UV-cross-linked membranes from polymers of intrinsic microporosity for liquid separations
First Claim
1. A process for separating at least one liquid from a mixture of liquids, the process comprising:
- a) providing a membrane comprising a microporous material comprising organic macromolecules comprised of a generally planar species connected by rigid linkers having a point of contortion such that two adjacent of said generally planar species connected by said rigid linkers are held in non-coplanar orientation wherein said organic macromolecules have further been cross-linked by exposure to ultraviolet radiation;
b) contacting the mixture of liquids, wherein said mixture of liquids comprises sulfur containing compounds and naphtha hydrocarbons, on one side of the membrane to cause said at least one liquid to permeate the membrane; and
c) removing from the opposite side of the membrane a permeate liquid composition comprising a portion of said at least one liquid which permeated said membrane.
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Abstract
The present invention is for high performance UV-cross-linked membranes from polymers of intrinsic microporosity (PIMs) and the use of such membranes for separations. More specifically, the invention involves the methods of making UV-cross-linked membranes from PIMs. These membranes were prepared by cross-linking the UV-cross-linkable membranes from PIMs by exposure to UV-radiation. Pure gas permeation test results demonstrate that the UV-cross-linked membranes from PIMs exhibit CO2/CH4 performance well above the Robeson'"'"'s polymer upper bound trade-off curve for CO2/CH4 separation. They have more than doubled selectivity for CO2/CH4 and extremely high permeability of CO2 compared to the original UV-cross-linkable membranes from PIMs. These membranes also show excellent separation performance for CO2/N2, H2/CH4, O2/N2, and propylene/propane separations. These high performance UV-cross-linked membranes are very useful for gas and liquid separations such as CO2/CH4, CO2/N2, H2/CH4, O2/N2, olefin/paraffin, deep desulfurization of gasoline and diesel fuels, and ethanol/water separations.
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10 Claims
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1. A process for separating at least one liquid from a mixture of liquids, the process comprising:
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a) providing a membrane comprising a microporous material comprising organic macromolecules comprised of a generally planar species connected by rigid linkers having a point of contortion such that two adjacent of said generally planar species connected by said rigid linkers are held in non-coplanar orientation wherein said organic macromolecules have further been cross-linked by exposure to ultraviolet radiation; b) contacting the mixture of liquids, wherein said mixture of liquids comprises sulfur containing compounds and naphtha hydrocarbons, on one side of the membrane to cause said at least one liquid to permeate the membrane; and c) removing from the opposite side of the membrane a permeate liquid composition comprising a portion of said at least one liquid which permeated said membrane. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10)
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Specification