Method and apparatus for electrolyzing water

• US 8,211,288 B2
• Filed: 08/27/2004
• Issued: 07/03/2012
• Est. Priority Date: 03/06/2002
• Status: Expired due to Fees

• Current Assignee: The University of Georgia Research Foundation, Inc.
• Original Assignee: The University of Georgia Research Foundation, Inc.
• Inventors: Hung, Yen-Con, Chung, Donghwan
• Primary Examiner(s): Phasge, Arun S
• Application Number:
  US10/927,924
• Publication Number:
  US 20050126928A1
• Time in Patent Office: 2,867 Days
• Field of Search: 205/701, 205/746, 205/257, 205/275.1
• US Class Current: 205/701
• CPC Class Codes: A61L 2/035 Electrolysis
• CPC Class Codes: A61L 2/18 Liquid substances or solutions comprising solids or dissolved gases
• CPC Class Codes: C02F 1/4618 for producing "ionised" acidic or basic water
• CPC Class Codes: C02F 1/4674 with halogen or compound of halogens, e.g. chlorine, bromine
• CPC Class Codes: C02F 2001/46142 Catalytic coating
• CPC Class Codes: C02F 2201/46115 Electrolytic cell with membranes or diaphragms
• CPC Class Codes: C02F 2201/46145 Fluid flow
• CPC Class Codes: C02F 2201/46185 Recycling the cathodic or anodic feed
• CPC Class Codes: C02F 2209/04 Oxidation reduction potential [ORP]
• CPC Class Codes: C02F 2209/06 pH
• CPC Class Codes: C02F 2303/04 Disinfection

Abstract

Feed water comprising an aqueous salt solution is supplied to an anode chamber and to a cathode chamber. The feed water is cathodically electrolyzed in the cathode chamber to produce alkaline electrolyzed water (catholyte) and is anodically electrolyzed in the anode chamber to produce electrolyzed water (anolyte) whose pH is modified. A portion of alkaline catholyte from the cathode chamber is recycled back to the feed water during continuous electrolysis to provide a blend of feed water and alkaline catholyte to the anode chamber to control pH of the anodically electrolyzed water therein to provide more stable bactericidal activity thereof over time.

Claims

1. A method of making electrolyzed water, comprising supplying unelectrolyzed feed water comprising an aqueous salt solution to an anode chamber where anodically electrolyzed water is produced and to a cathode chamber where cathodically electrolyzed alkaline water is produced, and returning a portion of the cathodically electrolyzed water to only the unelectrolyzed feed water supplied to the anode chamber to provide a blend of the unelectrolyzed feed water and the cathodically electrolyzed water to the anode chamber to control pH of the anodically electrolyzed water wherein the flow rate of the blend in the anode chamber is substantially equal to the flow rate of the unelectrolyzed feed water in the cathode chamber.

2. The method of claim 1 wherein said pH is controlled above 5.

3. The method of claim 2 wherein said pH is controlled between 6 and 9.

4. The method of claim 2 wherein the active chlorine concentration of said anodically electrolyzed water is generally constant over at said pH above 5.

5. The method of claim 1 wherein the pH of said anodically electrolyzed water is controlled to provide a concentration of active chlorine therein that is substantially constant over a storage time up to 38 hours at 25 degrees C. in an open container with agitation.

6. A method of making electrolyzed water, comprising supplying unelectrolyzed feed water comprising an aqueous salt solution to an anode chamber where anodically electrolyzed water is produced and to a cathode chamber where cathodically electrolyzed alkaline water is produced, and returning a portion of the cathodically electrolyzed water to the unelectrolyzed feed water supplied to both the anode chamber and the cathode chamber to provide a blend of the unelectrolyzed feed water and the cathodically electrolyzed water to the anode chamber and to the cathode chamber, said blend supplied to the anode chamber being effective to control pH of the anodically electrolyzed water, wherein the flow rate of the blend in the cathode chamber is substantially equal to the flow rate of the blend in the anode chamber.

7. The method of claim 6 wherein the pH of said anodically electrolyzed water is controlled to provide a concentration of active chlorine therein that is substantially constant over a storage time up to 38 hours at 25 degrees C. in an open container with agitation.