein the metal or metal alloy layer comprises silver.

32. A film according to claim 22 wherein the crosslinked polymeric layer comprises an acrylate polymer.

33. A film according to claim 22 wherein the film can be laminated into an automotive windshield without substantial wrinkling.

34. A safety glazing pre-laminate comprising at least one layer of a mechanical energy-absorbing material joined to a visible light-transmissive and infrared-reflective film comprising a birefringent dielectric multilayer support that reflects at least 50% of light in a band at least 100 nm wide in a wavelength region of interest and which has atop the support in either order a crosslinked polymeric layer and a metal or metal alloy layer whose thickness is such that the film is at least about 20% visible light-transmissive and its reflection band is broadened with respect to tat of the support.

35. A glazing article comprising at least one layer of glazing material joined to a visible light-transmissive and infrared-reflective film comprising a birefringent dielectric multilayer support that reflects at least 50% of light in a band at least 100 nm wide in a wavelength region of interest id which has atop the support in either order a crosslinked polymeric layer and a metal or metal alloy layer whose thickness is such that the film is at least about 20% visible light-transmissive and its reflection band is broadened wit respect to that of the support.

36. An article according to claim 35 wherein the metal or metal alloy layer is between the support and the crosslinked polymeric layer.

37. An article according to claim 35 wherein the crosslinked polymeric layer is between the support and the metal or metal alloy layer.

38. An article according to claim 35 wherein an interface between die metal or metal alloy layer and an adjacent layer within the film has been subjected to an adhesion-enhancing treatment, or one or more adjacent layers comprises an adhesion-enhancing adjuvant, whereby the interlayer adhesion is increased.

39. An article according to claim 35 wherein the metal or metal alloy layer or an adjacent layer has been subjected to plasma treatment.

40. An article according to claim 35 wherein the metal or metal alloy layer comprises silver and the crosslinked polymeric layer comprises an acrylate polymer.

41. An article according to claim 35 wherein the glazing material comprises glass and the glazing article comprises an adhesive layer between the film and the glass.

42. An article according to claim 35 wherein the glazing material comprises non-planar glass and the laminate article is optically clear and infrared-reflective.

43. An article according to claim 35 wherein the article comprises a windshield.

44. An article according to claim 35 comprising architectural glazing.

45. A vehicle with glazing comprising at least one windshield, backlight, side window or skylight comprising a visible light-transmissive and infrared reflective film comprising a birefringent dielectric multilayer support that reflects at least 50% of light in a band at least 100 nm wide in a wavelength region of interest and which has atop the support in either order a crosslinked polymeric layer and a metal or metal alloy layer whose thickness is such that the film is at least about 20% visible light-transmissive and its reflection band is broadened with respect to that of the support.

46. A vehicle according to claim 45 wherein the crosslinked polymeric layer comprises silver and the crosslinked polymeric layer comprises an acrylate polymer.