Adsorber for pretreatment of natural gas containing bulk hydrogen sulfide

• US 7,803,215 B2
• Filed: 12/12/2007
• Issued: 09/28/2010
• Est. Priority Date: 12/12/2007
• Status: Expired due to Fees

• Current Assignee: UOP Llc (Honeywell International Inc.)
• Original Assignee: UOP Llc (Honeywell International Inc.)
• Inventors: Cartwright, Gordon T., Russell, Bradley P., Schott, Mark E.
• Primary Examiner(s): LAWRENCE JR, FRANK M
• Application Number:
  US11/954,437
• Publication Number:
  US 20090151562A1
• Time in Patent Office: 1,021 Days
• Field of Search: 96/4, 961/08, 961/21, 96132-135, 961/43, 961/44, 962/43, 95/43, 951/17, 951/36, 951/43, 952/35, 423/220, 423/228, 423/229, 208/208.R, 208/310.R, 585/820, 585/822
• US Class Current: 95/136
• CPC Class Codes: B01D 2253/102 Carbon
• CPC Class Codes: B01D 2253/106 Silica or silicates
• CPC Class Codes: B01D 2258/06 Polluted air
• CPC Class Codes: B01D 2259/4009 using hot gas
• CPC Class Codes: B01D 2259/4145 arranged in series
• CPC Class Codes: B01D 53/02 by adsorption, e.g. preparative gas chromatography solid sorbent compositions B01J20/00, preparation of inorganic compounds or elements C01
• CPC Class Codes: C10L 3/10 Working-up natural gas or synthetic natural gas
• CPC Class Codes: C10L 3/102 of acid contaminants
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

The invention relates to a process for removing heavy hydrocarbons and hydrogen sulfide from natural gas. The combination of a silica-gel and an activated carbon adsorber allow for a significant reduction in the overall bed volume required for removal of hydrocarbons.

Claims

1. A process for pretreatment of a natural gas stream containing methane, higher hydrocarbons, 10-40 mole % hydrogen sulfide and carbon dioxide wherein said process comprises passing said natural gas stream through at least one layer of a silica gel adsorbent and then through at least one layer of an activated carbon adsorbent under controlled conditions at which the adsorption capacity of the activated carbon adsorbent for the higher hydrocarbons exceeds that of the silica gel adsorbent.

2. The process of claim 1 wherein said at least one layer of a silica gel adsorbent and said at least one layer of an activated carbon adsorbent are contained within a single adsorbent bed.

3. The process of claim 1 wherein said at least one layer of a silica gel adsorbent and said at least one layer of an activated carbon adsorbent are contained within separate adsorbent beds.

4. The process of claim 1 wherein said silica gel adsorbent and said activated carbon adsorbent are regenerated by first passing a hot regeneration gas through said activated carbon layer and then through said silica gel layer.

5. The process of claim 1 wherein said silica gel adsorbent and said activated carbon adsorbent are present in a ratio of between about 80/20 to about 20/80 by volume.

6. The process of claim 1 wherein said activated carbon adsorbent removes at least 50% of said higher hydrocarbons.

7. The process of claim 1 wherein after said pretreatment of said natural gas stream, a purified natural gas stream is sent to a treatment zone comprising a membrane unit.

8. The process of claim 1 wherein after said pretreatment of said natural gas stream, a purified natural gas stream is sent to a treatment zone comprising an amine containing solvent.

9. The process of claim 2 wherein said adsorbent bed has at least a 25% greater capacity for removal of higher hydrocarbons than an adsorbent bed of an identical volume that consists of silica gel.

10. The process of claim 2 wherein said adsorbent bed is in a thermal swing adsorption unit.

11. A natural gas pretreatment process, comprising:

selecting a natural gas stream containing higher hydrocarbons and having 10-40 mole % hydrogen sulfide; and

passing the selected natural gas stream through at least one layer of silica gel adsorbent and through at least one layer of an activated carbon adsorbent at a feed pressure exceeding approximately 25 bar to promote co-adsorption of hydrogen sulfide on the silica gel adsorbent while suppressing higher hydrocarbon loadings thereon.

12. The process of claim 11 wherein said at least one layer of a silica gel adsorbent and said at least one layer of an activated carbon adsorbent are contained within a single adsorbent bed.

13. The process of claim 11 wherein said at least one layer of a silica gel adsorbent and said at least one layer of an activated carbon adsorbent are contained within separate adsorbent beds.

14. The process of claim 11 wherein said silica gel adsorbent and said activated carbon adsorbent are regenerated by first passing a hot regeneration gas through said activated carbon layer and then through said silica gel layer.

15. The process of claim 11 wherein said silica gel adsorbent and said activated carbon adsorbent are present in a ratio of between about 80/20 to about 20/80 by volume.

16. The process of claim 11 wherein said activated carbon adsorbent removes at least 50% of said higher hydrocarbons.

17. The process of claim 11 wherein after said pretreatment of said natural gas stream, a purified natural gas stream is sent to a treatment zone comprising a membrane unit.

18. The process of claim 11 wherein after said pretreatment of said natural gas stream, a purified natural gas stream is sent to a treatment zone comprising an amine containing solvent.

19. The process of claim 12 wherein said adsorbent bed has at least a 25% greater capacity for removal of higher hydrocarbons than an adsorbent bed of an identical volume that consists of silica gel.

20. The process of claim 12 wherein said adsorbent bed is in a thermal swing adsorption unit.