Method and apparatus for in-situ characterization of energy storage and energy conversion devices

• US 7,675,293 B2
• Filed: 05/04/2006
• Issued: 03/09/2010
• Est. Priority Date: 05/04/2006
• Status: Active Grant

• Current Assignee: Battelle Energy Alliance LLC (Battelle Memorial Institute)
• Original Assignee: Battelle Energy Alliance LLC (Battelle Memorial Institute)
• Inventors: Albrecht, Weston, Morrison, John L., Motloch, Chester G., Christophersen, Jon P.
• Primary Examiner(s): Natalini; Jeff
• Application Number:
  US11/381,689
• Publication Number:
  US 20070257681A1
• Time in Patent Office: 1,405 Days
• Field of Search: 324/613, 324/430
• US Class Current: 324/613
• CPC Class Codes: G01R 31/367 Software therefor, e.g. for battery testing using modelling or look-up tables
• CPC Class Codes: G01R 31/389 Measuring internal impedance, internal conductance or related variables

Abstract

Disclosed are methods and apparatuses for determining an impedance of an energy-output device using a random noise stimulus applied to the energy-output device. A random noise signal is generated and converted to a random noise stimulus as a current source correlated to the random noise signal. A bias-reduced response of the energy-output device to the random noise stimulus is generated by comparing a voltage at the energy-output device terminal to an average voltage signal. The random noise stimulus and bias-reduced response may be periodically sampled to generate a time-varying current stimulus and a time-varying voltage response, which may be correlated to generate an autocorrelated stimulus, an autocorrelated response, and a cross-correlated response. Finally, the autocorrelated stimulus, the autocorrelated response, and the cross-correlated response may be combined to determine at least one of impedance amplitude, impedance phase, and complex impedance.

Claims

1. An apparatus for characterizing an energy-output device, comprising:

a random noise generator configured for generating a random noise signal;

a current generator configured for generating a random noise stimulus that is correlated to the random noise signal and configured for operable coupling to an energy-output device terminal;

a current measurement device operably coupled to the random noise stimulus and configured for measuring the random noise stimulus to determine a measured noise stimulus;

a bias reducer operably coupled an average voltage signal and configured for operable coupling to the energy-output device terminal, the bias reducer configured for generating a bias-reduced response by substantially removing the average voltage signal offset from a voltage of the energy-output device terminal; and

an analyzer operably coupled to the measured noise stimulus and the bias-reduced response, the analyzer configured for correlating the measured noise stimulus and the bias-reduced response to determine an impedance of the energy-output device.

2. The apparatus of claim 1, wherein the random noise generator comprises:

a digital signal generator configured for generating a substantially random digital signal; and

a bandpass filter configured for filtering the substantially random digital signal to generate the random noise signal.

3. The apparatus of claim 2, wherein the bandpass filter is selected from the group consisting of a digital filter, an analog filter, and a combination thereof.

4. The apparatus of claim 1, wherein the bias reducer comprises a differential amplifier configured to generate the bias-reduced response by comparing the average voltage signal to the voltage of the energy-output device terminal.

5. The apparatus of claim 1, wherein the current measurement device comprises a resistor configured for operable coupling between the random noise stimulus and the energy-output device terminal, wherein the measured noise stimulus is measured as a voltage drop across the resistor.

6. The apparatus of claim 1, further comprising a voltage measurement device operably coupled to the random noise stimulus and the analyzer, the voltage measurement device configured for measuring the voltage of the energy-output device terminal;

and

wherein the analyzer includes a bias generator configured to generate the average voltage signal as an average of periodic samples of the voltage of the energy-output device terminal.

7. The apparatus of claim 1, further comprising an amplifier module, the amplifier module comprising:

a first amplifier operably coupled between the current measurement device and the analyzer and configured for amplifying the measured noise stimulus prior to use by the analyzer; and

a second amplifier operably coupled between the bias reducer and the analyzer and configured for amplifying the bias-reduced response prior to use by the analyzer.

8. The apparatus of claim 1, further comprising a filter module, the filter module comprising:

a first filter operably coupled between the current measurement device and the analyzer and configured for filtering the measured noise stimulus prior to use by the analyzer; and

a second filter operably coupled between the bias reducer and the analyzer and configured for filtering the bias-reduced response prior to use by the analyzer.

9. The apparatus of claim 1, wherein the analyzer is configured for:

periodically sampling the random noise stimulus to generate a time-varying current stimulus;

periodically sampling a voltage response of the energy-output device to the random noise stimulus to generate a time-varying voltage response;

autocorrelating the time-varying current stimulus to generate an autocorrelated stimulus;

autocorrelating the time-varying voltage response to generate an autocorrelated response;

cross-correlating the time-varying current stimulus and the time-varying voltage response to generate a cross-correlated response; and

combining the autocorrelated stimulus, the autocorrelated response, and the cross-correlated response to determine at least one of an impedance amplitude, an impedance phase, and a complex impedance.

10. The apparatus of claim 1, further comprising a computing system wherein the random noise generator, the analyzer, and a bias generator, are included in the computing system.

11. The apparatus of claim 10, wherein the analyzer includes computer instructions, which when executed by the computing system, perform the process of:

periodically sampling the random noise stimulus to generate a time-varying current stimulus;

periodically sampling a voltage response of the energy-output device to the random noise stimulus to generate a time-varying voltage response;

autocorrelating the time-varying current stimulus to generate an autocorrelated stimulus;

autocorrelating the time-varying voltage response to generate an autocorrelated response;

cross-correlating the time-varying current stimulus and the time-varying voltage response to generate a cross-correlated response; and

combining the autocorrelated stimulus, the autocorrelated response, and the cross-correlated response to determine at least one of an impedance amplitude, an impedance phase, and a complex impedance.

12. The apparatus of claim 11, further comprising a display, and wherein the analyzer includes additional computer instructions, which when executed by the computing system, perform the process of displaying, on the display, at least one characteristic of interest of the energy-output device.

13. The apparatus of claim 12, wherein the at least one characteristic of interest includes a visual presentation selected from the group consisting of a plot of the time-varying current stimulus, a plot of the time-varying voltage response, a plot of the average voltage signal, a plot of the bias-reduced response, a frequency plot of the impedance amplitude, a frequency plot of the impedance phase, a Nyquist plot of the complex impedance, and combinations thereof.

14. A method of determining an impedance of an energy-output device, comprising:

generating a random noise signal;

generating a random noise stimulus as a current source correlated to the random noise signal;

applying the random noise stimulus to an energy-output device terminal of the energy-output device;

measuring the random noise stimulus as a measured noise stimulus;

generating a bias-reduced response by comparing a voltage at the energy-output device terminal to an average voltage signal to substantially remove the average voltage signal offset from a voltage of the energy-output device terminal; and

correlating the measured noise stimulus and the bias-reduced response to determine the impedance of the energy-output device.

15. The method of claim 14, wherein generating the random noise signal comprises:

generating a substantially random digital signal; and

filtering the substantially random digital signal with a bandpass filter to generate the random noise signal.

16. The method of claim 15, wherein the filtering comprises a process selected from the group consisting of digital filtering, analog filtering, and a combination thereof.

17. The method of claim 14, wherein measuring the random noise stimulus comprises measuring a voltage drop across a resistor configured for operable coupling between the random noise stimulus and the energy-output device terminal.

18. The method of claim 14, further comprising:

measuring the voltage of the energy-output device terminal; and

generating the average voltage signal as an average of periodic samples of the voltage of the energy-output device terminal.

19. The method of claim 14, further comprising:

amplifying the measured noise stimulus prior to correlating the measured noise stimulus and the bias-reduced response; and

amplifying the bias-reduced response prior to correlating the measured noise stimulus and the bias-reduced response.

20. The method of claim 14, further comprising:

filtering the measured noise stimulus prior to correlating the measured noise stimulus and the bias-reduced response; and

filtering the bias-reduced response prior to correlating the measured noise stimulus and the bias-reduced response.

21. The method of claim 14, further comprising:

periodically sampling the random noise stimulus to generate a time-varying current stimulus;

periodically sampling a voltage response of the energy-output device to the random noise stimulus to generate a time-varying voltage response;

autocorrelating the time-varying current stimulus to generate an autocorrelated stimulus;

autocorrelating the time-varying voltage response to generate an autocorrelated response;

cross-correlating the time-varying current stimulus and the time-varying voltage response to generate a cross-correlated response; and

combining the autocorrelated stimulus, the autocorrelated response, and the cross-correlated response to determine at least one of an impedance amplitude, an impedance phase, and a complex impedance.

22. The method of claim 21, further comprising displaying, on a display, at least one characteristic of interest of the energy-output device.

23. The method of claim 22, wherein the at least one characteristic of interest includes a visual presentation selected from the group consisting of a plot of the time-varying current stimulus, a plot of the time-varying voltage response, a plot of the average voltage signal, a plot of the bias-reduced response, a frequency plot of the impedance amplitude, a frequency plot of the impedance phase, a Nyquist plot of the complex impedance, and combinations thereof.

24. A method of determining an impedance of an energy-output device using a random noise stimulus applied to the energy-output device, the method comprising:

periodically sampling the random noise stimulus to generate a time-varying current stimulus;

periodically sampling a voltage response of the energy-output device to the random noise stimulus to generate a time-varying voltage response;

autocorrelating the time-varying current stimulus to generate an autocorrelated stimulus;

autocorrelating the time-varying voltage response to generate an autocorrelated response;

cross-correlating the time-varying current stimulus and the time-varying voltage response to generate a cross-correlated response; and

combining the autocorrelated stimulus, the autocorrelated response, and the cross-correlated response to determine at least one of an impedance amplitude, an impedance phase, and a complex impedance.

25. The method of claim 24, further comprising:

generating a substantially random digital signal; and

filtering the substantially random digital signal with a bandpass filter to generate the random noise stimulus.

26. The method of claim 25, wherein the filtering comprises a process selected from the group consisting of digital filtering, analog filtering, and a combination thereof.

27. The method of claim 24, further comprising:

amplifying the random noise stimulus prior to periodically sampling; and

amplifying the voltage response prior to periodically sampling.

28. The method of claim 24, further comprising:

filtering the random noise stimulus prior to periodically sampling; and

filtering the voltage response prior to periodically sampling.

29. The method of claim 24, further comprising displaying, on a display, at least one characteristic of interest of the energy-output device.

30. The method of claim 29, wherein the at least one characteristic of interest includes a visual presentation selected from the group consisting of a plot of the time-varying current stimulus, a plot of the time-varying voltage response, a plot of the average voltage signal, a plot of the bias-reduced response, a frequency plot of the impedance amplitude, a frequency plot of the impedance phase, a Nyquist plot of the complex impedance, and combinations thereof.