Magnetic substrates with high magnetic loading

• US 7,338,573 B2
• Filed: 10/18/2002
• Issued: 03/04/2008
• Est. Priority Date: 11/26/2000
• Status: Expired due to Term

• Current Assignee: MagnetNotes, Ltd.
• Original Assignee: MagnetNotes, Ltd.
• Inventors: Richards, Raymond, Boudouris, Randall
• Primary Examiner(s): Crispino; Richard
• Assistant Examiner(s): Musser; Barbara J.
• Application Number:
  US10/274,189
• Publication Number:
  US 20030077465A1
• Time in Patent Office: 1,964 Days
• Field of Search: 156/244.11, 156/244.16, 156/244.17, 156/244.23, 156/244.24, 156/272.4, 156/314, 156/315
• US Class Current: 156/244.11
• CPC Class Codes: B32B 2307/208 Magnetic, paramagnetic
• CPC Class Codes: B32B 27/18 characterised by the use of special additives
• CPC Class Codes: B32B 37/153 at least one layer is extruded and immediately laminated while in semi-molten state
• CPC Class Codes: B32B 38/145 Printing
• CPC Class Codes: G09F 7/04 the elements being secured or adapted to be secured by magnetic means
• CPC Class Codes: H01F 1/0027 Thick magnetic films forming thick magnetic films H01F41/16
• CPC Class Codes: H01F 41/16 the magnetic material being applied in the form of particles, e.g. by serigraphy , to form thick magnetic films or precursors therefor H01F41/18 -H01F41/24 take precedence
• CPC Class Codes: Y10T 428/31993 Of paper

Abstract

A method of forming a magnetic assembly having at least one magnetic layer having dimensions of thickness, width and length, and at least one printable substrate layer having dimensions of thickness, width and length, including the steps of providing a molten magnetic composition including about 70 wt-% to about 95 wt-% of at least one magnetic material and about 5 wt-% to about 30 wt-% of at least one thermoplastic binder, forming the magnetic composition into a magnetic layer at an elevated temperature and directly applying the magnetic layer at an elevated temperature to a first surface of a printable substrate layer wherein. An adhesion promoting composition may be further provided between the magnetic layer and the printable substrate layer for improving adhesion between the magnetic layer and the printable substrate layer.

Claims

1. The method of forming a multi-layer magnetic assembly in-line, said multi-layer magnetic assembly consisting of a magnetic layer, an adhesion promoting layer, and a printable substrate layer, said method comprising the steps of:

a) providing a hot melt magnetic composition, said hot melt magnetic composition comprising comprises about 80 wt-% to about 95 wt-% of at least one magnetic material and about 5 wt-% to about 20 wt-% of at least one thermoplastic material at an elevated temperature with an extruder;

b) providing a printable substrate layer;

c) providing an adhesion promoting layer on said printable substrate layer; and

d) applying said hot melt magnetic composition at an elevated temperature directly to said printable substrate layer with a first slot die application head to form a magnetic layer having a thickness of about 50 microns to about 305 microns on said printable substrate layer, the adhesion promoting layer between said printable substrate layer and said magnetic layer.

2. A method of forming a magnetic assembly having at least one magnetic layer having dimensions of thickness, width and length, and at least one printable substrate layer having dimensions of thickness, width and length, the method comprising the steps of:

a) providing a hot melt magnetic composition at an elevated temperature with an extruder, said magnetic hot melt composition comprising about 75 wt-% to about 95 wt-% of at least one magnetic material and about 5 wt-% to about 25 wt-% of at least one thermoplastic binder;

b) providing a printable substrate layer selected from paper, paper products and pasteboard;

c) providing an adhesion promoting layer on said printable substrate layer;

d) applying said hot melt magnetic composition directly with a slot die head to said printable substrate layer to form a magnetic layer on said printable substrate layer, said magnetic layer having a thickness of about 50 microns to about 305 microns, said adhesion promoting layer between said printable substrate layer and said hot melt magnetic layer; and

e) subjecting said magnetic assembly to a strong magnetic field sufficient to result in a permanent magnetic effectin the assembly.

3. The method of claim 2 wherein said adhesion promoting layer is an adhesive, a primer, a tie layer, or a mixture thereof.

4. The method of claim 2 wherein said adhesion promoting layer is a thermoplastic pressure sensitive adhesive or a water-based pressure sensitive adhesive.

5. The method of claim 3 wherein said adhesive comprises at least one polymer selected from the group consisting of polyolefins, polyesters, polyurethanes, polyamides, copolymers and terpolymers thereof.

6. The method of claim 2 wherein said adhesion promoting layer is thermoplastic, thermosetting, water based or solvent based.

7. The method of claim 2 wherein said adhesion promoting layer comprises at least one isocyanate or polyisocyanate and said magnetic composition comprises at least one polyurethane, polyamide or polyether.

8. The method of claim 2 wherein said magnetic composition is provided in pellet form.

9. The method of claim 2 wherein said thermoplastic binder comprises a polyolefin copolymer.

10. The method of claim 9 wherein said thermoplastic binder comprises an ethylene vinyl acetate copolymer. permanent magnetic effect in the assembly.

11. The method of claim 2 further comprising the step of forming said magnetic assembly into a plurality of magnetic sheet assemblies.

12. The method of claim 11 further comprising the step of layering the sheet assemblies together to form a stacked pad.

13. The method of claim 12 further comprising the step of binding said sheet assemblies together at one end.

14. The method of claim 2 wherein said adhesion promoting layer is provided on said printable substrate layer by applying an adhesion promoting composition said printable substrate layer in-line with said hot melt magnetic composition.

15. The method of claim 14 wherein said adhesion promoting layer is provided on said printable substrate layer in-line by coextruding said adhesion promoting composition with said hot melt magnetic composition.

16. The method of claim 15 wherein said adhesion promoting composition is applied using a second die head.

17. The method of claim 14 wherein said adhesion promoting composition is applied to said printable substrate layer substantially simultaneously with said hot melt magnetic composition.

18. The method of claim 2 wherein said magnetic hot melt composition comprises about 85% to about 95% of at least one magnetic material and about 5 wt-% to about 15 wt-% of at least one thermoplastic material.

19. The method of claim 2 wherein said adhesion promoting layer is pre-applied to said printable substrate layer.