Process for manufacturing a water-resistant telecommunication cable

• US 7,713,451 B2
• Filed: 10/29/2003
• Issued: 05/11/2010
• Est. Priority Date: 10/29/2003
• Status: Active Grant

• Current Assignee: Prysmian Cavi E Sistemi Italia Srl (Prysmian SPA)
• Original Assignee: Prysmian Cavi E Sistemi Italia Srl (Prysmian SPA)
• Inventors: Testi, Stefano, Pavan, Massimiliano, Donetti, Raffaella, Puppi, Cristiano, Maritano, Mauro
• Primary Examiner(s): Gupta; Yogendra N
• Assistant Examiner(s): LEE, DANIEL H.
• Application Number:
  US10/577,350
• Publication Number:
  US 20070246848A1
• Time in Patent Office: 2,386 Days
• Field of Search: 264/211, 264/1.28, 264/1.29, 523/348
• US Class Current: 264/1.28
• CPC Class Codes: B29C 48/04 Particle-shaped making granules B29B9/00
• CPC Class Codes: B29C 48/07 Flat, e.g. panels
• CPC Class Codes: B29C 48/10 flexible, e.g. blown foils
• CPC Class Codes: B29C 48/29 in liquid form
• CPC Class Codes: B29C 48/297 at several locations, e.g. using several hoppers or using a separate additive feeding
• CPC Class Codes: B29D 11/00673 Supports for light guides
• CPC Class Codes: B29K 2105/0005 containing compounding ingredients releasing, lubricating or separating agents B29C33/56, fibers B29K2105/08, B29K2105/12; fillers B29K2105/16, recycled material B29K2105/26
• CPC Class Codes: C08J 2329/04 Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
• CPC Class Codes: C08J 3/18 Plasticising macromolecular compounds plasticisers C08K
• CPC Class Codes: C08K 5/005 Stabilisers against oxidation, heat, light, ozone
• CPC Class Codes: C08K 5/053 Polyhydroxylic alcohols
• CPC Class Codes: C08L 29/04 Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids

Abstract

A process for manufacturing a water-resistant telecommunication cable. The cable has a solid and compact element having a water-soluble polymer material having vinyl alcohol/vinyl acetate copolymer having a hydrolysis degree of 60-95% and a polymerisation degree higher than 1,800 and at least one solid low-melting and one solid high melting plasticizers. The process produces continuously the water-soluble polymer material by separately feeding, in sequence, a multi-screw extruder, in the flow direction, with the copolymer and the high melting plasticizer melting and mixing them while transporting them through the extruder, and with the low melting plasticizer, melting and mixing them with the copolymer and the high melting plasticizer, subsequently homogenizing the copolymer and the plasticizers and finally discharging the melt, at a temperature lower than or equal to 205° C. A process for extruding the above PVA based water-soluble polymer material. The process allows extrusion of PVA with an enhanced productivity and reproducibility requiring shorter times for absorbing the plasticizers onto the polymer.

Claims

1. A process for manufacturing a water-resistant telecommunication cable comprising a solid and compact element housing at least one transmitting element, wherein the solid and compact element comprises a water-soluble polymer material comprising:

a vinyl alcohol/vinyl acetate copolymer having a hydrolysis degree of 60-95% and a polymerisation degree higher than 1,800;

at least a first solid plasticizer, having a melting point of 50-100°

C., and a second solid plasticizer having a melting point equal to or higher than 140°

C., in an amount of 10-30 and 1-10 parts by weight per hundred parts by weight of the copolymer, respectively;

the water-soluble polymer material having;

a complex modulus equal to or higher than 2.5×

10⁶ MPa;

a ratio of the viscous modulus to the elastic modulus equal to or lower than 2.30;

a glass transition temperature of 20-35°

C.;

the process comprising;

continuously producing the water-soluble polymer material by separately feeding in sequence to a multi-screw extruder, in the flow direction, with the copolymer and the second solid plasticizer;

melting and mixing the copolymer and the second solid plasticizer at 170-220°

C.;

melting and mixing the first solid plasticizer with the second solid plasticizer and the copolymer at 140-180°

C.;

subsequently homogenizing the copolymer and the plasticizers at 100-150°

C.; and

discharging the melt, at a temperature lower than or equal to 205°

C.

2. The process according to claim 1, wherein the solid and compact element comprises 30% by weight or more of the water-soluble polymer material.

3. The process according to claim 1, wherein the solid and compact element comprises 50% by weight or more of the water-soluble polymer material.

4. The process according to claim 1, wherein the solid and compact element comprises 75% by weight or more of the water-soluble polymer material.

5. The process according to claim 1, wherein the solid and compact element is a structural element of the cable.

6. The process according to claim 1, wherein the solid and compact element is a tubular element comprising at least one sheath comprising the water-soluble polymer material.

7. The process according to claim 6, wherein the tubular element is a single sheath substantially made of the water-soluble polymer material.

8. The process according to claim 6, wherein the tubular element is a double layer sheath, the inner layer being made of the water-soluble polymer material and the outer layer being made of a water-insoluble polymer material.

9. The process according to claim 6, wherein the tubular element is a three-layer sheath, the inner and the outer layers being made of the water-soluble polymer material and the intermediate layer being made of a water-insoluble polymer material.

10. The process according to claim 1, wherein the solid and compact element is a buffer tube and the transmitting element is an optical fibre.

11. The process according to claim 1, wherein the copolymer is 50-95% of the total weight of the water-soluble polymer material.

12. The process according to claim 1, wherein the copolymer is 60-85% of the total weight of the water-soluble polymer material.

13. The process according to claim 1, wherein the copolymer has a hydrolysis degree of 70-92% and a polymerisation degree of 2,500-3,700.

14. The process according to claim 13, wherein the copolymer has a polymerisation degree of 3,000-3,500.

15. The process according to claim 1, wherein the first and the second plasticizers comprise 12-25 and 3-7 parts by weight per hundred parts by weight of the copolymer, respectively.

16. The process according to claim 1, wherein the first and second plasticizers are polyhydric alcohols.

17. The process according to claim 1, wherein the first plasticizer is selected from sorbitol, trimethylolpropane, di-trimethyloipropane, methylpropyl propanediol, and mixtures thereof, and the second plasticizer is selected from mannitol, pentaerythritol, dipentaerythritol, trimethylolethane, and mixtures thereof.

18. The process according to claim 1, wherein the first plasticizer is trimethyloipropane or ditrimethylolpropane and the second plasticizer is pentaerythritol or dipentaerythritol.

19. The process according to claim 1, wherein the first and the second plasticizers comprise 20 and 5 parts by weight per hundred parts by weight of said copolymer, respectively.

20. The process according to claim 1, wherein the water-soluble polymer material comprises a third plasticizer, liquid at room temperature, in an amount of 0.5-10 parts by weight per hundred parts by weight of the copolymer, the third plasticizer being fed, after the copolymer and the second plasticizer, at 170-220°

C.

21. The process according to claim 20, wherein the third plasticizer is a polyhydric alcohol.

22. The process according to claim 20, wherein the third plasticizer is selected from glycerol, ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol, trimethylolpropane ethoxylates, pentaerythritol exthoxylates, and mixtures thereof.

23. The process according to claim 20, wherein the third plasticizer comprises 2-7 parts by weight per hundred parts by weight of said copolymer.

24. The process according to claim 20, wherein the third plasticizer comprises 5 parts by weight per hundred parts by weight of said copolymer.

25. The process according to claim 20, wherein the third plasticizer is diethylene glycol or triethylene glycol.

26. The process according to claim 20, wherein the third plasticizer is fed before the first solid plasticizer.

27. The process according to claim 1, wherein the complex modulus is 3.0×

10⁶ to 4.0×

10⁶ MPa.

28. The process according to claim 1, wherein the ratio of the viscous modulus to the elastic modulus is 0.5 to 2.0.

29. The process according to claim 1, wherein the glass transition temperature is 25°

C. to 30°

C.

30. The process according to claim 1, wherein the melting and mixing of the copolymer and the second solid plasticizer are carried out at 180-210°

C.

31. The process according to claim 1, wherein the melting and mixing of the first plasticizer with the copolymer and the second solid plasticizer are carried out at 150-170°

C.

32. The process according to claim 1, wherein the homogenization of the copolymer with the plasticizers is carried out at 110-140°

C.

33. The process according to claim 1, wherein the discharging of the melt is carried out at a temperature lower than or equal to 195°

C.

34. The process according to claim 1, wherein the water-soluble polymer material comprises a hydrolysis stabilizer compound comprising a chelant group comprising two hydrogen atoms bonded to two respective heteroatoms selected from nitrogen, oxygen and sulphur, said two hydrogen atoms having a distance between each of 4.2×

10<sup>−

10</sup> m to 5.8×

10<sup>−

10</sup> m, said stabilizer compound being present in an amount of at least 0.75 mmoles per 100 g of the copolymer.

35. The process according to claim 34, wherein the stabilizer is fed together with the copolymer and the second solid plasticizer.

36. The process according to claim 34, wherein the stabilizer is N,N′

-hexane-1,6-diylbis (3-(3,5-di-tert-butyl-4-hydroxyphenylpropionamide)).

37. The process according to claim 1, wherein the multi-screw extruder is a self-cleaning co-rotating fully intermeshing twin screw extruder, a Buss kneader, a Ring extruder RE®

or a Farrell FCM®

extruder.

38. The process according to claim 1, wherein the multi-screw extruder provides an energy input of 0.15-0.50 kWh/kg to the water-soluble polymer material.

39. The process according to claim 1, wherein the multi-screw extruder provides an energy input of 0.30-0.40 kWh/kg to the water-soluble polymer material.

40. The process according to claim 1, wherein the multi-screw extruder has a multi-zone thermally controlled barrel.

41. The process according to claim 1, wherein the multi-screw extruder comprises a thermal control apparatus.

42. The process according to claim 41, wherein the thermal control apparatus comprises an electrical system for heating and a water system for cooling.

43. The process according to claim 1, wherein a pressure build-up system followed by a die head are provided at the end of the multi-screw extruder.

44. The process according to claim 43, wherein the pressure build-up system is a tight pitch conveying section in the multi-screw extruder, a gear pump or a single screw extruder flanged or in cascade to the multi-screw extruder.

45. The process according to claim 43, wherein a cutting device is provided after the die head.

46. The process according to claim 45, wherein the cutting device is a dry air cutting system or a strand pelletizing system with fast centrifuge water separation.

47. A process for extruding a water-soluble polymer material comprising:

a vinyl alcohol/vinyl acetate copolymer having a hydrolysis degree of 60-95% and a polymerisation degree higher than 1,800;

at least a first solid plasticizer, having a melting point of 50-110°

C, and a second solid plasticizer, having a melting point equal to or higher than 140°

C., in an amount of 10-30 and 1-10 parts by weight per hundred parts by weight of the copolymer, respectively;

the water-soluble polymer material having;

a complex modulus equal to or higher than 2.5×

10⁶ MPa;

a ratio of the viscous modulus to the elastic modulus equal to or lower than 2.30;

a glass transition temperature of 20-35°

C.;

the process comprising

continuously producing the water-soluble polymer material by separately feeding in sequence a multi-screw extruder, in the flow direction, with the copolymer and the second solid plasticizer;

melting and mixing the copolymer and second solid plasticizer at 170-220°

C.;

melting and mixing the first solid plasticizer with the second solid plasticizer and the copolymer at 140-180°

C.;

subsequently homogenizing the copolymer and the plasticizers at 100-150°

C.; and

discharging the melt at a temperature lower than or equal to 205°

C.

48. The process according to claim 47, wherein the water-soluble polymer material comprises a third plasticizer, liquid at room temperature, in an amount of 0.5-10 parts by weight per hundred parts by weight of the copolymer, the third plasticizer being fed, after the copolymer and the second plasticizer, at 170-220°

C.

49. The process according to claim 47, wherein the water-soluble polymer material comprises a hydrolysis stabilizer compound comprising a chelant group comprising two hydrogen atoms bonded to two respective heteroatoms selected from nitrogen, oxygen and sulphur, said two hydrogen atoms having a distance between each other of 4.2×

10<sup>−

10</sup> m to 5.8×

10<sup>−

10</sup> m, said stabilizer compound being present in an amount of at least 0.75 mmoles per 100 g of the copolymer.