Sensor device and method for qualitative and quantitative analysis of gas phase substances

• US 8,201,992 B2
• Filed: 11/06/2007
• Issued: 06/19/2012
• Est. Priority Date: 07/16/2001
• Status: Expired due to Fees

• Current Assignee: Sensor Tech Inc.
• Original Assignee: Sensor Tech Inc.
• Inventors: Horovitz, Michael L., Anderson, Karl F.
• Primary Examiner(s): Verbitsky, Gail
• Application Number:
  US11/935,928
• Publication Number:
  US 20080101434A1
• Time in Patent Office: 1,687 Days
• Field of Search: 374 29- 40, 374 43- 45, 374 10- 12, 374/144, 422/83, 422/50, 422/68.1, 422/82.02, 422/88, 422/90, 422/82.01, 422 95- 96, 422/151, 422/51, 422/109, 422/119, 422/122, 422/94, 436/43, 436/147, 436/149, 436/151, 436/152, 436/155, 436/159, 73/10.1, 73/230.1, 73/230.5, 73/232, 73/10.2, 73/250.1, 73/232.5
• US Class Current: 374/29
• CPC Class Codes: G01N 27/123 for controlling the temperature temperature control per se G05D23/00
• CPC Class Codes: G01N 27/16 caused by burning or catalytic oxidation of surrounding material to be tested, e.g. of gas
• CPC Class Codes: G01N 27/3271 Amperometric enzyme electrodes for analytes in body fluids, e.g. glucose in blood amperometry per se G01N27/49; aspects concerning the enzyme reagent C12Q1/001
• CPC Class Codes: G01N 33/497 of gaseous biological material, e.g. breath
• CPC Class Codes: Y10T 29/49 Method of mechanical manufacture
• CPC Class Codes: Y10T 29/49002 Electrical device making
• CPC Class Codes: Y10T 436/11 Automated chemical analysis

Abstract

New sensors and methods for qualitative and quantitative analysis of multiple gaseous substances simultaneously with both high selectivity and high sensitivity are provided. The new sensors rely on a characteristic difference in energy between the interaction of a particular substance with a catalyst coated heat transfer device (HTD) and a non-catalyst coated (or one coated with a different catalyst) reference HTD. Molecular detection is achieved by an exothermic or endothermic chemical or physical reaction between the catalytic surface of the sensor and the molecule, tending to induce a temperature change of the sensor. Both high temperature and non-destructive low temperature detection are possible. The magnitude and rate of endothermic or exothermic heat transfer from a specific molecule-catalyst interaction is related to molecular concentration.

Claims

1. A sensor for detecting gas phase substances, comprising:

a sensing element in contact with the gas phase substances, comprising;

a first resistance temperature detector which functions as a temperature detector and a variable resistance heater, and

a first catalyst in thermal contact with the first resistance temperature detector, wherein the first catalyst interacts with the gas phase substances;

a reference element in contact with the gas phase substances, comprising;

a second resistance temperature detector which functions as a temperature detector and a variable resistance heater, and

a second catalyst in thermal contact with the second resistance temperature detector, wherein the second catalyst interacts with the gas phase substances;

a thermal barrier separating the sensing element from the reference element; and

a heat flow monitor connected to both the sensing and reference elements for measuring any change in heat flow for the sensing element relative to the reference element by monitoring the change in electric power needed to maintain the first resistance temperature detector at a desired temperature relative to the second resistance temperature detector.

2. The sensor of claim 1, wherein the interaction between the first and second catalyst and the gas phase substances comprises one of endothermic and exothermic heat flow from the first and second catalyst to the first resistance temperature detector.

3. The sensor of claim 1, wherein the first catalyst comprises a first catalyst face of a catalyst crystal and the second catalyst comprises a second catalyst face of the catalyst crystal.

4. The sensor of claim 3, wherein the catalyst crystal is an oxide catalyst.

5. The sensor of claim 4, wherein the oxide catalyst is selected from a metal oxide, boride, carbide, silicide, nitride, phosphide, arsenide, sulfide, selenide, telluride, fluoride, chloride, bromide, or iodide;

a non-metal oxide, boride, carbide, suicide, nitride, phosphide, arsenide, sulfide, selenide, telluride, fluoride, chloride, bromide, or iodide;

a metal;

an alloy, a substance in which more than one metal or more than one nonmetal are combined with an element;

a substance in which a metal or a non-metal are combined with more than one other element;

or a combination thereof.

6. The sensor of claim 1, wherein the heat flow monitor comprises an Anderson Loop measurement circuit topology.

7. The sensor of claim 1, wherein the heat flow monitor comprises a Wheatstone bridge measurement circuit topology.

8. The sensor of claim 1, wherein the heat flow monitor comprises a Kelvin circuit topology.

9. The sensor of claim 1, wherein the first and second temperature detectors comprise a material selected from nickel, platinum, or tungsten.