Electrode material for lithium secondary battery, electrode structure comprising the electrode material and secondary battery comprising the electrode structure
First Claim
1. An electrode material for a lithium secondary battery, the electrode material comprising alloy particles, the alloy particles comprising:
- a silicon phase as a major component; and
an intermetallic compound dispersed in the silicon phase,wherein the intermetallic compound contains tin and at least one element selected from the group consisting of copper, nickel, cobalt, iron, manganese, vanadium, molybdenum, niobium, tantalum, titanium, zircon, yttrium, lanthanum, selenium, magnesium and silver,wherein the alloy particles have an average particle diameter of 0.02 μ
m to 5 μ
m, andwherein the crystallite size of the silicon phase is not less than 2 nm but no more than 500 nm, as determined by the Scherrer Equation Lc=0.94λ
/(β
cos θ
), where Lc is the crystallite size, λ
is the wavelength of the X-ray beam, β
is the full width at half maximum of peak and θ
is the Bragg angle of diffracted rays.
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Accused Products
Abstract
There are provided an electrode material for a lithium secondary battery which comprises alloy particles comprising silicon as a major component and having an average particle diameter of 0.02 μm to 5 μm, wherein the size of a crystallite of the alloy is not less than 2 nm but no more than 500 nm and an intermetallic compound containing at least tin is dispersed in a silicon phase and an electrode material for a lithium secondary battery which comprises alloy particles comprising silicon as a major component and having an average particle diameter of 0.02 μm to 5 μm, wherein the size of a crystallite of the alloy is not less than 2 nm but no more than 500 nm and an at least one intermetallic compound containing at least one element selected from the group consisting of aluminum, zinc, indium, antimony, bismuth and lead is dispersed in a silicon phase. Thereby, an electrode material for a lithium secondary battery, an electrode structure comprising the electrode material and a secondary battery comprising the electrode structure are provided in which a drop in capacity due to repeated charging/discharging is small, and the charge/discharge cycle life is improved.
66 Citations
7 Claims
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1. An electrode material for a lithium secondary battery, the electrode material comprising alloy particles, the alloy particles comprising:
-
a silicon phase as a major component; and an intermetallic compound dispersed in the silicon phase, wherein the intermetallic compound contains tin and at least one element selected from the group consisting of copper, nickel, cobalt, iron, manganese, vanadium, molybdenum, niobium, tantalum, titanium, zircon, yttrium, lanthanum, selenium, magnesium and silver, wherein the alloy particles have an average particle diameter of 0.02 μ
m to 5 μ
m, andwherein the crystallite size of the silicon phase is not less than 2 nm but no more than 500 nm, as determined by the Scherrer Equation Lc=0.94λ
/(β
cos θ
), where Lc is the crystallite size, λ
is the wavelength of the X-ray beam, β
is the full width at half maximum of peak and θ
is the Bragg angle of diffracted rays. - View Dependent Claims (2, 3, 4, 5, 6, 7)
-
Specification