Detection of chemicals with infrared light

• US 8,101,915 B2
• Filed: 10/21/2008
• Issued: 01/24/2012
• Est. Priority Date: 10/24/2007
• Status: Active Grant

• Current Assignee: The Government Of The United States As Represented By The Secretary Of The Navy
• Original Assignee: the united states of america as represented by the secretary of the navy
• Inventors: McGill, R Andrew, Kendziora, Chris, Furstenberg, Robert, Papantonakis, Michael, Hubler, Graham K, Horwitz, James S
• Primary Examiner(s): Kim, Kiho
• Application Number:
  US12/255,103
• Publication Number:
  US 20100044570A1
• Time in Patent Office: 1,190 Days
• Field of Search: 250330-335, 2503361-3362, 2503381-3385, 25033901-33915, 250/340, 2503411-3418
• US Class Current: 250/338.5
• CPC Class Codes: G01N 21/71 thermally excited
• CPC Class Codes: G01N 21/718 Laser microanalysis, i.e. with formation of sample plasma

Abstract

The present invention is directed to a method for non-contact or stand off chemical detection by selectively exciting one or more analytes of interest using an IR source tuned to at least one specific absorption band without significantly decomposing the analyte and determining if the analyte is present by comparing emitted photons with an IR detector signal made before and during or shortly after exciting the analyte. Another embodiment provides a method for non-contact or stand off chemical detection by selectively exciting one or more analytes of interest using an IR source tuned to at least one specific absorption band without significantly decomposing the analyte, wherein the analyte is excited sufficiently to generate a vapor plume, and wherein the plume is examined to detect the presence of the analyte. Additionally, the present invention provides for a system for non-contact or stand off chemical detection.

Claims

1. A method for non-contact chemical detection, comprising:

(a) selectively exciting one or more analytes of interest using an IR source tuned to at least one specific absorption band without decomposing more than five percent of the analyte; and

(b) determining if the analyte is present by comparing emitted photons with an IR detector signal collected before and during or shortly after exciting the analyte,

wherein a differential signal is created by subtracting a first signal taken before exciting the analyte from a second signal taken during or shortly after exciting the analyte and scaling by the power of the excitation IR source, wherein the differential signal is used to identify the presence of the analyte.

2. The method of claim 1, wherein the method is eye-safe, and wherein the method does not cause significant damage to a surface on which the analyte is located.

3. The method of claim 1, wherein the method is stand off.

4. The method of claim 1, wherein the analyte of interest is selected from the group consisting of explosives, additives to explosives, drugs, chemical warfare agents, biochemicals, and biological warfare agents.

5. The method of claim 1, wherein the IR source is a pulsed laser, continuous laser, broad band light source, filtered broad band light source, swept source, chirped source, variable source, or tunable source.

6. The method of claim 1, wherein multiple IR wavelengths are used to detect multiple analytes of interest.

7. The method of claim 1, wherein multiple IR wavelengths are used to improve selectivity where at least one IR wavelength is on-resonance for the analyte and at least one IR wavelength is off-resonance.

8. The method of claim 1, wherein the IR source emits somewhere in the range between 1 and 20 microns.

9. The method of claim 1, wherein to detect nitrogen based explosives, the IR source is tuned to a wavelength at or near a peak in the absorption spectrum characteristic of an N—

O bond;

wherein to detect phosphonate ester chemical warfare agents, the IR source is tuned to a wavelength at or near a peak in the absorption spectrum characteristic of a P═

O double bond or a C—

O—

P bond; and

wherein to detect drugs of abuse, the IR source is tuned to a wavelength at or near a peak in the absorption spectrum characteristic of a secondary or tertiary amine.

10. The method of claim 1, wherein the IR detector is a single channel or a multi channel detector.

11. The method of claim 1, wherein the IR detector signal in step (b) is filtered to be selective for the analyte by using an optical filter that passes wavelengths which the analyte emits and blocks wavelengths from the rest of the thermal band.

12. A method for non-contact chemical detection, comprising selectively exciting one or more analytes of interest using an IR source tuned to at least one specific absorption band without decomposing more than five percent of the analyte, wherein the analyte is excited sufficiently to generate a vapor plume, wherein the plume is examined to detect the presence of the analyte, wherein a differential signal is created by subtracting a first signal taken before exciting the analyte from a second signal taken during or shortly after exciting the analyte and scaling by the power of the excitation IR source, wherein the differential signal is used to identify the presence of the analyte.

13. The method of claim 12, wherein the method is eye-safe, and wherein the method does not cause significant damage to a surface on which the analyte is located.

14. The method of claim 12, wherein the method is stand off.

15. The method of claim 12, wherein the analyte of interest is selected from the group consisting of explosives, additives to explosives, drugs, chemical warfare agents, biochemicals, and biological warfare agents.

16. The method of claim 12, wherein the IR source is a pulsed laser, continuous laser, broad band light source, filtered broad band light source, swept source, chirped source, variable source, or tunable source.

17. The method of claim 12, wherein multiple IR wavelengths are used to detect multiple analytes of interest.

18. The method of claim 12, wherein multiple IR wavelengths are used to improve selectivity where at least one IR wavelength is on-resonance for the analyte and at least one IR wavelength is off-resonance.

19. The method of claim 12, wherein the IR source emits somewhere in the range between 1 and 20 microns.

20. The method of claim 12, wherein to detect nitrogen based explosives, the IR source is tuned to a wavelength at or near a peak in the absorption spectrum characteristic of an N—

O bond;

wherein to detect phosphonate ester chemical warfare agents, the IR source is tuned to a wavelength at or near a peak in the absorption spectrum characteristic of a P═

O double bond or a C—

O—

P bond; and

wherein to detect drugs of abuse, the IR source is tuned to a wavelength at or near a peak in the absorption spectrum characteristic of a secondary or tertiary amine.

21. The method of claim 12, wherein an optical technique is used to examine the vapor plume.

22. The method of claim 12, wherein the vapor plume is examined using an IR source, visible source, IR detector, visible detector, diffraction grating, filter wheel, Michelson interferometer, laser cavity and integrating sphere, or any combination thereof;

and wherein the presence of the analyte is determined by using IR absorption, IR backscattering, IR thermal luminescence, Raman spectroscopy, LIBS, or any combination thereof.

23. The method of claim 12, wherein the vapor plume is examined by ion mobility spectrometry, mass spectrometry, gas chromatography, chemiluminescence, surface acoustic wave, gravimetric, microbalance, crystal resonance, or any combination thereof.

24. A system for non-contact chemical detection, comprising:

(a) an IR source tuned to at least one specific absorption band specific to one or more analytes of interest; and

(b) an IR detector;

wherein the analyte is selectively excited using the IR source without decomposing more than five percent of the analyte, and the presence of the analyte is determined by comparing emitted photons with an IR detector signal collected before and during or shortly after exciting the analyte, and

wherein a differential signal is created by subtracting a first thermal signal from a second thermal signal and scaling by the power of the excitation IR source, wherein the differential signal is used to identify the presence of the analyte.

25. The system of claim 24, wherein the detection is eye-safe, and wherein the detection does not cause significant damage to a surface on which the analyte is located.

26. The system of claim 24, wherein the detection is stand off.

27. The system of claim 24, wherein the analyte of interest is selected from the group consisting of explosives, additives to explosives, drugs, chemical warfare agents, biochemicals, and biological warfare agents.

28. The system of claim 24, wherein the IR source is a pulsed laser, continuous laser, broad band light source, filtered broad band light source, swept source, chirped source, variable source, or tunable source.

29. The system of claim 24, wherein multiple IR wavelengths are used to detect multiple analytes of interest.

30. The system of claim 24, wherein multiple IR wavelengths are used to improve selectivity where at least one IR wavelength is on-resonance for the analyte and at least one IR wavelength is off-resonance.

31. The system of claim 24, wherein the IR source emits somewhere in the range between 1 and 20 microns.

32. The system of claim 24, wherein to detect nitrogen based explosives, the IR source is tuned to a wavelength at or near a peak in the absorption spectrum characteristic of an N—

O bond;

wherein to detect phosphonate ester chemical warfare agents, the IR source is tuned to a wavelength at or near a peak in the absorption spectrum characteristic of a P═

O double bond or a C—

O—

P bond; and

wherein to detect drugs of abuse, the IR source is tuned to a wavelength at or near a peak in the absorption spectrum characteristic of a secondary or tertiary amine.

33. The system of claim 24, wherein the IR detector is a single channel detector or a multi channel.

34. The system of claim 24, wherein an optical filter that passes wavelengths which the analyte emits and blocks wavelengths from the rest of the thermal band is used with the IR detector.

35. A system for non-contact chemical detection, comprising:

(a) an IR source tuned to at least one specific absorption band specific to one or more analytes of interest; and

(b) means for detecting the presence of the analyte;

wherein, the analyte is selectively excited using the IR source creating a vapor plume without decomposing more than five percent of the analyte, and the presence of the analyte is determined by examining the vapor plume,

wherein a differential signal is created by subtracting a first signal from a second signal and scaling by the power of the excitation IR source, wherein the differential signal is used to identify the presence of the analyte.

36. The system of claim 35, wherein the detection is eye-safe, and wherein the detection does not cause significant damage to a surface on which the analyte is located.

37. The system of claim 35, wherein the detection is stand off.

38. The system of claim 35, wherein the analyte of interest is selected from the group consisting of explosives, additives to explosives, drugs, chemical warfare agents, biochemicals, and biological warfare agents.

39. The system of claim 35, wherein the IR source is a pulsed laser, continuous laser, broad band light source, filtered broad band light source, swept source, chirped source, variable source, or tunable source.

40. The system of claim 35, wherein multiple IR wavelengths are used to detect multiple analytes of interest.

41. The system of claim 35, wherein multiple IR wavelengths are used to improve selectivity where at least one IR wavelength is on-resonance for the analyte and at least one IR wavelength is off-resonance.

42. The system of claim 35, wherein the IR source emits somewhere in the range between 1 and 20 microns.

43. The system of claim 35, wherein to detect nitrogen based explosives, the IR source is tuned to a wavelength at or near a peak in the absorption spectrum characteristic of an N—

O bond;

wherein to detect phosphonate ester chemical warfare agents, the IR source is tuned to a wavelength at or near a peak in the absorption spectrum characteristic of a P═

O double bond or a C—

O—

P bond; and

wherein to detect drugs of abuse, the IR source is tuned to a wavelength at or near a peak in the absorption spectrum characteristic of a secondary or tertiary amine.

44. The system of claim 35, wherein an optical technique is used to examine the vapor plume.

45. The system of claim 35, wherein the vapor plume is examined using an IR source, visible source, IR detector, visible detector, diffraction grating, filter wheel, Michelson interferometer, laser cavity and integrating sphere, or any combination thereof;

and wherein the presence of the analyte is determined by using IR absorption, IR backscattering, IR thermal luminescence, Raman spectroscopy, LIBS, or any combination thereof.

46. The system of claim 35, wherein the vapor plume is examined by ion mobility spectrometry, mass spectrometry, gas chromatography, chemiluminescence, surface acoustic wave, gravimetric, microbalance, crystal resonance, or any combination thereof.