Method of molding rigid polyurethane foams with enhanced thermal conductivity

• US 7,943,679 B2
• Filed: 11/03/2006
• Issued: 05/17/2011
• Est. Priority Date: 11/14/2005
• Status: Active Grant

• Current Assignee: Dow Global Technologies LLC (Dow, Inc.)
• Original Assignee: Dow Global Technologies LLC (Dow, Inc.)
• Inventors: Parenti, Vanni, De Vos, Hans A. G.
• Primary Examiner(s): Cooney; John
• Application Number:
  US12/093,083
• Publication Number:
  US 20080255262A1
• Time in Patent Office: 1,656 Days
• Field of Search: 521/130, 521/131, 521/164, 521/167, 521/170, 521/174
• US Class Current: 521/131
• CPC Class Codes: B29C 44/38 into a closed space, i.e. to make articles of definite length B29C44/365 and B29C44/367 take precedence
• CPC Class Codes: C08G 18/482 Mixtures of polyethers containing at least one polyether containing nitrogen
• CPC Class Codes: C08G 18/4829 Polyethers containing at least three hydroxy groups C08G18/4833 - C08G18/5096 take precedence
• CPC Class Codes: C08G 18/7664 containing alkylene polyphenyl groups
• CPC Class Codes: C08G 2110/0025 rigid
• CPC Class Codes: C08G 2110/005 < 50kg/m3
• CPC Class Codes: C08J 2203/12 Organic compounds only containing carbon, hydrogen and oxygen atoms, e.g. ketone or alcohol
• CPC Class Codes: C08J 2203/14 Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
• CPC Class Codes: C08J 2203/142 Halogenated saturated hydrocarbons, e.g. H3C-CF3
• CPC Class Codes: C08J 2205/10 Rigid foams
• CPC Class Codes: C08J 2375/04 Polyurethanes
• CPC Class Codes: C08J 9/14 organic

Abstract

The present invention is to a molded rigid polyurethane foam for application in appliance, having a reduced thermal conductivity at densities between 33 and 38 kg/m³ and a process for the production of such foams. The molded rigid polyurethane foam have a ratio of applied foam density (kg/m3) to lambda (mW/mK), measured at 10° C., 24 hours after foam production from 1.65 and to 2.15 and are obtained by the process of injecting into a closed mold cavity under reduced pressure a reaction mixture at a packing factor of 1.1 to 1.9 and the reaction mixture comprises: A) an organic polyisocyanate; B) a physical blowing agent, C) a polyol composition containing at least one polyol with a functionality of 3 or greater and a hydroxyl number between 200 and 800 and a water content of 0 to 2.5 weight percent of the total polyol composition; D) catalyst and E) auxiliary substances and/or additives.

Claims

1. A process for producing a rigid polyurethane foam having a molded density of 33 to 38 kg/m³ and Lambda_(10°

C.) of less than 21 mW/m.K and a ratio of molded foam density (kg/m³) to Lambda<sub>(10°

C.)</sub> (mW/m.K), measured 24 hours after foam production, from 1.65 to 2.15, obtained by injecting into a closed mold cavity a reaction mixture at a packing factor of 1.03 to 1.9 wherein the mold cavity has a reduced pressure of 300 to 950 mbar and the reaction mixture comprises;

A) an organic polyisocyanate;

B) a physical blowing agent present in an amount from 10 to 30 weight percent of the polyol composition wherein the blowing agent is a hydrocarbon selected from n-pentane, iso-pentane, cyclopentane, n-butane, cyclohexane or a mixture thereof,

C) a polyol composition containing at least one polyol with a functionality of 3 or greater and a hydroxyl number between 300 and 800

D) water present at 0.1 to 2.5 weight percent of the total polyol formulation;

E) catalyst and

F) auxiliary substances and/or additives.

2. The process of claim 1 wherein the mold cavity has an initial pressure of 500 to 850 mbar.

3. The process of claim 1 wherein the packing factor is from 1.1 to 1.6.

4. The process of claim 1 wherein the isocyanate index is 105 to 125.

5. The process of claim 4 wherein the organic polyisocyanate is an aromatic polyisocyanate selected from 4,4′

-, 2,4′

- and 2,2′

-diphenylmethane diisocyanate, polyphenyl-polymethylene polyisocyanates, 2,4- and 2,6-tolylene diisocyanates, or mixtures thereof.

6. The process of claim 5 wherein the organic polyisocyanate is a mixture of diphenylmethane diisocyanate and polyphenyl-polymethylene polyisocyanate wherein the diphenylmethane diisocyanate isomer content is from 30 to 60 percent by weight of the polyisocyanate.

7. The process of claim 1 wherein the produced foam has a lambda of 19 to 20 mW/m.K.

8. The process of claim 1 wherein the demold time is less than 6 minutes.

9. The process of claim 1 wherein the demold time is less than 5 minutes.

10. The process of claim 1 wherein the polyol composition has a viscosity of 1000 mPa.s at 25°

C.

11. The process of claim 1 wherein the polyol composition contains at least one polyol prepared by anionic polyaddition of at least one alkylene oxide onto at least one aromatic initiator molecule containing an amine.

12. process of claim 11 wherein the initiator is selected from aromatic polycarboxylic acids, aromatic hydrocarboxylic acids and aromatic aminocarboxylic acids, aromatic mono- and polyamines, condensates of phenols, formaldehyde and optionally dialkanolamines, or a mixture thereof.

13. The process of claim 11 wherein the initiator molecule is an aromatic polyamine selected from 1,2- 1,3- and 1,4-phenylenediamine, 1,3-, 2,4-, 3,4-and 2,6-tolylenediamines, 4,4′

-, 2,4′

- and 2,2-diaminodiphenylmethane, polypehnyl-polymethylene-polyamines, and mixtures thereof.

14. The foam process of claim 13 wherein the aromatic amine initiated polyol comprises from 10 to 60 wt percent of the polyol composition.