Composition and process for well cleaning

• US 7,380,606 B2
• Filed: 02/28/2003
• Issued: 06/03/2008
• Est. Priority Date: 03/01/2002
• Status: Active Grant

• Current Assignee: Flotek Industries Incorporated
• Original Assignee: CESI Chemical, Inc. (Flotek Industries Incorporated)
• Inventors: Holcomb, David L., Pursley, John T., Penny, Glenn S.
• Primary Examiner(s): Feely; Michael J
• Application Number:
  US10/377,322
• Publication Number:
  US 20030166472A1
• Time in Patent Office: 1,922 Days
• Field of Search: 507/203, 507/263, 507/267, 507/261, 507/266, 166/311, 166/312
• US Class Current: 166/305.1
• CPC Class Codes: C09K 2208/20 Hydrogen sulfide elimination
• CPC Class Codes: C09K 8/035 Organic additives
• CPC Class Codes: C09K 8/28 containing organic additives
• CPC Class Codes: C09K 8/36 Water-in-oil emulsions
• CPC Class Codes: C09K 8/52 Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning
• CPC Class Codes: C09K 8/602 containing surfactants
• CPC Class Codes: C09K 8/74 combined with additives added for specific purposes
• CPC Class Codes: C09K 8/82 Oil-based compositions C09K8/64 takes precedence
• CPC Class Codes: Y10S 507/927 Well cleaning fluid

Abstract

Disclosed is a microemulsion well treatment microemulsion that is formed by combining a solvent-surfactant blend with a carrier fluid. In preferred embodiments, the solvent-surfactant blend includes a surfactant and a solvent selected from the group consisting of terpenes and alkyl or aryl esters of short chain alcohols. The disclosed well treatment microemulsion can be used in well remediation, stimulation and hydrogen sulfide mitigation operations. Additionally, the well treatment microemulsion can be used in the production of benzothiophenes through interaction with hydrogen sulfide.

Claims

1. A well treatment microemulsion comprising:

a solvent-surfactant blend, wherein the solvent-surfactant blend comprises;

a solvent selected from the group consisting of terpenes and alkyl or aryl esters of short chain alcohols; and

a surfactant;

a carrier fluid, wherein the carrier fluid is water-based and the surfactant is an oil-in-water surfactant mixture that includes an ethoxylated castor oil, polyoxyethylene sorbitan monopalmitate and polyethylene glycol; and

wherein the solvent-surfactant blend is combined with the carrier fluid to produce the well treatment microemulsion.

2. A well treatment microemulsion comprising:

a solvent-surfactant blend, wherein the solvent-surfactant blend comprises;

about 27% by volume surfactant, wherein the surfactant is an oil-in-water surfactant mixture that includes polyoxyethylene sorbitan monopalmitate,

ethoxylated castor oil and polyethylene glycol;

about 34% by volume d-limonene;

about 5% by volume isopropanol;

about 45% by volume water; and

about 5% by volume triethylene glycol;

a carrier fluid used to transport the solvent-surfactant blend into a wellbore; and

wherein the solvent surfactant blend is combined with the carrier fluid to produce the well treatment microemulsion.

3. A well treatment microemulsion comprising:

a solvent-surfactant blend, wherein the solvent-surfactant blend comprises;

a solvent selected from the group consisting of terpenes and alkyl or aryl esters of short chain alcohols; and

a surfactant, wherein the surfactant is a water-in-oil surfactant mixture that includes sorbitan monopalmitate, ethoxylated castor oil and polyethylene glycol;

a carrier fluid, wherein the carrier fluid is oil-based; and

wherein the solvent-surfactant blend is combined with the carrier fluid to produce the well treatment microemulsion.

4. A well treatment microemulsion comprising:

a solvent-surfactant blend, wherein the solvent-surfactant blend comprises;

a solvent selected from the group consisting of terpenes and alkyl or aryl esters of short chain alcohols;

a surfactant; and

wherein the solvent surfactant blend comprises;

25%-76% by volume surfactant;

14%-54% by volume d-limonene;

0%-20% by volume isopropanol; and

0%-20% by volume water and triethylene glycol;

a carrier fluid, wherein the carrier fluid is oil-based; and

wherein the solvent-surfactant blend is combined with the carrier fluid to produce the well treatment microemulsion.

5. The well treatment microemulsion of claim 4, wherein the solvent-surfactant blend includes:

about 56% by volume surfactant, wherein the surfactant is a water-in-oil surfactant mixture that includes sorbitan monopalmitate, ethoxylated castor oil and polyethylene glycol;

about 34% by volume d-limonene; and

about 10% by volume isopropanol.

6. A method for treating an oil or gas well having a wellbore, comprising:

forming a solvent-surfactant blend by combining a solvent and a surfactant, wherein the surfactant has a hydrophile-lipophile balance value of between 8-18 and wherein the surfactant is an oil-in-water surfactant mixture that includes an ethoxylated castor oil;

preparing a microemulsion by combining the solvent-surfactant blend with a water-based carrier fluid; and

injecting the microemulsion into the oil or gas well.

7. The method of claim 6, wherein the oil-in-water surfactant mixture also includes polyoxyethylene sorbitan monopalmitate and polyethylene glycol.

8. A method for treating an oil or gas well having a wellbore, comprising:

forming a solvent-surfactant blend by combining a solvent and a surfactant, wherein the surfactant is a water-in-oil mixture of ethoxylated castor oil, sorbitan monopalmitate and polyethylene glycol;

preparing a microemulsion by combining the solvent-surfactant blend with an oil-based carrier fluid; and

injecting the microemulsion into the oil or gas well.

9. A method for treating an oil or gas well having a wellbore, comprising:

forming a solvent-surfactant blend, wherein the solvent-surfactant blend comprises;

about 25%-76% by volume of an oil-in-water surfactant mixture that includes polyoxyethylene sorbitan monopalmitate, ethoxylated castor oil and polyethylene glycol;

about 14%-54% by volume d-limonene;

about 0%-20% by volume isopropanol; and

about 0%-50% by volume of water;

preparing a microemulsion by combining the solvent-surfactant blend with a carrier fluid;

combining the microemulsion with proppant material; and

injecting the microemulsion and proppant material into the wellbore to stimulate the oil or gas well.

10. A method for treating an oil or gas well having a wellbore, comprising:

forming a solvent-surfactant blend;

preparing a microemulsion by combining the solvent-surfactant blend with a carrier fluid, wherein the microemulsion comprises;

about 25%-76% by volume of a water-in-oil surfactant mixture that includes sorbitan monopalmitate, ethoxylated castor oil and polyethylene glycol;

about 14%-54% by volume d-limonene;

about 0%-20% by volume isopropanol; and

about 0%-5% by volume of water;

combining the microemulsion with a drilling fluid, wherein the drilling fluid is oil-based; and

injecting the microemulsion and drilling fluid into the oil or gas well during a drilling operation.

11. A method for treating an oil or gas well having a wellbore, comprising:

forming a solvent-surfactant blend;

preparing a microemulsion by combining the solvent-surfactant blend with a carrier fluid, wherein the microemulsion comprises;

about 25%-76% by volume of an oil-in-water surfactant mixture that includes polyoxyethylene sorbitan monopalmitate, ethoxylated castor oil and polyethylene glycol;

about 14%-54% by volume d-limonene;

about 0%-20% by volume isopropanol; and

about 0%-50% by volume of water;

combining the microemulsion with a drilling fluid, wherein the drilling fluid is water-based; and

injecting the microemulsion and drilling fluid into the oil or gas well during a drilling operation.

12. A method for treating an oil or gas well having a wellbore, comprising:

forming a solvent-surfactant blend, wherein the solvent-surfactant blend comprises;

about 25%-76% by volume surfactant;

about 14%-54% by volume d-limonene;

about 0%-20% by volume isopropanol; and

about 0%-50% by volume of water;

combining the solvent-surfactant blend with an acidified carrier fluid to prepare a microemulsion suitable for acidizing operations; and

injecting the microemulsion into the oil or gas well.

13. The method of claim 12, wherein the acidified carrier fluid includes one or more acids selected from the group of hydrochloric, acetic, formic, and hydrochloric-hydrofluoric acids.

14. The method of claim 12, wherein the acidified carrier fluid includes about 3%-28% acid by volume of the microemulsion.

15. The method of claim 14, wherein the acidified carrier fluid includes about 15% hydrochloric acid by volume of the microemulsion.

16. The method of claim 14, wherein the step of combining the solvent-surfactant blend with an acidified carrier fluid further comprises:

adding 0.2%-5% solvent-surfactant by volume of the microemulsion to the acidified carrier fluid.