Refrigerant with lubricating oil for replacement of R22 refrigerant

• US 8,197,706 B2
• Filed: 12/06/2010
• Issued: 06/12/2012
• Est. Priority Date: 09/08/2003
• Status: Active Grant

• Current Assignee: R421A, LLC
• Original Assignee: Kenneth M. Ponder, Thomas, Steffan Jr.
• Inventors: Ponder, Kenneth M., Thomas, Steffan Jr.
• Primary Examiner(s): Hardee, John
• Application Number:
  US12/961,045
• Publication Number:
  US 20110163117A1
• Time in Patent Office: 554 Days
• Field of Search: 252/68
• US Class Current: 252/68
• CPC Class Codes: C09K 2205/22 All components of a mixture being fluoro compounds
• CPC Class Codes: C09K 2205/43 Type R22
• CPC Class Codes: C09K 5/045 containing only fluorine as halogen
• CPC Class Codes: C10M 171/008 Lubricant compositions compatible with refrigerants
• CPC Class Codes: C10M 2203/1065 used as base material
• CPC Class Codes: C10M 2223/041 Triaryl phosphates
• CPC Class Codes: C10N 2020/101 Containing Hydrofluorocarbons
• CPC Class Codes: F25B 2400/18 Refrigerant conversion

Abstract

An apparatus and method wherein potential ozone layer-damaging chlorodifluoromethane (Refrigerant R-22) is substituted with a mix of less environmentally damaging refrigerants pentafluoroethane and tetrafluoroethane in chlorodifluoromethane-based air-cooling systems mainly in residential cooling. While less environmentally damaging than chlorodifluoromethane, the substitute refrigerant has a temperature-pressure relationship similar to that of chlorodifluoromethane, making the substitute refrigerant suitable for use with chlorodifluoromethane-based air-cooling systems. In this event, it is mixed with a relatively small percentage of a lubricating oil which is compatible with both the unit refrigerant and typical R-22 system design.

Claims

1. In an apparatus designed for use with chlorodifluoromethane refrigerant, the improvement comprising substituting the chlorodifluoromethane with a refrigerant composition designed to achieve a phase change, the refrigerant composition comprising a combination of refrigerant gases, said refrigerant gases consisting of a blend of tetrafluoroethane and pentafluoroethane, the ratio of the tetrafluoroethane to the pentafluoroethane being selected such that the blend exhibits a dew point at about −

32°

F. or a bubble point at about −

41.5°

F., wherein the refrigerant composition further comprises non-refrigerant gas components, said non-refrigerant gas components including a lubricating oil, wherein the lubricating oil is present up to about 20% by weight of the refrigerant gases and is soluble in chlorodifluoromethane, tetrafluoroethane and pentafluoroethane wherein the lubricating oil is selected from the group consisting of napthenic based lubricants and polyol ester.

2. In the apparatus of claim 1, wherein the blend exhibits a dew point at About −

32°

F. and a bubble point at about −

41.5°

F.

3. In an apparatus designed for use with chlorodifluoromethane refrigerant, the improvement comprising substituting the chlorodifluoromethane with a refrigerant composition, the refrigerant composition comprising a combination of refrigerant gases, said refrigerant gases consisting of a blend of tetrafluoroethane and pentafluoroethane,

the ratio of the tetrafluoroethane to the pentafluoroethane being selected such that the blend exhibits one or more of a dew point at about −

32°

F. or a bubble point at about −

41.5°

F. wherein the refrigerant composition further comprises non-refrigerant gas components, said non-refrigerant gas components including up to about 20% by weight of the refrigerant gases a lubricating oil that is soluble in the lubricating oil having the following components;

65-88% hydrotreated light napthenic distillate, and

10-20% solvent refined light napthenic distillate petroleum.

4. In the apparatus of claim 3, wherein the blend exhibits a dew point at about −

32°

F. and a bubble point at about −

41.5°

F.

5. In the apparatus of claim 3, wherein the apparatus is selected from the group consisting of refrigeration equipment, air-conditioning equipment, and HVAC equipment.

6. In the apparatus of claim 3, wherein the lubricating oil includes an additive selected from the group consisting of acrylic polymer, a corrosion inhibitor, a surfactant, a foaming agent, and mixtures thereof.

7. In the apparatus of claim 3, wherein the tetrafluoroethane is 1,1,1,2-tetrafluoroethane.

8. In the apparatus of claim 7, wherein in the substitute refrigerant said pentafluoroethane is present in the ratio of about 58% by weight to said tetrafluoroethane present in an amount of about 42% by weight.

9. A method for refilling an apparatus designed for use with a chlorodifluoromethane refrigerant, the method comprising:

(1) selecting a substitute refrigerant composition designed to achieve a phase change and comprising a combination of refrigerant gases, the refrigerant gases consisting of a blend of tetrafluoroethane and pentafluoroethane, the ratio of the tetrafluoroethane to the pentafluoroethane being selected such that the blend exhibits a dew point at about −

32°

F. or a bubble point at about −

41.5°

F.

(2) supplying a the substitute refrigerant composition under pressure, in a cylinder can fitted with an outlet compatible with a chlorodifluoromethane recharging manifold of the apparatus; and

(3) adding to said apparatus via the manifold the substitute refrigerant composition for chlorodifluoromethane, wherein the refrigerant

composition further comprises non-refrigerant gas components, said non-refrigerant gas components including a lubricating oil, wherein the lubricating oil is present up to about 20% by weight of the refrigerant gases and is soluble in chlorodifluoromethane, tetrafluoroethane and pentafluoroethane,

wherein the lubricating oil is selected from the group consisting of napthenic based lubricants and polyol ester.

10. The method of claim 9, wherein the blend exhibits a dew point at about 32°

F. and a bubble point at about −

41.5°

F.

11. A method for refilling an apparatus designed for use with a chlorodifluoromethane refrigerant, the method comprising:

(1) selecting a substitute refrigerant composition designed to achieve a phase change and comprising a combination of refrigerant gases, the refrigerant gases consisting of a blend of tetrafluoroethane and pentafluoroethane, the ratio of the tetrafluoroethane to the pentafluoroethane being selected such that the blend exhibits a dew point at about −

32°

F. or a bubble point at about −

41.5°

F.,

(2) supplying a the substitute refrigerant composition under pressure, in a cylinder can fitted with an outlet compatible with a chlorodifluoromethane recharging manifold of the apparatus; and

(3) adding to said apparatus via the manifold the substitute refrigerant composition for chlorodifluoromethane, the lubricating oil having the following components;

65-85% hydrotreated light napthenic distillate, and

10-20% solvent refined light napthenic distillate petroleum.

12. The method of claim 11, wherein the blend exhibits a dew point at about −

32°

F. and a bubble point at about −

41.5°

F.

13. The method according to claim 11, wherein the apparatus is selected from the group consisting of refrigeration equipment, air-conditioning equipment, and HVAC equipment.

14. The method according to claim 11, wherein the lubricating oil includes an additive selected from the group consisting of acrylic polymer, a corrosion inhibit, a surfactant, a foaming agent, and mixtures thereof.

15. The method of claim 11, wherein the tetrafluoroethane is 1,1,1,2-tetrafluoroethane.

16. The method according to claim 15, wherein in the substitute refrigerant said pentafluoroethane is present in the ratio of about 58% by weight to said tetrafluoroethane present in an amount of about 42% by weight.

17. A refrigerant composition comprising a combination of refrigerant gases, the refrigerant gases consisting of a blend of tetrafluoroethane and pentafluoroethane, the ratio of the tetrafluoroethane to the pentafluoroethane being selected such that the blend exhibits a dew point at about −

32°

F. or a bubble point at about −

41.5°

F., wherein the refrigerant composition further comprises non-refrigerant gas components, said non-refrigerant gas components including a lubricating oil, wherein the lubricating oil is present up to about 20% by weight of the refrigerant gases and is soluble in chlorodifluoromethane, tetrafluoroethane and pentafluoroethane, wherein the lubricating oil is selected from the group consisting of napthenic based lubricants and polyol ester.

18. The refrigerant composition of claim 17, wherein the blend exhibits a dew point at −

32°

F. and a bubble point at −

41.5°

F.

19. A refrigerant composition comprising a combination of refrigerant gases, the refrigerant gases consisting of a blend of tetrafluoroethane and pentafluoroethane, the ratio of the tetrafluoroethane to the pentafluoroethane being selected such that the blend exhibits one or more of a dew point at about −

32°

F. or a bubble point at about −

41.5°

F., wherein the refrigerant composition further comprises non-refrigerant gas components, said non-refrigerant gas components including up to about 20% by weight of the refrigerant gases a lubricating oil that is soluble in the lubricating oil having the following components;

65-88% hydrotreated light napthenic distillate, and

10-20% solvent refined light napthenic distillate petroleum.

20. The refrigerant composition of claim 19, wherein the blend exhibits a dew point at about −

32°

F. and a bubble point at about −

41.5°

F.

21. The refrigerant composition according to claim 19, wherein the lubricating oil further includes an acrylic polymer, a corrosion inhibitor, a surfactant or a foaming agent.

22. The refrigerant composition of claim 19, wherein the tetrafluoroethane is 1,1,1,2-tetrafluoroethane.

23. The refrigerant composition according to claim 22, wherein said pentafluoroethane is present in the ratio of about 58% by weight to said tetrafluoroethane present in an amount of about 42% by weight with a napthenic lubricant.