Method and arrangement of measuring acidity or other chemical or physical property of a gas

• US 8,182,748 B2
• Filed: 03/07/2008
• Issued: 05/22/2012
• Est. Priority Date: 03/16/2007
• Status: Expired due to Fees

• Current Assignee: Janesko Oy
• Original Assignee: Janesko Oy
• Inventors: Voipio, Ville, Vuokila, Katri
• Primary Examiner(s): Bullock, In Suk
• Assistant Examiner(s): Pregler, Sharon
• Application Number:
  US12/073,657
• Publication Number:
  US 20080227215A1
• Time in Patent Office: 1,537 Days
• Field of Search: 422/88, 422/820.05, 422/82.06, 422/82.07, 422/82.08, 422/164, 422/82.11, 436/169, 356/446, 356/445, 356/234, 356/432, 356/436, 356/409, 356/300, 356/326, 356/346, 356/450
• US Class Current: 422/82.05
• CPC Class Codes: G01N 21/783 for analysing gases
• CPC Class Codes: G01N 21/80 Indicating pH value

Abstract

A method and an arrangement of measuring acidity or other chemical or physical property of a gas. The invention comprises a membrane having optical indicator molecules bound to a microporous matrix arranged to be placed into contact with the gas to be measured, the optical indicator molecules changing their colour in response to the acidity or other chemical or physical property of the gas, a light source, and a detector. The light source is arranged to emit and direct light to the membrane, the light being transmitted through the membrane, whereby a part of the light is absorbed into the optical indicator molecules, and the rest of the light emitted is guided to the detector, where it is measured.

Claims

1. A method of measuring acidity or other chemical or physical property of a gas, the method comprising:

contacting a membrane having optical indicator molecules bound to a microporous matrix with the gas to be measured, the optical indicator molecules changing their color in response to the acidity or other chemical or physical property of the gas, and

directing light to the membrane, whereby a part of the light is absorbed into the optical indicator molecules, and measuring the light passed through the membrane,

wherein the light directed to the membrane has more than one wave length,

wherein a porous mirror is disposed on the membrane and includes at least one layer allowing ions to pass through and reflecting light backwards to a detector.

2. The method according to claim 1, wherein the light directed to the membrane is a monochromatic light.

3. The method according to claim 1, wherein the membrane is deposited on an optical window of a flow cell containing the gas to be measured.

4. A system for measurement of acidity or other chemical or physical property of a gas, comprising:

a membrane having optical indicator molecules bound to a microporous matrix arranged to be placed into contact with the gas to be measured, the optical indicator molecules changing their color in response to the acidity or other chemical or physical property of the gas,

a light source, and

a detector,

the light source being arranged to emit and direct light to the membrane,

wherein the membrane, light source and detector are arranged such that a part of the light is absorbed into the optical indicator molecules, and the rest of the light emitted is passed through the membrane and guided to the detector, where it is measured,

wherein the light source is arranged to emit more than one wavelength,

wherein a porous mirror is disposed on the membrane and includes at least one layer allowing ions to pass through and reflecting light backwards to the detector.

5. The system according to claim 4, wherein the light source is arranged to emit monochromatic light.

6. The system according to claim 4, wherein the membrane having optical indicator molecules bound to the microporous matrix is a dye film deposited on a substrate.

7. The system according to claim 6, wherein the membrane having optical indicator molecules bound to microporous matrix is a dye film fabricated by a Sol-Gel method.

8. The system according to claim 6, wherein the dye film deposited on the substrate is covered by the porous mirror.

9. The system according to claim 8, wherein the porous mirror is a dielectric mirror.

10. The system according to claim 4, wherein the membrane is deposited on an optical window of a flow cell for containing the gas to be measured.