Luminous materials

• US 7,507,352 B2
• Filed: 06/08/2001
• Issued: 03/24/2009
• Est. Priority Date: 06/08/2000
• Status: Expired due to Fees

• Current Assignee: Visual 24/7, Ltd.
• Original Assignee: Dualglo Technology, PLC
• Inventors: Lambert, Stephen, Baillie, Craig Jameson
• Primary Examiner(s): KOSLOW, CAROL M
• Application Number:
  US10/297,461
• Publication Number:
  US 20040021407A1
• Time in Patent Office: 2,846 Days
• Field of Search: 439/490, 501/32, 362/84, 362/95, 362/205, 200310-317, 428/690, 428/325, 428/355.R, 428/141, 428/143, 428/149, 252/301.33, 252/301.36, 252/301.6 F, 252/301.6 R, 252/301.4 R, 252/301.4 F
• US Class Current: 252/301.36
• CPC Class Codes: C09K 11/02 Use of particular materials as binders, particle coatings or suspension media therefor
• CPC Class Codes: C09K 11/025 non-luminescent particle coatings or suspension media
• CPC Class Codes: C09K 11/08 containing inorganic luminescent materials
• CPC Class Codes: F21K 2/00 Non-electric light sources using luminescence using excitation by radioactivity G21H3/02, H01J65/06, H01J65/08; using excitation by an external electromagnetic field or by external corpuscular radiation H01J65/04; Light sources using electrochemiluminescence
• CPC Class Codes: H01H 9/185 Fluorescent or phosphorescent symbols or distinguishing marks H01H9/181 takes precedence
• CPC Class Codes: Y02B 20/00 Energy efficient lighting technologies, e.g. halogen lamps or gas discharge lamps
• CPC Class Codes: Y10T 428/24355 Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
• CPC Class Codes: Y10T 428/252 Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]
• CPC Class Codes: Y10T 428/2852 Adhesive compositions

Abstract

A luminous material comprising a rubber, glass or plastics material matrix. A luminescent material is dispersed throughout the matrix, and a colorant dispersed throughout the matrix. The colourant gives the matrix a colour when it is observed under substantially white light, and the colourant allowing substantial transmission of light emitted by the luminous material.

Claims

1. A luminous material comprising a rubber, glass or plastics material matrix, a rare earth metal luminescent material dispersed throughout the matrix and titanium dioxide with a particle size of less than one micron dispersed throughout the matrix as a colourant, the colourant allowing substantial transmission of light emitted by the luminous material.

2. A luminous material according to claim 1, in which the luminescent material comprises a rare earth metal which is selected from one of europium or dysprosium.

3. A luminous material according to claim 1, in which the luminescent material is in the form of a metal oxide or an aluminate.

4. A luminous material according to claim 1, in which the luminescent material further comprises an alkaline earth metal which is strontium.

5. A luminous material according to claim 1, in which the luminescent material comprises particles having dimensions between 8 and 100 micrometers.

6. A luminous material according to claim 1, in which the percentage by weight of the luminescent material to the matrix is between 4% and 32.5%.

7. A luminous material according to claim 6, in which the percentage by weight of the luminescent material is between 4% and 20%.

8. A luminous material according to claim 6, in which the percentage by weight of the luminescent material is between 6% and 12%.

9. A luminous material according to claim 1, in which the matrix material is polyurethane, a co-polymer of styrene and butadiene, a polyolefin which comprises a selected one of polypropylene or polyethylene, acrylic, ABS, polyethylene-terephthalate or polycarbonate.

10. A luminous material according to claim 1 in which the luminescent material constitutes at least 90% by weight of the combined weight of the luminescent material and the colourant.

11. A luminous material according to claim 10, in which luminescent material constitutes between 94% and 99% by weight of the combined weight of the luminescent material and the colourant.

12. A luminous material according to claim 10, in which luminescent material constitutes between 94 to 96% thereof by weight of the combined weight of luminescent material and the colourant.

13. A luminous material according to claim 1, in which the percentage by weight of the colourant to the matrix material is between 0.2% and 1%.

14. A luminous material according to claim 1, in which the material matrix is an engineering grade polymer.

15. A luminous material according to claim 14, in which the polymer is one of acrylic, ABS, polycarbonate or a polyamide such as nylon or a polyamide elastomer.

16. A luminous material according to claim 1, in which the percentage by weight of the luminescent material to the combined weight of the luminescent material and the colourant is at least 99%.

17. A luminous material according to claim 16, in which the percentage by weight of the luminescent material to the combined weight of the luminescent material and the colourant is between 99.1% and 99.98%.

18. A luminous material according to claim 16, in which the percentage by weight of the luminescent material to the combined weight of the luminescent material and the colourant is between 99.7% and 99.9%.

19. A luminous material according to claim 14, in which the percentage by weight of the colourant to the engineering grade polymer matrix is between 0.005% and 0.05%.

20. A luminous material according to claim 1, in which the percentage by weight of the luminescent material to the combined weight of the luminescent material and the colourant is at least 97%.

21. A luminous material according to claim 20, in which the percentage by weight of the luminescent material to the combined weight of the luminescent material and the colourant is between 98.2% and 99.67%.

22. A luminous material according to claim 1, in which the percentage by weight of the colourant to the matrix material is between 0.3 3% and 3%.

23. A luminous material according to claim 1, in which the matrix material used with the colourant is of a high clarity and is one of polyurethane, a co- polymer of styrene and butadiene, a polyolefin, ABS or a polyamide.

24. A luminous material according to claim 1, in which the colourant additionally comprises silicon dioxide.

25. A luminous material according to claim 1, in which the luminous material further comprises an optical brightener dispersed in the matrix such that both the visibility of the material in daylight, and the visibility in the dark, via the luminescence, is enhanced.

26. A luminous material according to claim 25, in which the optical brightener is a fluorescent blue dye.

27. A luminous material according to claim 1, in which the matrix material has a high clarity.

28. A luminous material according to claim 1, in which the opacity of the matrix is increased with the addition of the colourant and luminescent material.

33. A colourant combination comprising a colourant and a luminescent material, the colourant combination being suitable for adding to a rubber, glass or plastics material matrix for the creation of a luminous material according to claim 1.

34. A colourant combination according to claim 33, in which the colourant combination is prepared in a universal masterbatch carrier, which is advantageously ethylene-based and made of selected one of polyethylene methacrylate or polyethylene vinyl acetate.

35. A colourant combination according to claim 34, in which the colourant combination is prepared in the carrier at a concentration of up to about 65% by weight of the matrix material.

36. A colourant combination according to claim 33, in which the colourant combination is prepared in a machine fitted with a low shear screw.

37. A colourant combination according to claim 33, in which the colourant combination is prepared by adding the luminescent material and the colourant to the carrier when the carrier is substantially heated or melted.

38. A colourant combination according to claim 33, in which the colorant combination further comprises optical brighteners.

39. A non-luminous article provided with a coating, or outer layer, of luminous material according to claim 1.

40. An article comprising the luminous material according to claim 1.

41. An article according to claim 40, in which the article is made by moulding the luminous material.

42. An article according to claim 41 in which the moulding is formed by injection or co-injection.

43. An article according to claim 40, in which the article is made by extruding the luminous material.

44. An article according to claim 40, in which the article is a switch that actuates an electrical connection to a conductive element that is associated with and separate from the switch.

45. An article according to claim 44 , in which the switch is suitable for use in controlling a selected one of an electric light or a computer keyboard.

46. An article according to claim 44, in which the switch actuates an electrical light emitting device, which is controlled by the switch, such that light is emitted when the switch is in the on position.

47. An article according to claim 44, in which the switch is water-proof

48. An article according to claim 44, in which the switch is retarded against fire.

49. An article according to claim 40, in which the article is a flashlight casing, or part therefor, which is a rubber or plastics moulding.

50. An article according to claim 49, in which the moulding for the casing or part therefor is shaped from a matrix comprising a rubber or plastics material which is selected from one of a thermoplastic or a thermoset with colorant materials dispersed therein.

51. An article according to claim 40, in which the article is an electrical plug which is retarded against fire.

52. An article comprising the luminous material of claim 1 the article including a reverse or inner side and a substantially reflective layer on its reverse or inner side.

53. The article of claim 52, in which the reflective layer is white.

54. An article comprising the luminous material of claim 1 the article including a layer applied thereto containing reflective glass beads.

55. An adhesive tape, film or layer comprising the luminous material of claim 1.

56. The adhesive tape, film or layer of claim 55, in which the luminescent material constitutes not more than 65% by weight of the total of the luminescent material, the colourant and the matrix material used to make the tape.

29. A method for making a luminous material, comprising the steps of a) providing a rubber, glass or plastics matrix material;

b) compounding a titanium dioxide colourant having a particle size of less than one micron into the matrix material; and

c) compounding a rare earth metal luminescent material into the matrix material, the luminescent material including at least one alkaline earth metal and at least one rare earth metal;

wherein the colourant provides the matrix material with a substantially white color when it is observed under substantially white light and wherein the opacity of the matrix is increased with the compounding of such colourant and luminescent material.

30. A method according to claim 29, in which step b and step c are performed sequentially such that one of the steps is performed before the other.

31. A method according to claim 29, in which the compounding steps of b and c are combined into a single blending step.

32. A method according to claim 29, in which the making of the luminous material is carried out using machinery adapted to reduce shearing of the material.