Catalytic microcombustors for compact power or heat generation

• US 7,862,331 B2
• Filed: 06/12/2006
• Issued: 01/04/2011
• Est. Priority Date: 06/17/2005
• Status: Expired due to Fees

• Current Assignee: University of Delaware
• Original Assignee: University of Delaware
• Inventors: Vlachos, Dionisios G., Wetzel, Eric Dean, Norton, Daniel G.
• Primary Examiner(s): Rinehart; Kenneth B
• Assistant Examiner(s): NDUBIZU, CHUKA CLEMENT
• Application Number:
  US11/451,113
• Publication Number:
  US 20070082310A1
• Time in Patent Office: 1,667 Days
• Field of Search: 431/268, 431/354, 431/7, 422/240, 126/208, 136/205
• US Class Current: 431/268
• CPC Class Codes: F23C 13/02 characterised by arrangements for starting the operation, e.g. for heating the catalytic material to operating temperature
• CPC Class Codes: F23C 13/08 characterised by the catalytic material
• CPC Class Codes: F23C 2900/03001 Miniaturized combustion devices using fluid fuels
• CPC Class Codes: H01M 14/00 Electrochemical current or voltage generators not provided for in groups H01M6/00 - H01M12/00; Manufacture thereof
• CPC Class Codes: H01M 16/003 of fuel cells with other electrochemical devices, e.g. capacitors, electrolysers
• CPC Class Codes: H01M 2250/407 Combination of fuel cells with mechanical energy generators
• CPC Class Codes: H01M 8/0606 with means for production of gaseous reactants
• CPC Class Codes: H10N 10/13 characterised by the heat-exchanging means at the junction
• CPC Class Codes: Y02E 60/50 Fuel cells
• CPC Class Codes: Y02T 10/12 Improving ICE efficiencies

Abstract

The present invention comprises a device which utilizes catalytic microcombustion for the production of heat or power and which exhibits a low pressure drop and has a high catalytic surface area. The catalytic microcombustor includes catalyst inserts in the reaction chamber separated by a sub millimeter distance. Thermal spreaders ensure temperature uniformity and maximum thermal efficiency. A mixing zone is prior to the combustion zone. Thermally conductive and/or insulating inserts are in the vicinity of the reaction zone.

Claims

1. A device for producing heat or power comprising:

a catalytic microcombustor having a reaction chamber formed by one or more walls that define a channel as a catalytic zone;

a fuel inlet tube communicating with said chamber at a first location;

an exit tube communicating with said chamber at a second location remote from said first location;

at least two thermal spreaders conductively mounted to the one or more walls of the reaction chamber external to said chamber said thermal spreaders adapted to increase thermal uniformity in said reaction chamber as compared to an identical said reaction chamber without said thermal spreaders; and

two spaced catalytic inserts disposed on the one or more walls of said reaction chamber with said channel between them, each of said catalytic inserts comprising a catalyst.

2. The device of claim 1, further comprising a mixing zone prior to the reaction chamber for mixing of reactants.

3. The device of claim 2, wherein said mixing zone comprises a static mixer.

4. The device of claim 1, wherein each catalytic insert comprises a nanoporous substrate for supporting the catalyst.

5. The device of claim 1, wherein said microcombustor has no movable parts in operation.

6. The device of claim 1, further comprising at least a first thermoelectric element coupled to said microcombustor.

7. The device of claim 6, further comprising at least a first heat sink mounted externally to said first thermoelectric element.

8. The device of claim 6, further comprising a second thermoelectric element and a second heat sink diametrically opposite said first thermoelectric element and heat sink.

9. The device of claim 1 wherein the two catalytic inserts have a gap between them greater than 1 μ

m and less than 5 mm.

10. The device of claim 9 wherein the gap between said catalytic inserts is greater than 100 μ

m and less than 1 mm.

11. The device of claim 1, comprising two said thermal spreaders conductively mounted to the walls of the reaction chamber.

12. The device of claim 1, wherein said thermal spreader has a length coextensive with the reaction chamber.

13. The device of claim 1, wherein the one or more walls of the reaction chamber comprise a pair of plates, the plates having a channel gap dimension between them, the channel gap dimension defined by a gasket sandwiched between the plates.

14. A device for producing heat or power comprising,

a catalytic microcombustor having a reaction chamber formed by one or more walls that define a channel as a catalytic zone;

a fuel inlet tube communicating with said chamber at a first location;

an exit tube communicating with said chamber at a second location remote from said first location;

at least one thermal spreader conductively connected to the reaction chamber a said thermal spreader adapted to increase thermal uniformity in said reaction chamber as compared to an identical said reaction chamber without said thermal spreader; and

two spaced catalytic inserts disposed on the one, or more walls of said reaction chamber with said channel between them, each of said catalytic inserts comprising a catalyst and having a ratio of catalytic surface area to geometric surface area greater than 100 m²/m².

15. A method of producing heat or power, the method comprising:

(a) providing a catalytic microcombustor having a reaction chamber formed by one or more walls that define a channel as a catalytic zone;

a fuel inlet tube communicating with said chamber at a first location;

an exit tube communicating with said chamber at a second location remote from said first location;

at least two thermal spreaders conductively mounted to the one or more walls of the reaction chamber external to said chamber said thermal spreaders adapted to increase thermal uniformity in said reaction chamber as compared to an identical said reaction chamber without said thermal spreaders; and

two spaced catalytic inserts disposed on the one or more walls of said reaction chamber with said channel between them, each of said catalytic inserts comprising a catalyst; and

(b) feeding a fuel through an inlet tube into the reaction chamber of the catalytic microcombustor.

16. The method of claim 15 further comprising mixing the fuel for the catalytic microcombustor in a mixing zone upstream of the reaction chamber.

17. The method of claim 16, further comprising providing the two catalytic inserts in the reaction chamber with a distance between them of less than 1 millimeter.

18. The method of claim 17, wherein the pressure drop in the microcombustor is less than 100 Pa/m.

19. The method of claim 15, comprising converting heat generated by microcombustion to electricity using a thermoelectric device.

20. The method of claim 19, comprising using the converted electricity to power an object selected from the group consisting of personal electronic devices, sensors, controllers, environmental monitors, remote devices, power harvesting devices, auxiliary power, and vehicles.

21. The method of claim 15, comprising converting heat generated by microcombustion to mechanical work using a thermomechanical device.

22. The method of claim 21, wherein the thermomechanical device is selected from the group consisting of wax actuators, shape memory alloys, and thermally expanding polymers.

23. The method of claim 22, comprising using the mechanical work to generate electricity.

24. The method of claim 15, wherein heat generated by microcombustion is used to convert a fuelstock to hydrogen, which is then used to generate electricity in a fuel cell.

25. The method of claim 15, wherein reactants in the reactant chamber undergo an expansion during combustion that is used to perform mechanical work.

26. The method of claim 15, wherein the catalytic insert comprises a nanoporous substrate for supporting the catalyst.

27. The method of claim 15, wherein the fuel comprises a fuel selected from the group consisting of hydrogen, methane, carbon monoxide, and propane.

28. The method of claim 15, further comprising igniting the fuel in the microcombustor by one of:

self-ignition, an electric spark, a heating element, and using hydrogen during startup when using a non-hydrogen fuel for sustained operation.

29. The method of claim 15, further comprising optimizing a stable combustion temperature by adjusting parameters selected from the group consisting of:

fuel type, equivalence ratio, gap size, flow rate, and wall characteristics, and wherein the wall characteristics are selected from the group consisting of;

thermal conductivity, thickness, porosity, surface geometry, and non-homogeneity.

30. The method of claim 15, further comprising selecting a distance between the two catalytic inserts in the microcombustor to optimize efficiency, pressure drop, fuel conversion, pollutant emissions, thermal uniformity, and flammability limits.

31. The method of claim 15, further comprising selecting wall characteristics of the chamber to optimize efficiency, pressure drop, fuel conversion, pollutant emissions, thermal uniformity, yield in chemical synthesis, microcalorimetric measurements, and flammability limits.

32. The method of claim 15, wherein the generated heat is used for a use selected from the group consisting of warmth for an individual, accelerating a chemical reaction, sustaining a living or biological system, measurement of heat release rate, and as a hydrogen sensor.

33. A device for producing heat or power comprising:

a catalytic microcombustor having a reaction chamber formed by one or more walls that define a channel as a catalytic zone;

a fuel inlet tube communicating with said chamber at a first location;

an exit tube communicating with said chamber at a second location remote from said first location;

a mixing zone prior to the reaction chamber for mixing of reactants;

at least one thermal spreader conductively connected to the reaction chamber said thermal spreader adapted to increase thermal uniformity in said reaction chamber as compared to an identical said reaction chamber without said thermal spreader; and

two spaced catalytic inserts disposed on the one or more walls of said reaction chamber with said channel between them, each of said catalytic inserts comprising a catalyst selected from the group consisting of;

platinum or rhodium.

34. A device for producing heat or power comprising:

a catalytic microcombustor having a reaction chamber formed by one or more walls that define a channel as a catalytic zone;

a fuel inlet tube communicating with said chamber at a first location;

an exit tube communicating with said chamber at a second location remote from said first location;

at least one thermal spreader conductively connected to the reaction chamber said thermal spreader adapted to increase thermal uniformity in said reaction chamber as compared to an identical said reaction chamber without said thermal spreader; and

two spaced catalytic inserts disposed on the one or more walls of said reaction chamber with said channel between them, each of said catalytic inserts comprising a catalyst and an anodized aluminum nanoporous substrate for supporting the catalyst.

35. A device for producing heat or power comprising:

a catalytic microcombustor having a reaction chamber formed by one or more walls that define a channel as a catalytic zone;

a fuel inlet tube communicating with said chamber at a first location;

an exit tube communicating with said chamber at a second location remote from said first location;

two thermal spreaders conductively mounted to the walls of the reaction chamber external to the reaction chamber said thermal spreaders adapted to increase thermal uniformity in said reaction chamber as compared to an identical said reaction chamber without said thermal spreaders; and

two catalytic inserts mounted to the walls of the reaction chamber internal to the reaction chamber, said catalytic inserts comprising a catalyst, with said channel disposed between said catalytic inserts, wherein the two thermal spreaders and the two catalytic inserts all have a same length and width.