Method of charging alkali metal polymer batteries

• US 7,307,402 B2
• Filed: 07/19/2004
• Issued: 12/11/2007
• Est. Priority Date: 07/19/2004
• Status: Active Grant

• Current Assignee: Bathium Canada Inc. (Bolloré SE)
• Original Assignee: Avestor (Bolloré SE)
• Inventors: Parent, Michel, Gagnon, Philippe, Vaillancourt, Jean-Pierre
• Primary Examiner(s): Easthom, Karl
• Assistant Examiner(s): Berhanu, Samuel
• Application Number:
  US10/893,311
• Publication Number:
  US 20060012335A1
• Time in Patent Office: 1,240 Days
• Field of Search: 320/116, 320/118, 320/119, 320/120, 320/124
• US Class Current: 320/118
• CPC Class Codes: H01M 10/052 Li-accumulators
• CPC Class Codes: H01M 10/441 for several batteries or cells simultaneously or sequentially
• CPC Class Codes: H01M 4/485 of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy H01M4/505, H01M4/525 take precedence
• CPC Class Codes: H02J 7/0019 using switched or multiplexed charge circuits

Abstract

A method of charging an electrochemical generator having a plurality of electrochemical cells. The method includes the step of charging the plurality of electrochemical cells such that the total voltage of the generator reaches a predetermined voltage level, followed by the steps of selecting a particular electrochemical cell and charging the particular electrochemical cell to its respective maximum voltage, such that the cathode(s) of the particular electrochemical cell is(are) restored to a fully-charged state. Once it has been restored to its fully-charged state, the particular electrochemical cell is allowed to discharge itself down to a nominal voltage. Each of the plurality of electrochemical cells of the generator is selected and charged to its respective maximum voltage in turn, according to a predetermined selection sequence.

Claims

1. A method of charging an electrochemical generator connected to a load application having a pre-set voltage limit, the electrochemical generator having a plurality of electrochemical cells, each electrochemical cell being characterized by a respective voltage and including at least one cathode, at least one anode and at least one electrolyte separator therebetween, the electrochemical generator being characterized by a total voltage substantially corresponding to a sum of the voltages the plurality of electrochemical cells, each electrochemical cell being chargeable to a respective maximum voltage at which each of its at least one cathode is restored to a respective original chemical state, said method comprising:

a) charging the plurality of electrochemical cells such that the total voltage of the electrochemical generator reaches a predetermined voltage level;

b) selecting a particular electrochemical cell of the electrochemical generator;

c) charging the particular electrochemical cell to its respective maximum voltage, thereby restoring each of the at least one cathode of the particular electrochemical cell to its respective original state;

d) controllably discharging the particular electrochemical cell from its respective maximum voltage to a nominal voltage that is less than its respective maximum voltage to prevent the sum of the voltages of the plurality of electrochemical cells from exceeding the pre-set voltage limit of the load application;

e) selecting a second particular electrochemical cell of the electrochemical generator and applying steps c) through d) to the second particular electrochemical cell; and

f) applying steps b) and d) to each of the plurality of electrochemical cells of the generator in turn, according to a selection sequence, until each electrochemical cell of the generator has been restored.

2. A method as defined in claim 1, further comprising maintaining each particular electrochemical cell at its respective maximum voltage for a predetermined period of time before discharging the particular electrochemical cell down to its respective nominal voltage.

3. A method as defined in claim 1, wherein charging of the particular electrochemical cell occurs in spurts.

4. A method as defined in claim 1, wherein the plurality of electrochemical cells of the generator are arranged in a stack, each electrochemical cell being characterized by a respective position within the stack, the selection sequence being based on the positions of the electrochemical cells within the stack.

5. A method as defined in claim 4, wherein the selection sequence is based on a random choice of positions within the stack of electrochemical cells.

6. A method as defined in claim 4, wherein the selection sequence is based on an ordered choice of positions within the stack of electrochemical cells.

7. A method as defined in claim 1, wherein the predetermined voltage level is a preset voltage limit of an application load of the electrochemical generator, said method further including the step of reducing via discharge the voltage of each of the remaining, non-selected electrochemical cells of the electrochemical generator before charging the particular electrochemical cell to its respective maximum voltage, thereby ensuring that the sum of the voltages of the plurality of electrochemical cells does not exceed the preset voltage limit of the application load.

8. A method as defined in claim 1, wherein the predetermined voltage level divided by the number of electrochemical cells comprised in the electrochemical generator is comprised into a range of about 2.8 Volts to about 3.2 Volts.

9. An electrochemical generator comprising at least two electrochemical cells and an electronic control system, said electronic control system being operative to implement the method defined in claim 1.