Silicon oxycarbide coatings having durable hydrophilic properties

• US 7,482,060 B2
• Filed: 07/14/2004
• Issued: 01/27/2009
• Est. Priority Date: 07/14/2004
• Status: Active Grant

• Current Assignee: AGC Flat Glass North America Incorporated (AGC, Inc.)
• Original Assignee: AGC Flat Glass North America Incorporated (AGC, Inc.)
• Inventors: Oudard, Jean-Francois
• Primary Examiner(s): XU, LING X
• Application Number:
  US10/890,127
• Publication Number:
  US 20060014027A1
• Time in Patent Office: 1,658 Days
• Field of Search: 428/428
• US Class Current: 428/428
• CPC Class Codes: C03C 17/22 with other inorganic material C03C17/34, C03C17/44 take precedence
• CPC Class Codes: C03C 2217/282 Carbides, silicides
• CPC Class Codes: C03C 2218/152 by cvd
• CPC Class Codes: Y10T 428/12576 Boride, carbide or nitride component
• CPC Class Codes: Y10T 428/12993 Surface feature [e.g., rough, mirror]
• CPC Class Codes: Y10T 428/2495 Thickness [relative or absolute]

Abstract

A silicon oxycarbide coating remains hydrophilic for a significantly longer period of time, on the order of several months, when both (i) the coating index of refraction is 1.70 or more and (ii) the coating thickness is 350 Å or more.

Claims

1. A coating having opposing first and second surfaces, where the first surface is in contact with either a solid substrate or an optional optical stack between the coating and the solid substrate, and the second surface is in contact with essentially only air at atmospheric pressure and a temperature of less than 100°

C., wherein

the coating has

a homogeneous composition comprising a silicon oxycarbide,

an index of refraction of 1.70 or more, and a thickness of 350 Å

or more; and

the second surface of the coating is hydrophilic with a contact angle with water of less than 20 degrees.

2. The coating according to claim 1, wherein the silicon oxycarbide comprisesatomic % or less Si, but more than 0 atomic % Si;

55 atomic % or less 0, but more than 0 atomic % 0; and

30 atomic % or less C, but more than 0 atomic % C.

3. The coating according to claim 1, wherein the silicon oxycarbide comprises SiOC.

4. The coating according to claim 1, wherein the index of refraction is in a range of 1.70 to 2.0.

5. The coating according to claim 1, wherein the thickness is in a range of 350 Å

to 800Å

.

6. The coating according to claim 1, wherein the coating was produced by a chemical vapor deposition process.

7. The coating according to claim 6, wherein the chemical vapor deposition process comprised exposing the solid substrate at a temperature in a range of from 400°

C. to 800°

C. to an atmosphere containing silane, ethylene, carbon dioxide and nitrogen.

8. The coating according to claim 1, wherein the first surface of the coating is in contact with a solid substrate comprising a glass.

9. The coating according to claim 8, wherein the first surface of the coating is in contact with an optical stack between the coating and the glass.

10. The coating according to claim 1, wherein the second surface of the coating is hydrophilic with a contact angle with water of less than 10 degrees.

11. The coating according to claim 1, wherein the second surface of the coating is hydrophilic with a contact angle with water of less than 5 degrees.

12. The coating according to claim 1, wherein the index of refraction is greater than 1.80.

13. A method of making a coating, the method comprising

depositing on a solid substrate by a chemical vapor deposition process a silicon oxycarbide composition;

and

producing the coating of claim 1.

14. The method according to claim 13, wherein the chemical vapor deposition process comprises exposing the solid substrate at a temperature in a range of from 400°

C. to 800°

C. to an atmosphere containing silane, ethylene, carbon dioxide and nitrogen.

15. A method of using a coating, the method comprising supporting the coating of claim 1 in a window frame.

16. A method of using a coating, the method comprising placing the coating of claim 1 between an interior region and an exterior region containing contaminants.

17. A method of using a coating to keep a substrate free of contamination, the method comprising

exposing the coating of claim 1 to the outdoors;

and

washing the second surface of the coating with a glass cleaner.

18. The method according to claim 17, wherein the glass cleaner comprises water and at least one member of the group consisting of soap and vinegar.

19. The method according to claim 17, wherein after the washing the second surface of the coating remains hydrophilic, with a contact angle with water of less than 20 degrees, in an environment longer than a silicon oxycarbide layer having an index of refraction of less than 1.70 and a thickness of less than 350 Å

in the same environment.

20. The method according to claim 19, wherein after the washing the second surface of the coating remains hydrophilic, with a contact angle with water of less than 20 degrees, in an environment at least twice as long as the silicon oxycarbide layer having an index of refraction of less than 1.70 and a thickness of less than 350 Å

in the same environment.

21. The method according to claim 19, wherein after the washing the second surface of the coating remains hydrophilic, with a contact angle with water of less than 20 degrees, in an environment at least five times as long as the silicon oxycarbide layer having an index of refraction of less than 1.70 and a thickness of less than 350 Å

in the same environment.