Process for application of a hydrophilic coating to fuel cell bipolar plates

• US 8,182,884 B2
• Filed: 08/09/2006
• Issued: 05/22/2012
• Est. Priority Date: 02/28/2005
• Status: Expired due to Fees

• Current Assignee: GM Global Technology Operations LLC (General Motors Company)
• Original Assignee: GM Global Technology Operations LLC (General Motors Company)
• Inventors: Winter, Gerhard, Vyas, Gayatri, Trabold, Thomas A., Datta, Reena L.
• Primary Examiner(s): Meeks, Timothy
• Assistant Examiner(s): MILLER, JR, JOSEPH ALBERT
• Application Number:
  US11/463,386
• Publication Number:
  US 20070031721A1
• Time in Patent Office: 2,113 Days
• Field of Search: None
• US Class Current: 427/578
• CPC Class Codes: H01M 8/0206 Metals or alloys
• CPC Class Codes: H01M 8/0213 Gas-impermeable carbon-containing materials
• CPC Class Codes: H01M 8/0221 Organic resins; Organic polymers
• CPC Class Codes: H01M 8/0228 in the form of layered or coated products
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A process comprising: depositing a coating on a fuel cell bipolar plate using plasma assisted chemical vapor deposition.

Claims

1. A process comprising:

providing a bipolar plate that comprises a plurality of lands and channels;

flowing a precursor gas that comprises a siloxane and a carrier gas that comprises oxygen into a plasma reaction chamber, wherein a volumetric flow rate ratio of the siloxane to the oxygen ranges from about 8% to about 10%;

depositing a coating comprising nodule shaped siloxane-derived nanoparticles over at least a portion of the bipolar plate using plasma assisted chemical vapor deposition of the precursor gas, wherein the siloxane-derived nanoparticles have a size ranging from about 1 to about 100 nm; and

positioning a porous diffusion media adjacent to the bipolar plate so that fibers from the diffusion media extend through the coating and provide an electrical flow path through the coating from the bipolar plate to the diffusion media.

2. A process as set forth in claim 1 wherein the precursor gas comprises hexamethyl disiloxane.

3. A process as set forth in claim 1 further comprising post-treating the coating to add polar functional groups onto the siloxane-derived nanoparticles in the coating.

4. A process as set forth in claim 1 further comprising post-treating the coating comprising exposing the coating to a plasma comprising oxygen ions.

5. A process as set forth in claim 1 further comprising pre-treating the bipolar plate prior to the depositing comprising attaching polar groups to the bipolar plate.

6. A process comprising:

providing a cathode-side bipolar plate and an anode-side bipolar plate that each comprise a plurality of lands and channels;

flowing a precursor gas that comprises a siloxane and a carrier gas that comprises oxygen into a plasma reaction chamber, wherein a volumetric flow rate ratio of the siloxane to the oxygen ranges from about 8% to about 10%;

depositing a first coating that comprises nodule shaped siloxane-derived nanoparticles on at least a portion of the cathode-side bipolar plate using plasma assisted chemical vapor deposition of the precursor gas, wherein the siloxane-derived nanoparticles have a size ranging from about 1 to about 100 nm;

depositing a second coating that comprises nodule shaped siloxane-derived nanoparticles on at least a portion of the anode-side bipolar plate using plasma assisted chemical vapor deposition of the precursor gas, wherein the siloxane-derived nanoparticles have a size ranging from about 1 to about 100 nm, and wherein the second coating is thicker than the first coating;

positioning a first porous diffusion media adjacent to the cathode-side bipolar plate so that fibers from the first diffusion media extend through the first coating and provide an electrical flow path through the first coating from the cathode-side bipolar plate to the first diffusion media;

positioning a second porous diffusion media adjacent to the anode-side bipolar plate so that fibers from the second diffusion media extend through the second coating and provide an electrical flow path through the second coating from the anode-side bipolar plate to the second diffusion media;

positioning the cathode-side bipolar plate and the first porous diffusion media on one side of a membrane-electrode assembly and the anode-side bipolar plate and the second porous diffusion media on the opposite side of the membrane-electrode assembly to form a fuel cell.

7. A process as set forth in claim 6 further comprising masking a portion of the cathode-side or the anode-side bipolar plate prior to depositing.