Binder of vegetable nature for the production of materials for building and/or civil engineering

• US 7,758,686 B2
• Filed: 09/25/2007
• Issued: 07/20/2010
• Est. Priority Date: 04/08/2003
• Status: Expired due to Fees

• Current Assignee: Colas SA (Bouygues SA)
• Original Assignee: Colas SA (Bouygues SA)
• Inventors: Delcroix, Thierry, Poirier, Jean-Eric, Ballie, Michel
• Primary Examiner(s): Brunsman; David M
• Application Number:
  US11/860,773
• Publication Number:
  US 20080006178A1
• Time in Patent Office: 1,029 Days
• Field of Search: 106/220, 106/222, 106/228
• US Class Current: 106/220
• CPC Class Codes: C04B 14/06 Quartz; Sand
• CPC Class Codes: C04B 2111/0075 for road construction
• CPC Class Codes: C04B 24/10 Carbohydrates or derivatives thereof
• CPC Class Codes: C04B 24/34 Natural resins, e.g. rosin C04B24/243 takes precedence
• CPC Class Codes: C04B 26/003 Oil-based binders, e.g. containing linseed oil
• CPC Class Codes: C04B 26/22 Natural resins, e.g. rosin
• CPC Class Codes: E01C 7/30 of road-metal and other binders, e.g. synthetic material , i.e. resin

Abstract

A binder for the production of a layer for road works or civil engineering comprises, with respect to the total weight of the binder:

• • (a) 2 to 98% in weight of at least one purely natural or modified natural resin, of vegetable origin, having a softening point measured of 30 to 200° C.;
  • (b) 98 to 2% in weight of at least one oil of vegetable origin having a viscosity at 25° C. of 50 mPa·s to 1000 Pa·s,
  • (c) the binder having:
    • (c1) either a penetrability at 25° C., of 20 to 300 1/10 mm and a softening point of 30 to 75° C.,
    • (c2) or a penetrability at 15° C., of 300 to 900 and a viscosity at 60° C., and
  • (d) the binder being exempt of any natural or synthetic elastomer and of any thermoplastic polymer.

Claims

1. A material for the production of building layers and/or coatings comprising a mixture of an aggregate and a binder,

wherein the binder comprises, based on the total weight of (a) and (b):

(a) 60 to 80% in weight of at least one purely natural or modified natural resin, of vegetable origin, having a softening point measured according to the standard EN 1427 of 100 to 200°

C.;

(b) 20 to 40% in weight of at least one oil of vegetable origin having a viscosity at 25°

C. of 50 mPa·

s to 1000 Pa·

s;

(c) said binder having a penetrability at 25°

C., measured according to the standard NF EN 1426, of 20 to 300 1/10 mm and a softening point of 30 to 75°

C., measured according to the standard NF EN 1427; and

said binder being exempt of any natural or synthetic elastomer and of any thermoplastic polymer, said aggregates being selected from the group consisting of fines, sand, gravel and combinations thereof.

2. The material according to claim 1, wherein the resin has a softening point measured according to the standard EN 1427 of 120 to 180°

C.

3. The material according to claim 1, wherein the purely natural or modified natural resin of vegetable origin is a harvest resin.

4. The material according to claim 3, wherein the resin is selected among the accroï

d resins, the dammar, the purely natural or modified natural rosins, the rosin esters, the rosin soaps and the metal resinates.

5. The material according to claim 4, wherein the rosin esters are polymerised rosin esters and glycerol and/or maleated rosin esters and glycerol and the resinates are calcium resinates.

6. The material according to claim 1, wherein the purely natural or modified natural resin of vegetable origin is a fossil resin.

7. The material according to claim 6, wherein the resin is selected among the copals.

8. The material according to claim 1, wherein the vegetable oil is selected among the oils made of colza, of sunflower, of soja bean, of flax, of olive, of palm, of ricin, of wood, of maize, of gourd, of grape pips, of jojoba, of sesame, of nut, of hazel, of almond, of shea, of macadamia, of cotton, of lucerne, of rye, of cartham, of groundnut and of copra, and their mixtures.

9. The material according to claim 1, wherein the binder comprises, besides, at least one catalyst for polymerizing vegetable oil(s).

10. The material according to claim 9, wherein the catalyst is selected among the cobalt, zirconium and manganese salts.

11. The material according to claim 10, wherein the salt is an octanoate or a naphtenate.

12. The material according to claim 1, wherein the material is a coated material.

13. The material according to claim 1, wherein the binder accounts for 3% to 10% of the total weight of the material.

14. The material according to claim 1, wherein the material is a superficial plaster.

15. A building layer or coating, wherein said building layer is composed of a material according to claim 1.

16. The building layer or coating according to claim 15, wherein said building layer makes up a layer or coating for road works or civil engineering.