Separation module, method for its production and its use

• US 8,021,619 B2
• Filed: 06/20/2003
• Issued: 09/20/2011
• Est. Priority Date: 06/21/2002
• Status: Expired due to Fees

• Current Assignee: Bayer AG, Hermsdorfer Institut For Technische Keramik E.V.
• Original Assignee: Bayer AG, Hermsdorfer Institut For Technische Keramik E.V.
• Inventors: Stange, Olaf, Fischer, Gundula, Voigt, Ingolf, Stahn, Michael, Nickel, Andreas, Köhler, Birgit
• Primary Examiner(s): Nagpaul; Jyoti
• Application Number:
  US10/600,391
• Publication Number:
  US 20040076874A1
• Time in Patent Office: 3,014 Days
• Field of Search: 422/130, 422 99-101, 422503-504, 429/104, 210/321.8, 210/323.2, 55522-523, 555/27
• US Class Current: 422/130
• CPC Class Codes: B01D 61/362 Pervaporation
• CPC Class Codes: B01D 63/02 Hollow fibre modules
• CPC Class Codes: B01D 63/021 Manufacturing thereof
• CPC Class Codes: B01D 63/022 Encapsulating hollow fibres
• CPC Class Codes: B01D 63/0221 using a mould
• CPC Class Codes: B01D 63/0233 forming the bundle
• CPC Class Codes: B01D 63/031 Two or more types of hollow fibres within one bundle or within one potting or tube-sheet
• CPC Class Codes: B01D 63/06 Tubular membrane modules
• CPC Class Codes: B01D 63/061 Manufacturing thereof
• CPC Class Codes: B01D 63/062 with membranes on a surface of a support tube
• CPC Class Codes: B01D 69/141 Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
• CPC Class Codes: B01D 71/02 Inorganic material

Abstract

A separation module which contains at least one bundle of ceramic capillaries (9), in which, for controlling the material transport and the flow in the separation module, a certain distance is established between the capillaries (9) by joining. The separation module can be used in a variety of ways in the separation of substances by filtration, also in combination with further measures of chemical process engineering.

Claims

1. A separation module comprising at least one bundle comprising a plurality of sintered porous ceramic capillaries arranged in parallel and joined together by staggered ceramic film strips pressed at least partially around and connecting adjacent sintered porous ceramic capillaries, the plurality of sintered porous ceramic capillaries and said staggered ceramic film strips being wound into said at least one bundle, the said staggered ceramic film strips when wound into said at least one bundle functioning as baffle plates, each of said sintered porous ceramic capillaries in the bundle having an external diameter ranging from 0.3 mm to 10 mm and an internal diameter ranging from 0.1 mm to 8 mm, each of said sintered porous ceramic capillaries in the bundle being spaced apart from an adjacent sintered porous ceramic capillary in the bundle by a defined distance established by said staggered ceramic film strips, and an end of each of said sintered porous ceramic capillaries passing through a perforated ceramic disc at a defined distance from an end of an adjacent sintered porous ceramic capillary also passing through said perforated ceramic disc.

2. The separation module of claim 1, wherein said end plate is shrunk-fit to said capillaries.

3. Separation module according to claim 1, wherein the end plate is a perforated plate and the module further comprises a housing, which housing encloses the bundle, the housing having an inlet and/or outlet pipe in fluid communication with the inside of the sintered porous ceramic capillaries for a first material flow and/or an outlet pipe in fluid communication with the innerspace between the sintered porous ceramic capillaries for a second material flow, wherein the distance between the sintered porous ceramic capillaries is further kept constant by spacers.

4. Separation module according to claim 1, wherein said external diameter ranges from 1 mm to 2.5 mm and said internal diameter ranges from 0.7 to 1.5 mm.

5. Separation module according to claim 1, wherein the distance between sintered porous ceramic capillaries in the bundle is 0.05-10 mm.

6. Separation module according to claim 5, wherein said distance is <

3 mm.

7. Separation module according to claim 1, wherein the distance between the sintered porous ceramic capillaries in the bundle is established by said staggered ceramic film strips as a function of the permeate flow and permeate medium.

8. Separation module according claim 1, wherein the bundles of capillaries have a diameter of from 10 mm to 250 mm.

9. Separation module according to claim 8, wherein said diameter is from 20 mm to 50 mm.

10. Separation module according to claim 1, wherein the sintered porous ceramic capillaries have, on the inside, a thin membrane having separation activity.

11. Separation module according to claim 1, wherein the sintered porous ceramic capillaries have, on the outside, a thin membrane having separation activity.

12. Separation module according to claim 1, wherein several bundles of sintered porous ceramic capillaries are arranged parallel to each other in a housing and the separation module further comprises a feed space and a permeation space.

13. Separation module according to claim 12, wherein the housing comprises stainless steel and the feed space and permeation space is sealed by an elastomer O-ring, a graphite seal or a sealing compound.

14. Separation module according to claim 12, wherein the housing comprises ceramic and the feed space and permeation space is sealed at joints by ceramic- or glass-containing slip, paste or adhesive.

15. A membrane reactor comprising the separation module of claim 1, wherein the individual sintered porous ceramic capillaries are coated with a catalyst or are themselves a catalyst or the catalyst is otherwise present in the module.

16. A membrane separation process, wherein a fluid to be separated is passed through a separation module of claim 1, having a feed space and a permeation space, and wherein a vacuum is applied to the permeation space.

17. A method of producing a separation module according to claim 1, said method comprising:

(a) providing a plurality of sintered porous ceramic capillaries arranged in parallel, (b) joining the sintered porous ceramic capillaries together by pressing staggered ceramic film strips at least partially around adjacent sintered porous ceramic capillaries to connect them, each of said sintered porous ceramic capillaries thereby being spaced apart from an adjacent sintered porous ceramic capillary by a defined distance established by said staggered ceramic film strips, (c) winding the plurality of sintered porous ceramic capillaries and staggered ceramic film strips into said at least one bundle and (d) passing an end of each of said sintered porous ceramic capillaries through an perforated ceramic disc at a defined distance from an end of an adjacent capillary also passing through said perforated ceramic disc.

18. Method according to claim 17, which further comprises placing sintered porous ceramic capillaries in holes at the bottom of a mold, filling this mold with a polymer-, ceramic- and/or glass-containing casting compound and, after demolding, cutting off the projecting ends of the capillaries.

19. Method according to claim 17, which further comprises inserting sintered porous ceramic capillaries into perforated discs and sealing the joints between the two with the use of polymer-, ceramic- or glass-containing slips, pastes or adhesives.

20. Method according to claim 17, which further comprises inserting sintered porous ceramic capillaries into unsintered ceramic perforated discs and firmly connecting by shrinkage of the perforated disc.

21. Method according to claim 17, which further comprises inserting unsintered porous ceramic capillaries into unsintered ceramic perforated discs and firmly connecting by co-firing.

22. Method according to claim 17, which further comprises winding sintered porous ceramic capillaries with at least one strip of polymer-, ceramic- and/or glass-containing film, braid or woven fabric and firmly connecting by shrinkage during curing of the film.

23. Method according to claim 17, which further comprises winding unsintered porous ceramic capillaries with at least one strip of ceramic- and/or glass-containing film, braid or woven fabric and firmly connecting by co-firing.

24. Method according to claim 17, which further comprises coating the sintered porous ceramic capillaries on their inside or outside walls with a membrane having separation activity and, in the case of a completely ceramic capillary bundle, coating with the membrane having separation activity after completion of the capillary bundle in one step.

25. Method according to claim 17, which further comprises coating the sintered porous ceramic capillaries on their inside or outside walls with a membrane having separation activity, wherein a nonceramic component is present in the capillary bundle, and the capillaries are coated with the membrane having separation activity prior to installation in the module.