Energy conversion film and quantum dot film comprising quantum dot compound, energy conversion layer including the quantum dot film, and solar cell including the energy conversion layer

• US 7,791,157 B2
• Filed: 02/03/2006
• Issued: 09/07/2010
• Est. Priority Date: 02/03/2005
• Status: Active Grant

• Current Assignee: Samsung Electronics Co. Ltd.
• Original Assignee: Samsung Electronics Co. Ltd.
• Inventors: Cho, Kyung-sang, Kim, Byung-ki
• Primary Examiner(s): Wilson; Allan R.
• Application Number:
  US11/347,681
• Publication Number:
  US 20060169971A1
• Time in Patent Office: 1,677 Days
• Field of Search: 257/14, 257/103, 257/436, 257/451, 257/E31.119, 977/950, 977/954
• US Class Current: 257/436
• CPC Class Codes: B82Y 10/00 Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
• CPC Class Codes: H01G 9/2027 comprising an oxide semiconductor electrode
• CPC Class Codes: H01G 9/2031 comprising titanium oxide, e.g. TiO2 H01G9/2036 takes precedence
• CPC Class Codes: H01G 9/209 Light trapping arrangements
• CPC Class Codes: H01L 31/0352 characterised by their shape or by the shapes, relative sizes or disposition of the semiconductor regions
• CPC Class Codes: H01L 31/0384 including other non-monocrystalline materials, e.g. semiconductor particles embedded in an insulating material H01L31/0392 takes precedence
• CPC Class Codes: H01L 31/055 where light is absorbed and re-emitted at a different wavelength by the optical element directly associated or integrated with the PV cell, e.g. by using luminescent material, fluorescent concentrators or up-conversion arrangements
• CPC Class Codes: Y02E 10/52 PV systems with concentrators
• CPC Class Codes: Y02E 10/542 Dye sensitized solar cells
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

An energy conversion film and a quantum dot film which contain a quantum dot compound, an energy conversion layer including the quantum dot film, and a solar cell including the energy conversion layer. The films act as cut-off filters blocking light of a particular energy level using the light absorption and emission effects of quantum dots and can convert high energy light to low energy light. The efficiency of a solar cell may be improved by providing the cell with a film that converts light above the spectrum-responsive region to light in the cell'"'"'s spectrum-responsive region. The absorption wavelength region of the films can be broadened by providing the quantum dot compound in a variety of average particle sizes, for example, by providing a mixture of a first quantum dot compound having a first average particle size and a first quantum dot compound having a second average particle size.

Claims

1. A solar cell comprising a conductive substrate, an energy conversion layer comprising a quantum dot compound and formed on at least one side of the substrate,

a light absorption layer, and

a counter electrode,

wherein the thickness of the energy conversion layer is about 20 nm to about 10 μ

m, and the solar cell is configured to generate an electric current upon absorbing light.

2. The solar cell of claim 1 wherein the quantum dot compound has a core-shell structure or an inverse core-shell structure.

3. The energy conversion film solar cell of claim 1 wherein the energy conversion layer comprises multiple layers formed on at least one surface of a substrate.

4. The solar cell of claim 1, wherein the energy conversion layer absorbs light and converts the absorbed light to a lower energy light, and the light absorption layer is excited by absorbing the lower energy light.

5. The solar cell of claim 1, wherein the quantum dot compound is a substance selected from the group consisting of a) a combination of a first element selected from Group 2, 12, 13 and 14 of the Periodic Table of Elements and a second element selected from Group 16;

b) a combination of a first element selected from Group 13 and a second element selected from Group 15;

c) an element selected from Group 14;

or (d a composite comprising one or more of the forgoing compounds having core-shell structures.

6. The solar cell of claim 1, wherein the quantum dot compound is MgO, MgS, MgSe, MgTe, CaO, CaS, CaSe, CaTe, SrO, SrS, SrSe, SrTe, BaO, BaS, BaSe, BaTe, ZnO, ZnS, ZnSe, ZnTe, CdO, CdS, CdSe, CdTe, HgO, HgS, HgSe, HgTe, Al₂O₃, Al₂S₃, Al₂Se₃, Al₂Te₃, Ga₂O₃, Ga₂S₃, Ga₂Se₃, Ga₂Te₃, In₂O₃, In₂S₃, In₂Se₃, In₂Te₃, SiO₂, GeO₂, SnO₂, SnS, SnSe, SnTe, PbO, PbO₂, PbS, PbSe, PbTe, AN, AlP, AlAs, AlSb, GaN, GaP, GaAs, GaSb, InN, InP, InAs, InSb, BP, Si and Ge, or a composite comprising one or more of the forgoing materials having core-shell structures.

7. The solar cell of claim 6, wherein the quantum dot compound is CdSe, CdTe, CdS, ZnSe, ZnS, InP, InAs, GaN, GaP, GaAs, HgTe, Si, Ge, CdS/ZnSe, CdS/ZnS, CdSe/ZnS, CdSe/CdS, CdSe/ZnSe, CdTe/ZnS, CdTe/CdSe, or CdSe/ZnTe, or a combination comprising one or more of the foregoing components.

8. The solar cell of claim 1, wherein the energy conversion layer comprises an energy converting film having a Stokes shift value between absorption energy and emission energy of about 20 nm or greater.

9. The solar cell of claim 1, wherein the quantum dot compound is mixed or embedded in a matrix of an inorganic substance or a polymer resin.

10. The solar cell of claim 1, wherein an average diameter of the quantum dot is about 1.0 nm to about 10 nm.

11. The solar cell of claim 1, wherein the light absorption layer does not comprise a quantum dot compound.

12. The solar cell of claim 1, wherein the light absorption layer comprises a metal oxide and a dye.

13. The solar cell of claim 1, wherien further comprising an electrolyte.